479 research outputs found
Elucidation of role of graphene in catalytic designs for electroreduction of oxygen
Graphene is, in principle, a promising material for consideration as
component (support, active site) of electrocatalytic materials, particularly
with respect to reduction of oxygen, an electrode reaction of importance to
low-temperature fuel cell technology. Different concepts of utilization,
including nanostructuring, doping, admixing, preconditioning, modification or
functionalization of various graphene-based systems for catalytic
electroreduction of oxygen are elucidated, as well as important strategies to
enhance the systems' overall activity and stability are discussed
Evaluation of Reduced-Graphene-Oxide Aligned with WO3-Nanorods as Support for Pt Nanoparticles during Oxygen Electroreduction in Acid Medium
Hybrid supports composed of chemically-reduced graphene-oxide-aligned with
tungsten oxide nanowires are considered here as active carriers for dispersed
platinum with an ultimate goal of producing improved catalysts for
electroreduction of oxygen in acid medium. Here WO3 nanostructures are expected
to be attached mainly to the edges of graphene thus making the hybrid structure
not only highly porous but also capable of preventing graphene stacking and
creating numerous sites for the deposition of Pt nanoparticles. Comparison has
been made to the analogous systems utilizing neither reduced graphene oxide nor
tungsten oxide component. By over-coating the reduced-graphene-oxide support
with WO3 nanorods, the electrocatalytic activity of the system toward the
reduction of oxygen in acid medium has been enhanced even at the low Pt loading
of 30 microg cm-2. The RRDE data are consistent with decreased formation of
hydrogen peroxide in the presence of WO3. Among important issues are such
features of the oxide as porosity, large population of hydroxyl groups, high
Broensted acidity, as well as fast electron transfers coupled to unimpeded
proton displacements. The conclusions are supported with mechanistic and
kinetic studies involving double-potential-step chronocoulometry as an
alternative diagnostic tool to rotating ring-disk voltammetry.Comment: arXiv admin note: text overlap with arXiv:1805.0315
Electrocatalytic Oxygen Reduction in Alkaline Medium at Graphene-Supported Silver-Iron Carbon Nitride Sites Generated During Thermal Decomposition of Silver Hexacyanoferrate
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A formalism to compare electrocatalysts for the oxygen reduction reaction by cyclic voltammetry with the thin-film rotating ring-disk electrode measurements
This report describes a general method to correlate the features determining the performance of an electrocatalyst (EC), including the accessibility of O2 to the active sites and the kinetic activation barrier, with the outcome of conventional electrochemical experiments. The method has been implemented for oxygen reduction reaction ECs by cyclic voltammetry with the thin-film rotating ring-disk electrode setup. The method (i) does not rely on the simplifications associated with the Butler-Volmer kinetic description of electrochemical processes and (ii) does not make assumptions on the specific features of the EC, allowing to compare accurately the kinetic performance of oxygen reduction reaction ECs with completely different chemistry. Finally, with respect to other widespread figures of merit (e.g. the half-wave potential E1/2), the figure of merit here proposed, for example, E(jPt[5%]), allows for much more accurate comparisons of the kinetic performance of ECs
METHOD AND PLANT FOR ACTIVATING CATALYSTS
La presente invenzione si riferisce ad un metodo di attivazione di un materiale catalizzatore solido, ad un catalizzatore attivato ottenibile da detto metodo di attivazione, ad una cella a combustibile, un elettrolizzatore, una batteria metallo-aria o una marmitta catalitica contenente detto catalizzatore attivato, nonché ad un impianto per realizzare detto metodo di attivazione
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