Environmental characterisation to guide breeding decisions in a changing climate

Substantial evidence now exists suggesting that agricultural yields will have to increase significantly in order to meet food needs during the 21st century. One such way of increasing yields is to develop high yielding cultivars through crop improvement. This Working Paper summarises the results of a CCAFS project named Target Population of Environments (TPE). The project aimed at providing actionable information to crop breeders and, therefore, inform breeding decisions. We developed and applied a methodology for classifying crop growing environments, determining stress profiles and, finally, assessing the potential benefit of improved breeding practice. We present two contrasting case studies, one for upland rice in central Brazil and another for common beans in Goiás (Brazil). Analyses are also currently being conducted for lowland irrigated rice in Colombia, and plans to conduct research on rice in sub-Saharan Africa. Results of the TPE project are publicly available in the form of dynamic maps and graphs at http://www.ccafs-tpe.org

Optical spectrum of bottom-up graphene nanoribbons: towards efficient atom-thick excitonic solar cells

Recently, atomically well-defined cove-shaped graphene nanoribbons have been obtained using bottom-up synthesis. These nanoribbons have an optical gap in the visible range of the spectrum which make them candidates for donor materials in photovoltaic devices. From the atomistic point of view, their electronic and optical properties are not clearly understood. Therefore, in this work we carry out ab-initio density functional theory calculations combine with many-body perturbation formalism to study their electronic and optical properties. Through the comparison with experimental measurements, we show that an accurate description of the nanoribbon's optical properties requires the inclusion of electron-hole correlation effects. The energy, binding energy and the corresponding excitonic transitions involved are analyzed. We found that in contrast to zigzag graphene nanoribbons, the excitonic peaks in the absorption spectrum are a consequence of a group of transitions involving the first and second conduction and valence bands. Finally, we estimate some relevant optical properties that strengthen the potential of these nanoribbons for acting as a donor materials in photovoltaic