SR-FTiR microscopy and FTIR imaging in the earth sciences

During the last decades, several books have been devoted to the application of spectroscopic methods in mineralogy. Several short courses and meetings have addressed particular aspects of spectroscopy, such as the analysis of hydrous components in minerals and Earth materials. In these books, complete treatment of the infrared theory and practical aspects of instrumentation and methods, along with an exhaustive list of references, can be found. The present chapter is intended to cover those aspects of infrared spectroscopy that have been developed in the past decade and are not included in earlier reviews such as Volume 18 of Reviews in Mineralogy. These new topics involve primarily: (1) the use of synchrotron radiation (SR), which, although not a routine method, is now rather extensively applied in infrared studies, in particular those requiring ultimate spatial and time resolution and the analysis of extremely small samples (a few tens of micrometers); (2) the development of imaging techniques also for foreseen time resolved studies of geo-mineralogical processes and environmental studies.Comment: 36 pages, 24 figures - Reviews in Mineralogy & Geochemistry - Vol. 78 (2013) in pres

Blood lead levels in pregnant women and the neonate

Population studies carried out during the 1980s had shown that the Maltese population was characterized by high blood lead (PbB) levels. These high levels appeared to be a feature at all age groups including neonates. A number of environmental control measures had been initiated to attempt to decrease these PbB levels. The present study reviews PbB levels in pregnant women and newborns. It is shown that mean cord PbB levels decreased significantly in the last decade from a mean of 165.1 + 87.9 ug/I in 1985 to 89.79 + 31.23 ug/I in 1996. This decrease did not correlate with the increasing use of multimineral supplements which include the zinc cation said to be useful to counter the effects of chronic lead intoxication. Placental transfer of lead is also shown to follow closely maternal levels with a correlation coefficient of 0.81. In spite of the apparent decrease in PbB levels, about half of newborns still I have levels which require preventive community measures.peer-reviewe

An Alternative Fuel Refueling Station Location Model considering Detour Traffic Flows on a Highway Road System

With the development of alternative fuel (AF) vehicle technologies, studies on finding the potential location of AF refueling stations in transportation networks have received considerable attention. Due to the strong limited driving range, AF vehicles for long-distance intercity trips may require multiple refueling stops at different locations on the way to their destination, which makes the AF refueling station location problem more challenging. In this paper, we consider that AF vehicles requiring multiple refueling stops at different locations during their long-distance intercity trips are capable of making detours from their preplanned paths and selecting return paths that may be different from original paths for their round trips whenever AF refueling stations are not available along the preplanned paths. These options mostly need to be considered when an AF refueling infrastructure is not fully developed on a highway system. To this end, we first propose an algorithm to generate alternative paths that may provide the multiple AF refueling stops between all origin/destination (OD) vertices. Then, a new mixed-integer programming model is proposed to locate AF refueling stations within a preselected set of candidate sites on a directed transportation network by maximizing the coverage of traffic flows along multiple paths. We first test our mathematical model with the proposed algorithm on a classical 25-vertex network with 25 candidate sites through various scenarios that consider a different number of paths for each OD pair, deviation factors, and limited driving ranges of vehicles. Then, we apply our proposed model to locate liquefied natural gas refueling stations in the state of Pennsylvania considering the construction budget. Our results show that the number of alternative paths and deviation distance available significantly affect the coverage of traffic flows at the stations as well as computational time

Hard Cosmic Ray Sea in the Galactic Center: a consistent interpretation of H.E.S.S. and Fermi-LAT γ\gamma-ray data

We present a novel interpretation of the gamma-ray diffuse emission measured by H.E.S.S. in the Galactic Center (GC) region and the Galactic ridge. Our starting base is an updated analysis of PASS8 Fermi-LAT data, which allows to extend down to few GeV the spectra measured by H.E.S.S. and to infer the primary CR radial distribution above 100 GeV. We compare those results with a CR transport model assuming a harder scaling of the diffusion coefficient with rigidity in the inner Galaxy. Such a behavior reproduces the radial dependence of the CR spectral index recently inferred from Fermi-LAT measurements in the inner GP. We find that, in this scenario, the bulk of the Galactic ridge emission can be naturally explained by the interaction of the diffuse, steady-state Galactic CR sea interacting with the gas present in the Central molecular zone. The evidence of a GC PeVatron is significantly weaker than that inferred adopting a conventional (softer) CR sea.Comment: Oral contribution to the International Cosmic Ray Conference (ICRC 2017), 12-20 July 2017, Bexco, Busan, Kore