25 research outputs found

    In Situ Spectral Magnetoellipsometry for Structural, Magnetic and Optical Properties of Me/Si (Me Mn, Fe) Nanolayers

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    In our work we present in-situ spectral magnetoellipsometer is equipped with sapphire manipulator. which allows us to carry out in-situ and in-time optical and magnetooptical measurements in the range from 10 K to 1500 K in spectral range 1.5 eV-4.0 eV (830 nm-300 nm), the range of magnetic fields is +/-0.4 T. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3555

    ΠžΡΠΎΠ±Π΅Π½Π½ΠΎΡΡ‚ΠΈ Ρ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€Π½Ρ‹Ρ… элСктромагнитных ΠΊΠΎΠ»Π΅Π±Π°Π½ΠΈΠΉ ΠΏΠ»Π°Π·ΠΌΠ΅Π½Π½Ρ‹Ρ… сгустков Π² Π΄Π»ΠΈΠ½Π½ΠΎΠΌ ΠΏΡ€ΠΎΠ±ΠΊΠΎΡ‚Ρ€ΠΎΠ½Π΅

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    The aim of this work was to study the spectrum of LF and HF oscillations generated by plasma bunches created and confined in the volume of a microwave cavity immersed in the magnetic field of a mirror trap. The registration of electrostatic oscillations in the plasma was carried out using two flat electrodes mounted diametrically opposite in the central part of the cavity close to its wall. This diagnostic showed the presence of low-frequency oscillations with frequencies of 130 kHz and 450 kHz. The oscillation spectrum in the microwave range was recorded at the minimum of the magnetic trap using a real-time spectrometer and a loosely coupled loop antenna. The registration of the spectra in the 40 MHz band revealed a regular change in the frequency of the fundamental oscillation mode of the cavity and the presence of two harmonics of the synchrotron radiation of the plasma bunch at frequencies of 2.25 GHz and 4.52 GHz, respectively. According to the obtained data, the parameters of the formed bunch (density, shape, volume, energy spectra of plasma components) can be restored.ЦСлью Π΄Π°Π½Π½ΠΎΠΉ Ρ€Π°Π±ΠΎΡ‚Ρ‹ являлось ΠΈΠ·ΡƒΡ‡Π΅Π½ΠΈΠ΅ спСктра НЧ ΠΈ Π’Π§ ΠΊΠΎΠ»Π΅Π±Π°Π½ΠΈΠΉ Π³Π΅Π½Π΅Ρ€ΠΈΡ€ΡƒΠ΅ΠΌΡ‹Ρ… ΠΏΠ»Π°Π·ΠΌΠ΅Π½Π½Ρ‹ΠΌΠΈ сгустками, создаваСмыми ΠΈ ΡƒΠ΄Π΅Ρ€ΠΆΠΈΠ²Π°Π΅ΠΌΡ‹ΠΌΠΈ Π² Ρ€Π°Π±ΠΎΡ‡Π΅ΠΌ объСмС высокочастотного Ρ€Π΅Π·ΠΎΠ½Π°Ρ‚ΠΎΡ€Π°, находящСгося Π² ΠΌΠ°Π³Π½ΠΈΡ‚Π½ΠΎΠΌ ΠΏΠΎΠ»Π΅ Π·Π΅Ρ€ΠΊΠ°Π»ΡŒΠ½ΠΎΠΉ Π»ΠΎΠ²ΡƒΡˆΠΊΠΈ. РСгистрация элСктростатичСских ΠΊΠΎΠ»Π΅Π±Π°Π½ΠΈΠΉ Π² ΠΏΠ»Π°Π·ΠΌΠ΅ ΠΎΡΡƒΡ‰Π΅ΡΡ‚Π²Π»ΡΠ»ΠΎΡΡŒ ΠΏΡ€ΠΈ ΠΏΠΎΠΌΠΎΡ‰ΠΈ Π΄Π²ΡƒΡ… плоских элСктродов установлСнных Π΄ΠΈΠ°ΠΌΠ΅Ρ‚Ρ€Π°Π»ΡŒΠ½ΠΎ ΠΏΡ€ΠΎΡ‚ΠΈΠ²ΠΎΠΏΠΎΠ»ΠΎΠΆΠ½ΠΎ Π² Ρ†Π΅Π½Ρ‚Ρ€Π°Π»ΡŒΠ½ΠΎΠΉ части Ρ€Π΅Π·ΠΎΠ½Π°Ρ‚ΠΎΡ€Π° Π² Π΅Π³ΠΎ пристСночной области. Π­Ρ‚Π° диагностика ΠΏΠΎΠΊΠ°Π·Π°Π»Π° Π½Π°Π»ΠΈΡ‡ΠΈΠ΅ низкочастотных ΠΊΠΎΠ»Π΅Π±Π°Π½ΠΈΠΉ с частотами 130 ΠΊΠ“Ρ† ΠΈ 450 ΠΊΠ“Ρ†. Π‘ΠΏΠ΅ΠΊΡ‚Ρ€ ΠΊΠΎΠ»Π΅Π±Π°Π½ΠΈΠΉ Π² Π‘Π’Π§ Π΄ΠΈΠ°ΠΏΠ°Π·ΠΎΠ½Π΅ рСгистрировался Π² ΠΌΠΈΠ½ΠΈΠΌΡƒΠΌΠ΅ ΠΌΠ°Π³Π½ΠΈΡ‚Π½ΠΎΠΉ Π»ΠΎΠ²ΡƒΡˆΠΊΠΈ ΠΏΡ€ΠΈ ΠΏΠΎΠΌΠΎΡ‰ΠΈ спСктромСтра Ρ€Π΅Π°Π»ΡŒΠ½ΠΎ Π²Ρ€Π΅ΠΌΠ΅Π½ΠΈ ΠΈ слабо связанной ΠΏΠ΅Ρ‚Π»Π΅Π²ΠΎΠΉ Π°Π½Ρ‚Π΅Π½Π½Ρ‹. РСгистрация спСктров Π² полосС 40 ΠœΠ“Ρ† ΠΏΠΎΠ·Π²ΠΎΠ»ΠΈΠ»Π° Π²Ρ‹ΡΠ²ΠΈΡ‚ΡŒ Π·Π°ΠΊΠΎΠ½ΠΎΠΌΠ΅Ρ€Π½ΠΎΠ΅ ΠΈΠ·ΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ частоты основной ΠΌΠΎΠ΄Ρ‹ ΠΊΠΎΠ»Π΅Π±Π°Π½ΠΈΠΉ Ρ€Π΅Π·ΠΎΠ½Π°Ρ‚ΠΎΡ€Π° ΠΈ Π½Π°Π»ΠΈΡ‡ΠΈΠ΅ Π΄Π²ΡƒΡ… Π³Π°Ρ€ΠΌΠΎΠ½ΠΈΠΊ синхротронного излучСния ΠΏΠ»Π°Π·ΠΌΠ΅Π½Π½ΠΎΠ³ΠΎ сгустка Π½Π° частотах 2.25 Π“Π“Ρ† ΠΈ 4.52 Π“Π“Ρ† соотвСтствСнно. По ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½Π½Ρ‹ΠΌ Π΄Π°Π½Π½Ρ‹ΠΌ ΠΌΠΎΠ³ΡƒΡ‚ Π±Ρ‹Ρ‚ΡŒ восстановлСны ΠΏΠ°Ρ€Π°ΠΌΠ΅Ρ‚Ρ€Ρ‹ сформированного сгустка (ΠΏΠ»ΠΎΡ‚Π½ΠΎΡΡ‚ΡŒ, Ρ„ΠΎΡ€ΠΌΠ°, объСм, энСргСтичСскиС спСктры ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½Ρ‚ ΠΏΠ»Π°Π·ΠΌΡ‹)

    PHENYLATION OF BETA-PICOLINE ISOLATION AND STRUCTURAL ASSIGNMENT OF BETA-PYRIDYL-ALPHA-DEHYDROPIPERIDINE

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    The phenylation of 3Ξ²picoline. Isolation and establishment of the structure of Ξ²-pyridyl-Ξ±-dehydropiperidine

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    It was established that the side product that is formed in substantial amounts in the phenylation of Ξ²-picoline by phenyllithium is 3-methyl-2-phenyl-5-(3-methyl-2-phenyl-3,4-dehydropiperidyl-6)pyridine - a structural analog of anabasine. Its structure was demonstrated by spectral methods and by chemical conversions. Β© 1985 Plenum Publishing Corporation

    PHENYLATION OF BETA-PICOLINE ISOLATION AND STRUCTURAL ASSIGNMENT OF BETA-PYRIDYL-ALPHA-DEHYDROPIPERIDINE

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    The phenylation of 3Ξ²picoline. Isolation and establishment of the structure of Ξ²-pyridyl-Ξ±-dehydropiperidine

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    It was established that the side product that is formed in substantial amounts in the phenylation of Ξ²-picoline by phenyllithium is 3-methyl-2-phenyl-5-(3-methyl-2-phenyl-3,4-dehydropiperidyl-6)pyridine - a structural analog of anabasine. Its structure was demonstrated by spectral methods and by chemical conversions. Β© 1985 Plenum Publishing Corporation

    10-Sila-2-azaanthracenes hydrogenated in the pyridine fragment

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    The corresponding 1,2,3,4,4a, 9,9a, 10-octahydro derivatives were obtained in the catalytic hydrogenation of 10,10-dimethyl- and 10-methyl-10-phenyl-9,10-dihydro-10-sila-2-azaanthracenes. The hydrogenation of 10,10-dimethyl-10-sila-2-azaanthrone also leads to a substituted octahydrosilaazaanthracene. Isomeric (with respect to the position of the double bond in the nitrogen-containing ring) hexahydrosilaaza-9-anthrols were isolated as a result of the reduction of the methiodide of this silaazaanthrone with sodium borohydride. Β© 1991 Plenum Publishing Corporation
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