27 research outputs found
Anion-π interactions—interactions between benzo-crown ether metal cation complexes and counter ions
A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)(7)Al(OH)(6)Mo6O18](n)center dot 4nH(2)O
The structure of the complex [La(H2O)7Al(OH)6Mo6O18]n·4nH2O is the first example of a 1D extended chain in which an Anderson type heteropolyanion is linked by rare earth metal ions in zig-zag chains that arrange "head to tail" in the structure; furthermore the chains are themselves linked into an extensive three-dimensional hydrogen bonded network
Evaluation of in vitro antioxidant, antidiabetic activities and GC-MS analysis from Amomum nilgiricum leaf extract
Organic-Inorganic Hybrids Constructed of Anderson-Type Polyoxoanions and Oxalato-Bridged Dinuclear Copper Complexes
Supermolecular Architecture of a Polypseudo-rotaxane: [Cd(BPE)(a-Mo8O26)][Cd(BPE)(DMF)4]2DMF (BPE = 1, 2-Bis(4-pyridyl)ethane, DMF = N, N-Dimethylformamide)
New Inorganic Helical Chain: Synthesis, Structure, Characterization, and Interconversion of BaGa 2
Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry
The unsymmetrical Mn-Anderson polyoxometalate cluster, [N(C4H9)(4)](3)[MnMo6O18(C4H6O3NO2)(C4H6O3NH2)] (1; N(C4H9)(4)(+) = TBA(+)), has been prepared and characterized by X-ray crystallography and electrospray ionization mass spectrometry (ESI-MS). Covalent functionalization of compound 1 leads to the controlled assemblies of unsymmetrical alkoxopolyoxometalate clusters of compounds 2-5, which can be directly observed in solution as revealed by ESI-MS studies