27 research outputs found

    A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)(7)Al(OH)(6)Mo6O18](n)center dot 4nH(2)O

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    The structure of the complex [La(H2O)7Al(OH)6Mo6O18]n·4nH2O is the first example of a 1D extended chain in which an Anderson type heteropolyanion is linked by rare earth metal ions in zig-zag chains that arrange "head to tail" in the structure; furthermore the chains are themselves linked into an extensive three-dimensional hydrogen bonded network

    Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry

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    The unsymmetrical Mn-Anderson polyoxometalate cluster, [N(C4H9)(4)](3)[MnMo6O18(C4H6O3NO2)(C4H6O3NH2)] (1; N(C4H9)(4)(+) = TBA(+)), has been prepared and characterized by X-ray crystallography and electrospray ionization mass spectrometry (ESI-MS). Covalent functionalization of compound 1 leads to the controlled assemblies of unsymmetrical alkoxopolyoxometalate clusters of compounds 2-5, which can be directly observed in solution as revealed by ESI-MS studies
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