HYDROPHOBIC COATINGS BASED ON COMMERCIAL PERFLUOROPOLYETHERS FOR FOULING MITIGATION. APPROACH ON A PILOT HEAT EXCHANGER PLANT

This work concerns the mitigation of fouling in heat exchangers, by means of the modification of the interaction between the foulant particles and the solid surfaces involved in the fouling phenomenon. To achieve this goal, hydrophobic coatings containing commercial perfluoropolyethers (PFPE) and metal oxides were prepared. Specifically, three typologies of coatings were prepared for the protection of stainless steel surfaces: commercial \u3b1,\u3c9-inorganic substituted PFPE coatings, multilayer coatings containing the commercial PFPE and metal oxides nanopowders, and hybrid coatings containing sol-gel metal oxides networks and the commercial PFPE. All the coatings prepared were fully characterized in order to assess their morphology, composition and thickness. The wettability of the coatings was measured by contact angle (CA) determination, and all the coatings resulted to be hydrophobic, with CA>120\ub0. The chemical and mechanical stability of all the coatings prepared was investigated by means of particular resistance tests, performed in liquid environments. Hybrid coatings appeared as the most resistant coatings against the erosion induced by chemical aggressive liquids, high temperature liquids (343 K), or shear stresses induced by the flowing of water upon the coated surface (0.17 m/s). The experimentation on a heat exchanger pilot plant confirmed the ability of the hydrophobic hybrid coatings to mitigate crystallization fouling on stainless steel heat transfer surfaces. In the condition adopted (transient flow regime and heat exchanging fluids at temperatures of 291-293 K and 318-323 K), the hybrid coating was able to delay the fouling step of about 200 hours and to promote the removal of the fouling deposits progressively formed on the heat transfer surfaces

Use of a sol-gel hybrid coating composed by a fluoropolymer and silica for the mitigation of mineral fouling in heat exchangers

The technology of the organic/inorganic hybrid coating was employed in the preparation of a hydrophobic coating (contact angle higher than 140\ub0) for fouling mitigation on stainless steel heat transfer surfaces. A commercial triethoxysilane perfluoropolyethers was combined with a sol-gel silica network with the aim to increase the mechanical and thermal resistance of the films when exposed to aggressive liquid environments as the heat exchanging fluids. The experimentation on a shell and tube heat exchanger pilot plant confirmed the ability of the hybrid coating to prolong the crystallization fouling induction period of 200 h in respect to an uncoated heat exchanger, operating in the same conditions. Moreover, the fouling particles deposited on the coated heat transfer surfaces had only slight adhesion strength toward the coated surfaces and were easily removed by inducing higher wall shear stresses inside the tubes of the plant

Interstellar Comet 2I/Borisov exhibits a structure similar to native Solar System comets

We processed images taken with the Hubble Space Telescope (HST) to investigate any morphological features in the inner coma suggestive of a peculiar activity on the nucleus of the interstellar comet 2I/Borisov. The coma shows an evident elongation, in the position angle (PA) ~0-180d direction, which appears related to the presence of a jet originating from a single active source on the nucleus. A counterpart of this jet directed towards PA ~10d was detected through analysis of the changes of the inner coma morphology on HST images taken in different dates and processed with different filters. These findings indicate that the nucleus is probably rotating with a spin axis projected near the plane of the sky and oriented at PA ~100d-280d, and that the active source is lying in a near-equatorial position. Subsequent observations of HST allowed us to determine the direction of the spin axis at RA=17h20m+/-15d and Dec = -35d+\-10d.Comment: 5 pages, 6 figures (low resolution). Full-resolution figures and bonus material at this url https://web.oapd.inaf.it/bedin/files/PAPERs_eMATERIALs/BORISOV_comet/ Accepted for publication in MNRAS Letters on 2020 April 1st (not a joke ;

Perfluoropolyethers coatings design for fouling reduction on heat transfer stainless steel surfaces

The scope of this research is to obtain a film coating on stainless steel surfaces in order to reduce the interaction between the metal surface and the precipitates, so to mitigate fouling in heat exchangers. Perfuoropolyethers were used to obtain nano-range fluorinated layers in order to make hydrophobic the stainless steel surfaces. A pilot plant with two identical heat exchangers was built to investigate the ability of the hydrophobic coating of preventing fouling. The heat exchangers, installed in parallel, operated at the same temperature and pressure conditions, i.e. laminar flow regime and inlet flow temperatures of 291\u2013293 K for cold streams and 313\u2013333 K for hot streams. We compared the heat transfer performance of the two heat exchangers. After a five months operation the decrease in the heat transferred was 56% for the coated heat exchanger and 62% for the uncoated heat exchanger. Moreover, the increase of heat transfer resistance due to scale on the uncoated heat exchanger, with respect to the coated one, was three times higher

Reinforcement of perfluoropolyethers coatings by ceramic oxides sol-gels for fouling mitigation on metal surfaces

In this research we developed a coating formulation containing \u3b1,\u3c9-substituted perfluoropolyethers (PFPE) and ceramic oxides sol-gels, for fouling mitigation on solid surfaces. Micrometer coatings where obtained on metal substrates by dip-coating procedure; they showed hydrophobic behavior (CA>130\ub0) and low CA hysteresis. The coatings resistance against shear stresses and chemicals increased thanks to the high mechanical properties of the ceramic oxides, compared to a simple PFPE coating. The ability of the coatings to mitigate particulate fouling was preliminary confirmed in presence of CaSO4 in an appropriate test rig. Motivations and Objectives One potential application of hydrophobic coatings concerns fouling mitigation. It has been demonstrated that low energy surfaces are able to influence the mechanism of deposition and removal of fouling particles on heat transfer surfaces, increasing the fouling induction period of the heat exchangers [1]. This research aims to develop a hydrophobic organic-inorganic coating, combining a PFPE with a sol-gel network obtained from the hydrolysis of tetraethylorthosilicate (OTES) or Zr-n-propoxide, in order to improve the mechanical properties of the final coatings. The investigation focuses the attention on the important coatings parameters for a possible application on heat transfer surfaces, i.e., thickness, thermal resistance, surface roughness and chemical and physical resistance. Fouling mitigation ability of the coatings is assessed in particulate fouling conditions, in a specific test rig. Hydrophobic coatings were obtained by formulating in iso-propanol a commercial PFPE (Fluorolink\uaeS10) with SiO2 or ZrO2 sol-gels, at different weight proportion (80/20, 1/05 and 1/1 respectively). The coatings resistance was investigated against erosion induced by liquid environments and shear stresses induced by a water flow. Compared to a simple PFPE coating, the resistance against shear stresses and aggressive environments increased of the 90%. Fouling mitigation ability of coatings deposited on the internal surfaces of a stainless steel tube, was assessed in presence of a CaSO4 solution (4 g/L), flowed inside a coated tube (temperature=40\ub0C, flowrate= 1.5 m/s). Thanks to the hydrophobic coating, the foulants deposition is 95% lower in respect to an uncoated surface

Neurometabolic changes in a rat pup model of type C hepatic encephalopathy depend on age at liver disease onset.

Chronic liver disease (CLD) is a serious condition where various toxins present in the blood affect the brain leading to type C hepatic encephalopathy (HE). Both adults and children are impacted, while children may display unique vulnerabilities depending on the affected window of brain development.We aimed to use the advantages of high field proton Magnetic Resonance Spectroscopy ( <sup>1</sup> H MRS) to study longitudinally the neurometabolic and behavioural effects of Bile Duct Ligation (animal model of CLD-induced type C HE) on rats at post-natal day 15 (p15) to get closer to neonatal onset liver disease. Furthermore, we compared two sets of animals (p15 and p21-previously published) to evaluate whether the brain responds differently to CLD according to age onset.We showed for the first time that when CLD was acquired at p15, the rats presented the typical signs of CLD, i.e. rise in plasma bilirubin and ammonium, and developed the characteristic brain metabolic changes associated with type C HE (e.g. glutamine increase and osmolytes decrease). When compared to rats that acquired CLD at p21, p15 rats did not show any significant difference in plasma biochemistry, but displayed a delayed increase in brain glutamine and decrease in total-choline. The changes in neurotransmitters were milder than in p21 rats. Moreover, p15 rats showed an earlier increase in brain lactate and a different antioxidant response. These findings offer tentative pointers as to which neurodevelopmental processes may be impacted and raise the question of whether similar changes might exist in humans but are missed owing to <sup>1</sup> H MRS methodological limitations in field strength of clinical magnet

Reinforcement of perfluoropolyethers coatings by ceramic oxides sol-gels for fouling mitigation on metal surfaces

In this research we developed a coating formulation containing \u3b1,\u3c9-substituted perfluoropolyethers (PFPE) and ceramic oxides sol-gels, for fouling mitigation on solid surfaces. Micrometer coatings where obtained on metal substrates by dip-coating procedure; they showed hydrophobic behavior (CA>130\ub0) and low CA hysteresis. The coatings resistance against shear stresses and chemicals increased thanks to the high mechanical properties of the ceramic oxides, compared to a simple PFPE coating. The ability of the coatings to mitigate particulate fouling was preliminary confirmed in presence of CaSO4 in an appropriate test rig. Motivations and Objectives One potential application of hydrophobic coatings concerns fouling mitigation. It has been demonstrated that low energy surfaces are able to influence the mechanism of deposition and removal of fouling particles on heat transfer surfaces, increasing the fouling induction period of the heat exchangers [1]. This research aims to develop a hydrophobic organic-inorganic coating, combining a PFPE with a sol-gel network obtained from the hydrolysis of tetraethylorthosilicate (OTES) or Zr-n-propoxide, in order to improve the mechanical properties of the final coatings. The investigation focuses the attention on the important coatings parameters for a possible application on heat transfer surfaces, i.e., thickness, thermal resistance, surface roughness and chemical and physical resistance. Fouling mitigation ability of the coatings is assessed in particulate fouling conditions, in a specific test rig. Hydrophobic coatings were obtained by formulating in iso-propanol a commercial PFPE (Fluorolink\uaeS10) with SiO2 or ZrO2 sol-gels, at different weight proportion (80/20, 1/05 and 1/1 respectively). The coatings resistance was investigated against erosion induced by liquid environments and shear stresses induced by a water flow. Compared to a simple PFPE coating, the resistance against shear stresses and aggressive environments increased of the 90%. Fouling mitigation ability of coatings deposited on the internal surfaces of a stainless steel tube, was assessed in presence of a CaSO4 solution (4 g/L), flowed inside a coated tube (temperature=40\ub0C, flowrate= 1.5 m/s). Thanks to the hydrophobic coating, the foulants deposition is 95% lower in respect to an uncoated surface

Coma morphology and dust emission pattern of comet C/2020 F3 (NEOWISE)

The recent close approach of comet C/2020 F3 (NEOWISE) allowed us to study the morphology of its inner coma. From the measurement of the dust ejection velocity on spiral structures expanding around the nucleus, we estimated a mean deprojected expansion velocity Vd = 1.11 ± 0.08 km s-1. Assuming that a new shell formed after every rotation of the comet, a period of 7.8 ± 0.2 h was derived. The spin axis orientation was estimated at RA 210° ± 10°, Dec. +35° ± 10°. The coma morphology appears related to two strong, diametrically opposite emissions located at mid-latitudes on the nucleus. A qualitative modelling of the coma produced consistent results with a wide range of dust sizes (0.80-800 μm), with inversely correlated densities (0.003-3.0 g cm-3). Images taken with Vj and r-Sloan filters showed a greater concentration of dust in the first two shells, and an increasing density of radicals emitting in the B and V band passes from the third shell outwards. Striae-like structures in the tail suggest that dust particles have different sizes

Exploring characteristics associated with first benzodiazepine prescription in patients with affective disorders and related diagnoses

Objective In patients with affective disorders, benzodiazepines (BZDs) are frequently administered at the onset, sometimes inappropriately. We sought to identify clinical variables associated with first BZD prescription in a large sample of patients with affective disorders. Methods Four hundred sixty patients with mood or anxiety disorders attending different psychiatric services were assessed comparing those who received BZD as first treatment (BZD w/) and those who did not (BZD w/o). Results More than one third (35.7%) of the total sample had received BZDs as first prescription. In relation to mood disorders, BZD w/ subjects more frequently (a) had not a psychiatrist as first therapist, (b) had anxious symptoms at onset, (c) had adjustment disorder as first diagnosis, (d) were treated as outpatients. In relation to specific diagnoses, (a) personal decision of treatment for major depressive disorder, (b) outpatient status for bipolar disorder and (c) longer duration of untreated illness for adjustment disorder were more frequently associated with first BZD prescription. For anxiety disorders, the presence of stressful life events and the diagnoses of panic disorder or specific phobias were more frequently observed in BZD w/ patients. Conclusion Patients with affective disorders frequently received BZDs as first prescription with significant differences between and within mood and anxiety disorders

Photoactive TiO2-montmorillonite composite for degradation of organic dyes in water

TiO2\u2013montmorillonite composite (TiO2\u2013M) was prepared by impregnation with TiCl4 followed by calcination at 350 C. The synthesized material was characterized by FTIR, TG\u2013DTA, BET, XRD and SEM\u2013 EDX. The results show that TiO2 was efficiently formed in Na\u2013montmorillonite (Na\u2013M) framework, and only a crystalline, pure anatase phase was produced. Photoactivity tests were carried out under UV-A irradiation using five selected organic dyes. The results indicate that the activity of TiO2\u2013M is more important for cationic dyes, where the removal rates are in the order: crystal violet (97.1%) > methylene blue (93.20%) > rhodamine B (79.8%) > methyl orange (36.1%) > Congo red (22.6%). The results of the TiO2\u2013 M activity were compared with that of the commercial P25. The comparison demonstrates that the synthesized TiO2\u2013M exhibits a higher adsorptive behavior and can be used as low-cost alternative to the commercial TiO2 for wastewater treatment, showing also an extreme easiness to completely recover the composite catalyst at the end of the test