Study of olivines from Omolon and Seymchan meteorites using X-ray diffraction and Mössbauer spectroscopy with a high velocity resolution

Study of olivine from Omolon and Seymchan meteorites was performed using X-ray diffraction and Mössbauer spectroscopy with a high velocity resolution. X-ray diffraction patterns were measured at room temperature while Mössbauer spectra were measured at 295 and 90 K. The orthorhombic crystal lattice parameters were evaluated for olivine from Omolon and Seymchan. These parameters appeared to be different for olivines from both meteorites. Mössbauer spectral components related to 57Fe in crystallographically non-equivalent sites M1 and M2 in both olivines were determined and its Mössbauer hyperfine parameters were evaluated. Some differences in the tendencies of temperature dependence of spectral parameters and small variations of 57Fe quadrupole splitting in both M1 and M2 sites of olivines from Omolon and Seymchan were found. On the basis of Mössbauer parameters and chemical data, the temperatures of equilibrium cation distribution were evaluated for both olivines. © 2012 American Institute of Physics

THE INVESTIGATION OF DIATOMS DEMONSTRATING DEATH CAUSED BY DROWNING

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Preparation and characterization of Bi26–2xMn2xMo10O69-d and Bi26.4Mn0.6Mo10–2yMe2yO69-d(Me = V, Fe) solid solutions

Received: 06.06.2017; accepted: 23.06.2017; published: 14.07.2017.Single phase samples of bismuth molybdate, Bi26Mo10O69, doped with Mn on the bismuth sublattice and V, Fe on the molybdenum sublattice were found to crystallize in the triclinic Bi26Mo10O69 structure at low doping levels and in the monoclinic Bi26Mo10O69 structure - at higher dopant concentration. The assumption that all Mn ions have an oxidation state of +2 was confirmed by means of magnetic measurement results analysis using Curie-Weiss law. Conductivity was investigated using impedance spectroscopy. The conductivity of Bi26.4Mn0.6Mo9.6Fe0.4O69-d was 1.2*10-2 S*cm-1 at 973 K and 2.2*10-4 S*cm-1 at 623 K, and the conductivity of Bi26.4Mn0.6Mo9.2V0.8O69-d was 2.2*10-3 S*cm-1 at 973 K and 2.2*10-5 S*cm-1 at 623 K

Sociology, labour and transition in post-Soviet Russia: A view from within

For almost 20 years, since the early 1990s, Professor Simon Clarke led multiple international research projects in Russia, China and Vietnam studying labour relations, enterprise restructuring and household economics under post-socialist transition. Breaking out of post-socialist scholarship’s narrow confines, both social and ideological, he led an exploration of the void opened by former Soviet Union disintegration reconnecting with those who brought the brunt of it. Equally unique among western scholars was his promotion of a vast network of former Soviet Union researchers and activists, later formalised in the Institute for Comparative Research in Labour Relations. Here, for the first time, some of its leading scholars reflect on his legacy, methods and ever-lasting contribution to the advancement of sociology and social activism in Russia. Their accounts convey the radically alternative character of the overall project, returning both achievements and limitations. In substantive terms, the emerging picture confirms the indeterminacy and complexity of Clarke’s original findings: no linear development from ‘the subsumption of labour under capital’ to ‘familiar patterns of class conflict’ has occurred. Instead, growing labour protests follow labour degradation and restructuring, a strong state becoming the arbiter in the stand-off between neoliberalism and workers’ resistance

Interplay between lattice, orbital, and magnetic degrees of freedom in the chain-polymer Cu(II) breathing crystals

The chain-polymer Cu(II) breathing crystals C21H19CuF12N4O6 were studied using the x-ray diffraction and ab initio band structure calculations. We show that the crystal structure modification at T=146 K, associated with the spin crossover transition, induces the changes of the orbital order in half of the Cu sites. This in turn results in the switch of the magnetic interaction sign in accordance with the Goodenough-Kanamori-Andersen theory of the coupling between the orbital and spin degrees of freedom.Comment: 6 pages, 7 figure

Modern Technologies of Working with Families of Children with Disabilities

AbstractThe authors research the problems of families having children with mental retardation and autism spectrum disorder (ADS), from the point of view of their socialization. The following key spheres of the socialization process are identified: activities, communication, self-awareness. In the authors’ opinion, work with this category of families should be conducted with consideration of these spheres