432 research outputs found

    On the Initial-Value Problem to the Quantum Dual BBGKY Hierarchy

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    We develop a rigorous formalism for the description of the evolution of observables in quantum systems of particles. We construct a solution of the initial-value problem to the quantum dual BBGKY hierarchy of equations as an expansion over particle clusters whose evolution are governed by the corresponding-order dual cumulant (dual semi-invariant) of the evolution operators of finitely many particles. For initial data from the space of sequences of bounded operators the existence and uniqueness theorem is proved.Comment: 22 page

    Quantum Kinetic Evolution of Marginal Observables

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    We develop a rigorous formalism for the description of the evolution of observables of quantum systems of particles in the mean-field scaling limit. The corresponding asymptotics of a solution of the initial-value problem of the dual quantum BBGKY hierarchy is constructed. Moreover, links of the evolution of marginal observables and the evolution of quantum states described in terms of a one-particle marginal density operator are established. Such approach gives the alternative description of the kinetic evolution of quantum many-particle systems to generally accepted approach on basis of kinetic equations.Comment: 18 page

    Towards Rigorous Derivation of Quantum Kinetic Equations

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    We develop a rigorous formalism for the description of the evolution of states of quantum many-particle systems in terms of a one-particle density operator. For initial states which are specified in terms of a one-particle density operator the equivalence of the description of the evolution of quantum many-particle states by the Cauchy problem of the quantum BBGKY hierarchy and by the Cauchy problem of the generalized quantum kinetic equation together with a sequence of explicitly defined functionals of a solution of stated kinetic equation is established in the space of trace class operators. The links of the specific quantum kinetic equations with the generalized quantum kinetic equation are discussed.Comment: 25 page

    The von Neumann Hierarchy for Correlation Operators of Quantum Many-Particle Systems

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    The Cauchy problem for the von Neumann hierarchy of nonlinear equations is investigated. One describes the evolution of all possible states of quantum many-particle systems by the correlation operators. A solution of such nonlinear equations is constructed in the form of an expansion over particle clusters whose evolution is described by the corresponding order cumulant (semi-invariant) of evolution operators for the von Neumann equations. For the initial data from the space of sequences of trace class operators the existence of a strong and a weak solution of the Cauchy problem is proved. We discuss the relationships of this solution both with the ss-particle statistical operators, which are solutions of the BBGKY hierarchy, and with the ss-particle correlation operators of quantum systems.Comment: 26 page

    Hydrodynamic Equations for Microscopic Phase Densities

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    The evolution equations for the generalized microscopic phase densities are introduced. The evolution equations of average values of microscopic phase densities are derived and a solution of the initial-value problem of the obtained hydrodynamic type hierarchy is constructed.Comment: 4 page

    On Rigorous Derivation of the Enskog Kinetic Equation

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    We develop a rigorous formalism for the description of the kinetic evolution of infinitely many hard spheres. On the basis of the kinetic cluster expansions of cumulants of groups of operators of finitely many hard spheres the nonlinear kinetic Enskog equation and its generalizations are justified. It is established that for initial states which are specified in terms of one-particle distribution functions the description of the evolution by the Cauchy problem of the BBGKY hierarchy and by the Cauchy problem of the generalized Enskog kinetic equation together with a sequence of explicitly defined functionals of a solution of stated kinetic equation is an equivalent. For the initial-value problem of the generalized Enskog equation the existence theorem is proved in the space of integrable functions.Comment: 28 page

    And yet it moves: Recovery of volitional control after spinal cord injury

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    Preclinical and clinical neurophysiological and neurorehabilitation research has generated rather surprising levels of recovery of volitional sensory-motor function in persons with chronic motor paralysis following a spinal cord injury. The key factor in this recovery is largely activity-dependent plasticity of spinal and supraspinal networks. This key factor can be triggered by neuromodulation of these networks with electrical and pharmacological interventions. This review addresses some of the systems-level physiological mechanisms that might explain the effects of electrical modulation and how repetitive training facilitates the recovery of volitional motor control. In particular, we substantiate the hypotheses that: (1) in the majority of spinal lesions, a critical number and type of neurons in the region of the injury survive, but cannot conduct action potentials, and thus are electrically non-responsive; (2) these neuronal networks within the lesioned area can be neuromodulated to a transformed state of electrical competency; (3) these two factors enable the potential for extensive activity-dependent reorganization of neuronal networks in the spinal cord and brain, and (4) propriospinal networks play a critical role in driving this activity-dependent reorganization after injury. Real-time proprioceptive input to spinal networks provides the template for reorganization of spinal networks that play a leading role in the level of coordination of motor pools required to perform a given functional task. Repetitive exposure of multi-segmental sensory-motor networks to the dynamics of task-specific sensory input as occurs with repetitive training can functionally reshape spinal and supraspinal connectivity thus re-enabling one to perform complex motor tasks, even years post injury

    New approach to N,N-dialkoxy-N'-arylureas and N,N-dialkoxycarbamates

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    Methanolysis of N-chloro-N-alkoxy-N'-arylureas in the presence of silver trifluoroacetate gives the corresponding N,N-dialkoxy-N'‑arylureas, whereas N-chloro-N-alkoxycarbamates react with alcohols in the presence of silver trifluoroacetate to afford N,N-dialkoxycarbamates
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