Deep-seated gravitational slope deformations in central Sardinia: insights into the geomorphological evolution

In this study, we analyse deep-seated gravitational slope deformations (DSGSDs) in central Sardinia. The area is characterised by plateaus with a prominent limestone scarp overlying metamorphites. A comprehensive mapping of structural, karst, fluvial, and slope morphologies in Pardu and Ulassai valleys is presented herein. The uplift linked to the Plio-Pleistocene tectonic activity leads to high-slope topography, which favours gravitational processes, such as DSGSDs and rock-avalanches. Although DSGSD is a common phenomenon in the relief of the central Mediterranean region, it has never been studied in Sardinia. We describe the kinematic models and geomorphological evolution of DSGSD in Sardinia for the first time. The application of light detection and ranging, high-resolution unmanned aerial vehicle photogrammetry, and geological, structural, and geomorphological surveys enabled a depth morphometric analysis and the development of interpretative three-dimensional models. The geo-structural setting and high relief energy associated with recent upliftment are the major controlling factors of DSGSDs

Evolution of deep-seated gravitational slope deformations in relation with uplift and fluvial capture processes in Central Eastern Sardinia (Italy)

Connections between Plio-Pleistocenic tectonic activity and geomorphological evolution were studied in the Pardu Valley and Quirra Valley (Ogliastra, East Sardinia). The intensive Quaternary tectonic activity in Sardinia linked to the opening of the Tyrrhenian Basin is known. In Eastern Sardinia, it manifests with an uplift that is recorded by geomorphological indicators, such as deep-seated gravitational slope deformation, fluvial captures, engraved valleys, waterfalls, and heterogeneous water drainage. The Pardu River flows from the NW toward the SE and then abruptly changes direction toward the NE. At this point, a capture elbow adjacent to the current head of the Quirra River is well developed. The Quirra River, in its upstream part, flows at altitudes approximately 200 m higher than the Pardu River. It also shows an oversized and over-flooded valley with respect to the catchment area upstream. This setting indicates that the Pardu River, which previously flowed south along the Quirra River, was captured by the Pelau River. We analyzed long-term landslides with lateral spreading and sackung characteristics, which involve giant carbonate blocks and underlying foliated metamorphites in both valleys. The use of LiDAR, high-resolution uncrewed aerial vehicle digital photogrammetry (UAV-DP), and geological, structural, and geomorphological surveys enabled a depth morphometric analysis and the creation of interpretative 3D models of DGSDs. Space-borne interferometric synthetic aperture radar (InSAR) data using ERS and Sentinel-1 satellites identified downslope movement of up to 20 mm per year in both Pardu Valley flanks. Multi-source and multi-scale data showed that the state of activity of the DGSDs is closely linked to the geomorphological evolution of the catchment areas of the Rio Pardu and Rio Quirra. The intense post-capture erosion acted in the Rio Pardu Valley, giving it morphometric characteristics that were favorable to the current evolution of the DGSDs, while the Rio Quirra Valley presents paleo-DGSDs that have been fossilized by pre-capture terraced alluvial deposits

A human–AI collaboration workflow for archaeological sites detection

This paper illustrates the results obtained by using pre-trained semantic segmentation deep learning models for the detection of archaeological sites within the Mesopotamian floodplains environment. The models were fine-tuned using openly available satellite imagery and vector shapes coming from a large corpus of annotations (i.e., surveyed sites). A randomized test showed that the best model reaches a detection accuracy in the neighborhood of 80%. Integrating domain expertise was crucial to define how to build the dataset and how to evaluate the predictions, since defining if a proposed mask counts as a prediction is very subjective. Furthermore, even an inaccurate prediction can be useful when put into context and interpreted by a trained archaeologist. Coming from these considerations we close the paper with a vision for a Human–AI collaboration workflow. Starting with an annotated dataset that is refined by the human expert we obtain a model whose predictions can either be combined to create a heatmap, to be overlaid on satellite and/or aerial imagery, or alternatively can be vectorized to make further analysis in a GIS software easier and automatic. In turn, the archaeologists can analyze the predictions, organize their onsite surveys, and refine the dataset with new, corrected, annotations

The paleolandscape evolution of the southwestern coast of Sardinia (Italy) and its impact on Mesolithic settlements

We present a geomorphological map of the southwestern coast of Sardinia encompassing inland and offshore areas of the S'Omu e S'Orku Mesolithic site. The submerged area was documented by high-resolution multibeam bathymetry combined with Side-Scan Sonar data. The emerged coastal area was surveyed using Uncrewed Aerial Vehicle Remote Sensing and field surveys. The inland landforms were shaped by coastal, fluvial, and gravity-induced processes. Most of the submerged landforms appear be modeled in subaerial conditions during sea-level lowstands, and then sealed by the rising sea level. The coastal evolution has been characterized by the rapid cliff retreat facilitated intense linear erosion of watercourses, by debris flows, rockfalls and toppling. Geomorphological evidences of cliff retreat due to landslide was supported by a simplified analytic hydraulic model of the wave-cliff interaction. These processes and the sea level rise canceled any possible Mesolithic settlement along the coast. The survival of the S'Omu e S'Orku site is only due to a protected morphological position and to the distance from the Early Holocene coastline. The dearth of coastal Early Holocene prehistoric sites is likely the outcome of the presented coastal dynamics

Recent advances on innovative bioactive glass-hydroxyapatite composites for bone tissue applications: Processing, mechanical properties, and biological performance

New Hydroxyapatite-Bioactive Glass composites, xHA-(1-x)BG (x = 25, 50, and 75 wt %), are developed using HA and BGMS10 glass powders co-milled up to 2 h prior to Spark Plasma Sintering (SPS). Ball milling (BM) promoted the consolidation of HA-rich powders, whereas hindered the densification of 25HA-75BG samples. HA crystallite size is reduced from > 200 nm (unmilled) to 60 (x = 25 %) or 88 nm (x = 75 %) when using 2 h milled mixtures. Glass crystallization occurred in 75HA-25BG samples processed by SPS at 950 °C: a negligeable effect in the amount of the residual amorphous phase (12.3–13.3 wt %) is produced by BM, while changes are observed in the relative content of crystalline phases, with SiO2 increases from 8.5 to 13.1 wt %, whereas α- and β-CaSiO3 correspondingly decrease. Superior Young's modulus and Vickers hardness (130 GPa and 726, respectively) are obtained in HA rich products. Biological tests evidenced that the milling treatment does not determine negative consequences on cells viability

Geohazard features of the Southern Sardinia

The Maps of Geohazard features of Southern Sardinia produced in the framework of the Magic project (MArine Geohazard along Italian Coasts) are here presented. The MaGIC project (Marine Geohazard along the Italian Coasts) had the aim of mapping the geohazard in the Italian seas. The features were derived from the digital elevation model interpretation of the seafloor morphology and shallow sub-surface. From the marine geo-hazards point of view, the main critical elements are represented by gravitational mass processes in the canyon heads, some of which, as in the Toro Canyon, are exposed to seismic triggering. In other cases, we observed that gravitational dynamics connected to fluid leakage processes (pockforms). Large landslides and debris avalanches have been detected in Cagliari Gulf, whereas in eastern upper slope, crescent bedforms, occurring in the eastern sector of the upper slope testify to the upward migration of hyperpycnal erosional structures linked to flows from nearby river inputs

Combustion synthesis and spark plasma sintering of apatite-tricalcium phosphate nanocomposites

A processing route consisting of Spark Plasma Sintering (SPS) of precursor powders prepared by Solution Combustion Synthesis (SCS) is proposed for the first time for the fabrication of bulk nanostructured biphasic calcium phosphates. The apatite phase content in the product obtained by SCS was maximized using a fuel to oxidizer ratio of 1.1. After a post-synthesis air-annealing step conducted a 700 °C/3 h, powders consisted of 83 wt.% of carbonated apatite, with average crystallite size less than 70 nm, and β- and α-TCP (tricalcium phosphate), as secondary phases. Detailed structural analyses evidenced that the original nanostructure was retained after sintering at 900 °C, with the obtainment of nearly 91% dense, apatite-rich, biphasic bioceramics, with grains size of about 100 nm. The developed nanostructured biphasic material is expected to possess a higher resorption rate than standard microcrystalline hydroxyapatite, which makes it preferable for bone tissue regeneration

Fabrication and Characterization of Quinary High Entropy-Ultra-High Temperature Diborides” Ceramics

Due to their inherently chemical complexity and their refractory nature, the obtainment of highly dense and single-phase High Entropy (HE) diborides represents a very hard target to achieve. In this framework, homogeneous (Hf0.2Nb0.2Ta0.2Mo0.2Ti0.2)B2, (Hf0.2Zr0.2Ta0.2Mo0.2Ti0.2)B2, and (Hf0.2Zr0.2Nb0.2Mo0.2Ti0.2)B2 ceramics with high relative densities (97.4, 96.5 and 98.2 %, respectively) are successfully produced by Spark Plasma Sintering (SPS) using powders prepared by Self-propagating High-temperature Synthesis (SHS). Although the latter technique does not lead to the complete conversion of initial precursors into the prescribed HE phases, such goal is fully reached after SPS (1950°C/20min/20 MPa). The three HE products show similar, even better in some cases, mechanical properties compared to ceramics with the same nominal composition attained using alternative processing methods. Superior Vickers hardness and elastic modulus values are found for the (Hf0.2Nb0.2Ta0.2Mo0.2Ti0.2)B2 and (Hf0.2Zr0.2Ta0.2Mo0.2Ti0.2)B2 systems, i.e. 28.1 GPa/538.5 GPa and 28.08 GPa/498.1 GPa, respectively, in spite of the correspondingly higher residual po-rosities (1.2 and 2.2 vol.%, respectively). In contrast, the third ceramic, not containing Tantalum, displays lower values of these two properties (25.1 GPa/404.5 GPa). However, the corresponding fracture toughness (8.84 MPa m1/2) is relatively higher. This fact can be likely ascribed to the smaller residual porosity (0.3 vol.%) of the sintered material

Submarine Geomorphology of the Southwestern Sardinian Continental Shelf (Mediterranean Sea): Insights into the Last Glacial Maximum Sea-Level Changes and Related Environments

During the lowstand sea-level phase of the Last Glacial Maximum (LGM), a large part of the current Mediterranean continental shelf emerged. Erosional and depositional processes shaped the coastal strips, while inland areas were affected by aeolian and fluvial processes. Evidence of both the lowstand phase and the subsequent phases of eustatic sea level rise can be observed on the continental shelf of Sardinia (Italy), including submerged palaeo-shorelines and landforms, and indicators of relict coastal palaeo-environments. This paper shows the results of a high-resolution survey on the continental shelf off San Pietro Island (southwestern Sardinia). Multisensor and multiscale data\u2014obtained by means of seismic sparker, sub-bottom profiler chirp, multibeam, side scan sonar, diving, and uncrewed aerial vehicles\u2014made it possible to reconstruct the morphological features shaped during the LGM at depths between 125 and 135 m. In particular, tectonic controlled palaeo-cliffs affected by landslides, the mouth of a deep palaeo-valley fossilized by marine sediments and a palaeo-lagoon containing a peri-littoral thanatocenosis (18,983 \ub1 268 cal BP) were detected. The Younger Dryas palaeo-shorelines were reconstructed, highlighted by a very well preserved beachrock. The coastal paleo-landscape with lagoon-barrier systems and retro-littoral dunes frequented by the Mesolithic populations was reconstructed

MIS 5.5 highstand and future sea level flooding at 2100 and 2300 in tectonically stable areas of central mediterranean sea: Sardinia and the pontina plain (Southern Latium), Italy

Areas of the Mediterranean Sea are dynamic habitats in which human activities have been conducted for centuries and which feature micro-tidal environments with about 0.40 m of range. For this reason, human settlements are still concentrated along a narrow coastline strip, where any change in the sea level and coastal dynamics may impact anthropic activities. We analyzed light detection and ranging (LiDAR) and Copernicus Earth observation data. The aim of this research is to provide estimates and detailed maps (in three coastal plain of Sardinia (Italy) and in the Pontina Plain (southern Latium, Italy) of: (i) the past marine transgression occurred during MIS 5.5 highstand 119 kyrss BP; (ii) the coastline regression occurred during the last glacial maximum MIS 2 (21.5 krs cal BP); and (iii) the potential marine submersion for 2100 and 2300. The objective of this multidisciplinary study is to provide maps of sea level rise future scenarios using the IPCC RCP 8.5 2019 projections and glacio-hydro-isostatic movements for the above selected coastal zones (considered tectonically stable), which are the locations of touristic resorts, railways and heritage sites. We estimated a potential loss of land for the above areas of between about 146 km(2) (IPCC 2019-RCP8.5 scenario) and 637 km(2) along a coastline length of about 268 km