29 research outputs found
Multifunctional Eu3+- and Er3+/Yb3+-doped GdVO4 nanoparticles synthesized by reverse micelle method
Synthesis of Eu3+- and Er3+/Yb3+-doped GdVO4 nanoparticles in reverse micelles and their multifunctional luminescence properties are presented. Using cyclohexane, Triton X-100, and n-pentanol as the oil, surfactant, and co-surfactant, respectively, crystalline nanoparticles with similar to 4 nm diameter are prepared at low temperatures. The particle size assessed using transmission electron microscopy is similar to the crystallite size obtained from X-ray diffraction measurements, suggesting that each particle comprises a single crystallite. Eu3+-doped GdVO4 nanoparticles emit red light through downconversion upon UV excitation. Er3+/Yb3+-doped GdVO4 nanoparticles exhibit several functions; apart from the downconversion of UV radiation into visible green light, they act as upconvertors, transforming near-infrared excitation (980 nm) into visible green light. The ratio of green emissions from H-2(11/2)- GT I-2(15/2) and S-4(3/2)- GT I-4(15/2) transitions is temperature dependent and can be used for nanoscale temperature sensing with near-infrared excitation. The relative sensor sensitivity is 1.11%K-1, which is among the highest sensitivities recorded for upconversion-luminescence-based thermometers
Influence of Er3+/Yb3+ Concentration Ratio on the Down-conversion and Up-conversion Luminescence and Lifetime in GdVO4:Er3+/Yb3+ Microcrystals
In this paper, we studied the effects of Er3+/Yb3+ concentration ratio on structural, morphological and luminescence properties of GdVO4:Er3+/Yb3+ green phosphors prepared by a high-temperature solid state method. The samples with different concentrations (between 0.5 to 2 mol%) of dopant Er3+ emitting ions and different concentrations (between 5 to 20 mol%) of sensitizer ions (Yb3+) were studied. The phosphors were characterized by the X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectroscopy. For all samples, XRD diffraction patterns confirmed a formation of a pure GdVO4 phase, while the SEM showed that the materials are comprised of chunks of deformed particles with an average diameter ranging from approximately 2 mu m to 8 mu m. Both, down-conversion and up-conversion emission spectra of GdVO4: Er3+/Yb3+ samples, under near UV and IR excitations, exhibit two strong emission bands in the green spectral region at 525 nm and 552 nm wavelengths corresponding to H-2(11/2) - gt I-4(15/2) and S-4(3/2) - gt I-4(15/2) electronic transitions of Er3+ ions. The intensity of the green emission was changed by changing the Er3+/Yb3+ concentration ratio. This dual-mode luminescence makes these materials ideal as green phosphors for a wide variety of applications in the fields of bioanalysis and biomedical
The improved photovoltaic response of commercial monocrystalline Si solar cell under natural and artificial light by using water flow lens (WFL) system
Y3Al5O12:Re3+ (Re=Ce, Eu, and Sm) nanocrystalline powders prepared by modified glycine combustion method
Yttrium aluminum garnet doped with rare earth ions (Ce3+, Eu3+ and Sm3+) was
prepared by modified glycine method. Ce3+ as a dopant was used in four
different concentrations (Y3-xCexAl5O12; x(%) = 1, 2, 3, 5), while doping
concentration of Eu3+ and Sm3+ was Y3-xEuxAl5O12; x(%) = 3 and Y3-xSmxAl5O12;
x(%) = 1, respectively. Phase composition of powders was investigated using
XRD technique and expected target phase was confirmed. Photoluminescent
characterization included measurements of excitation and emission spectra, as
well as determination of emission decays. Y3-xCexAl5O12 shows intense
broad-band emission, with maximum in green spectral region, at about 524 nm
under ultraviolet or blue excitation. The origin of the luminescence is the
5d1→4f1 transition which is both parity and spin allowed. Ultraviolet and
blue excitations of Eu3+ and Sm3+ doped Y3Al5O12 produce intense orange and
red emissions. These emissions are phosphorescent in character and come from
spin forbidden f-f electron transitions in Eu3+ and Sm3+ ions. For the case
of Eu3+ doping emission comes mainly from 5D0→7F1 transitions with Stark
components peaking at 590 nm and 590.75 nm, and with emission decay of 4.15
ms. In the case of Sm3+ doping, the emission spectrum, shows 4G5/2→6H5/2,
4G5/2→6H7/2, and 4G5/2→6H9/2 transitions, with the most intense stark
components positioned at 567.5 nm, 617 nm, and 650 nm, respectively and for
transition centered at 617 nm, emission decay is 3.12 ms. [Projekat
Ministarstva nauke Republike Srbije, br. 171022 i br. 45012
Influence of Er3+/Yb3+ concentration ratio on the down-conversion and up-conversion luminescence and lifetime in GdVO4:Er3+/Yb3+ microcrystals
In this paper, we studied the effects of Er3+/Yb3+ concentration ratio on
structural, morphological and luminescence properties of GdVO4:Er3+/Yb3+
green phosphors prepared by a high-temperature solid state method. The
samples with different concentrations (between 0.5 to 2 mol%) of dopant Er3+
emitting ions and different concentrations (between 5 to 20 mol%) of
sensitizer ions (Yb3+) were studied. The phosphors were characterized by the
X-ray diffraction (XRD), scanning electron microscopy (SEM) and
photoluminescence spectroscopy. For all samples, XRD diffraction patterns
confirmed a formation of a pure GdVO4 phase, while the SEM showed that the
materials are comprised of chunks of deformed particles with an average
diameter ranging from approximately 2 μm to 8 μm. Both, down-conversion and
up-conversion emission spectra of GdVO4:Er3+/Yb3+ samples, under near UV and
IR excitations, exhibit two strong emission bands in the green spectral
region at 525 nm and 552 nm wavelengths corresponding to 2H11/2 →4I15/2 and
4S3/2 → 4I15/2 electronic transitions of Er3+ ions. The intensity of the
green emission was changed by changing the Er3+/Yb3+ concentration ratio.
This dual-mode luminescence makes these materials ideal as green phosphors
for a wide variety of applications in the fields of bioanalysis and
biomedical. [Projekat Ministarstva nauke Republike Srbije, br. 45020 i br.
172056
Enhancement of luminescence emission from GdVO4:Er3+/Yb3+ phosphor by Li+ co-doping
This paper demonstrates the effects of Li+ co-doping on the structure, morphology, and luminescence properties of GdVO4:Er3+/Yb3+ phosphor prepared using a high-temperature solid-state chemistry method. The GdVO4:Er3+/Yb3+ powders synthesized with the Li+ co-dopant (in concentrations of 0, 5, 10, and 15 mol%) are characterized by X-ray powder diffraction, scanning electron microscopy, and photoluminescence spectroscopy. Structural analysis showed that powders co-doped with Li+ have larger crystallite sizes and slightly smaller crystal lattice parameters than powders prepared without Li+ ions. Photoluminescence down-conversion (345-nm excitation) and up-conversion (980-nm excitation) spectra show characteristic Er3+ emissions, with the most intense bands peaking at 525 nm (H-2(11/2) - GT I-4(15/2) transition) and 552 nm (S-4(3/2) - GT I-4(15/2)). The intensity of up-conversion emission from GdVO4:Er3+/Yb3+ is enhanced (by a factor of four) by co-doping with 5 mol% of Li+ ions. The mechanisms responsible for this emission enhancement are discussed. (C) 2014 Elsevier Inc. All rights reserved