Tracing potential soil contamination in the historical Solvay soda ash plant area, Jaworzno, Southern Poland

This study of soil conditions was carried out on 30 meadow soil (podzol) samples from the vicinity of the soda ash heap in Jaworzno, supplemented by analyses of 18 samples of waste deposited on the heap. In all samples, the total content of macroelements (Ca and Na) and heavy metals (Cd, Cr, Ni, Pb and Zn) as well as pH were analysed. The element concentrations were measured using inductively coupled plasma optical emission spectrometry (ICP-OES). The materials examined were neutral to ultra-alkaline. Total accumulations (mg kg(−1)) of chemical elements in the soil vary from 130.24 to 14076.67 for Ca, 41.40–926.23 for Na, 0.03–3.34 for Cd, 0.94–103.62 for Cr, 0.94–35.89 for Ni, 3.51–76.47 for Pb and 12.05–279.13 for Zn, whereas quantities of the same elements in the waste samples vary from 171705.13 to 360487.94 for Ca, 517.64–3152.82 for Na, 0.2–9.89 for Cd, 1.16–20.40 for Cr, 1.08–9.79 for Ni, 0.1–146.05 for Pb and 10.26–552.35 for Zn. The vertical distribution of the metals was determined in each soil profile. Despite enrichment of heavy metals in the uppermost horizon on the top of the heap, the results lead to the conclusion that the relation of historical production of soda ash in Jaworzno to current contamination of the local soil environment is insignificant

50 years of different landscape management influencing retention of metals in soils

Abstract not availableVladislav Chrastný, Michael Komárek, Jan Procházka, Libor Pechar, Aleš Vaněk, Vít Penížek, Juraj Farka

Incubation of air-pollution-control residues from secondary Pb smelter in deciduous and coniferous organic soil horizons: leachability of lead, cadmium and zinc

Abstract not availableVladislav Chrastný, Aleš Vaněk, Michael Komárek, Juraj Farkaš, Ondřej Drábek, Petra Vokurková, Jana Němcov

Metal(loid) and isotopic tracing of Pb in soils, road and house dusts from the industrial area of Volos (central Greece)

This study examines the metal(loid) contents (As, Cd, Cr, Cu, Mn, Ni, Pb, Sb, Tl and Zn) and Pb isotopes in different environmental compartments (soil, road dust, house dust) from the industrial vicinity of Volos, central Greece. The area surrounding two steel factories, a cement plant, an industrial area and the city core were considered as potential hot spots of metal(loid) contamination. Significant anthropogenic enrichments of Cd, Pb and Zn in relation to local baseline were identified for the soil (median Enrichment Factors of 7, 15 and 8, respectively) and road dusts around the steel factory located at Velestino area. The high contents of As, Sb and Tl in the soil and road dust around the cement plant are attributed to natural sources of contamination associated with adjacent mineralization. The soil samples in the city core exhibited moderate enrichments with respect to typical tracers (Pb, Zn) of anthropogenic contamination in urban areas. Anthropogenic influences in terms of metal(loid) concentrations were more pronounced for the road and house dust material. The Pb isotopic ratios of soil (206Pb/207Pb = 1.154 to 1.194), road dust (206Pb/207Pb = 1.144 to 1.174) and house dust (206Pb/207Pb = 1.129 to 1.171) were between those of the local bedrock and anthropogenic Pb sources. Industrial Pb from the steel plant was the predominant anthropogenic Pb source with relative contributions of ~49% for the soil, ~42% for the road dust and ~44% for the house dust samples. For the road and house dust material, the geochemical signature obtained from Pb isotopic compositions and elemental ratios suggests additional contributors from vehicular emissions. The results of this study demonstrate the suitability of soil to trace natural and anthropogenic impacts in industrial areas and the sensitivity of the road and house dust material to record anthropogenic (industrial and vehicular-derived) contamination in such environments. © 2020 Elsevier B.V

Tracing the sources of bioaccessible metal(loid)s in urban environments: A multidisciplinary approach

Understanding the links between sources of magnetic particles and bioaccessibility of metal(loids) in environmental sampling media is crucial for better evaluating human health risks, although relevant information in the scientific literature is scarce. Here, soil, road and house dust samples from a heavy industrial area in Greece were characterized in a multidisciplinary study combining magnetic measurements, SEM/EDS analyses, bioaccessibility measurements and Pb isotopic analyses of bioaccessible Pb. The oral and inhalable bioaccessible fractions of As, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn were assessed by applying simulated gastric and lung solutions. SEM/EDS analysis revealed the abundant presence of anthropogenic Fe-containing spherules of industrial origin in all sampling media, often containing minor contents of Cr, Cu, Mn, Pb and Zn. The inhalation bioaccessibility (%) in all environmental compartments was higher than the oral one for most elements analyzed in the present study. Clear associations between magnetic susceptibility and bioaccessible amounts of most of analyzed elements were encountered for the soil and road dust. The isotopic analyses of bioaccessible Pb showed that there are significant differences in the isotopic ratios between total and bioaccessible Pb. We conclude that Pb solubilized by the simulated gastric and lung extractions is principally anthropogenic, representing a mixture of industrial Pb and Pb related to the past usage of leaded petrol. Low values of 206Pb/207Pb were accompanied by high bioaccessible contents of Cd, Pb and Zn indicating that anthropogenic (mostly industrial) sources exert influence on the bioaccessible forms of these metals. Coupling magnetic and bioaccessibility measurements with stable isotopic technique of bioaccessible Pb is more reliable for determining Pb and other metal sources with high oral and inhalation bioaccessibility. © 2021 Elsevier B.V

Chromium isotope variations (delta(53)/(52)Cr) in mantle-derived sources and their weathering products: Implications for environmental studies and the evolution of delta(53)/(52)Cr in the Earth's mantle over geologic time

Abstract not availableJuraj Farkaš, Vladislav Chrastný, Martin Novák, Eva Čadkova, Jan Pašava, Ramananda Chakrabarti, Stein B. Jacobsen, Lukáš Ackerman, Thomas D. Bulle

Antagonistic Cd and Zn isotope behavior in the extracted soil fractions from industrial areas

The remobilization of metals accumulated in contaminated soils poses a threat to humans and ecosystems in general. Tracing metal fractionation provides valuable information for understanding the remobilization processes in smelting areas. Based on the difference between the isotopic system of Cd and Zn, this work aimed to couple isotope data and their leachability to identify possible remobilization processes in several soil types and land uses. For soil samples, the delta Zn-66/64 values ranged from 0.12 +/- 0.05 parts per thousand to 0.28 +/- 0.05 parts per thousand in Avil & eacute;s (Spain) and from - 0.09 +/- 0.05 parts per thousand to - 0.21 +/- 0.05 parts per thousand in Pr & iacute;bram (Czech Republic), and the delta Cd-114/110 ranged from - 0.13 +/- 0.05 parts per thousand to 0.01 +/- 0.04 parts per thousand in Avil & eacute;s and from - 0.86 +/- 0.27 parts per thousand to - 0.24 +/- 0.05 parts per thousand in Pr & iacute;bram. The metal fractions extracted using chemical extractions were always enriched in heavier Cd isotopes whilst Zn isotope systematics exhibited light or heavy enrichment according to the soil type and land uses. Coupling Zn and Cd systematics provided a tool for deciphering the mechanisms behind the remobilization processes: leaching of the anthropogenic materials and/or metal redistribution within the soil components prior to remobilization