2,697 research outputs found
Study of olivines from Omolon and Seymchan meteorites using X-ray diffraction and Mössbauer spectroscopy with a high velocity resolution
Study of olivine from Omolon and Seymchan meteorites was performed using X-ray diffraction and Mössbauer spectroscopy with a high velocity resolution. X-ray diffraction patterns were measured at room temperature while Mössbauer spectra were measured at 295 and 90 K. The orthorhombic crystal lattice parameters were evaluated for olivine from Omolon and Seymchan. These parameters appeared to be different for olivines from both meteorites. Mössbauer spectral components related to 57Fe in crystallographically non-equivalent sites M1 and M2 in both olivines were determined and its Mössbauer hyperfine parameters were evaluated. Some differences in the tendencies of temperature dependence of spectral parameters and small variations of 57Fe quadrupole splitting in both M1 and M2 sites of olivines from Omolon and Seymchan were found. On the basis of Mössbauer parameters and chemical data, the temperatures of equilibrium cation distribution were evaluated for both olivines. © 2012 American Institute of Physics
Theoretical and experimental study of high-pressure synthesized B20-type compounds Mn(Co,Rh)Ge
The search and exploration of new materials not found in nature is one of
modern trends in pure and applied chemistry. In the present work, we report on
experimental and \textit{ab initio} density-functional study of the
high-pressure-synthesized series of compounds Mn(Co,Rh)Ge. These
high-pressure phases remain metastable at normal conditions, therewith they
preserve their inherent noncentrosymmetric B20-type structure and chiral
magnetism. Of particular interest in these two isovalent systems is the
comparative analysis of the effect of (Co) and (Rh) substitution for
Mn, since the orbitals are characterized by higher localization and
electron interaction than the orbitals. The behavior of
Mn(Co,Rh)Ge systems is traced as the concentration changes in the
range . We applied a sensitive experimental and theoretical
technique which allowed to refine the shape of the temperature dependencies of
magnetic susceptibility and thereby provide a new and detailed
magnetic phase diagram of MnCoGe. It is shown that both systems
exhibit a helical magnetic ordering that very strongly depends on the
composition . However, the phase diagram of MnCoGe differs from
that of MnRhGe in that it is characterized by coexistence of two
helices in particular regions of concentrations and temperatures.Comment: 12 pages, 11 figure
Preparation and characterization of Bi26–2xMn2xMo10O69-d and Bi26.4Mn0.6Mo10–2yMe2yO69-d(Me = V, Fe) solid solutions
Received: 06.06.2017; accepted: 23.06.2017; published: 14.07.2017.Single phase samples of bismuth molybdate, Bi26Mo10O69, doped with Mn on the bismuth sublattice and V, Fe on the molybdenum sublattice were found to crystallize in the triclinic Bi26Mo10O69 structure at low doping levels and in the monoclinic Bi26Mo10O69 structure - at higher dopant concentration. The assumption that all Mn ions have an oxidation state of +2 was confirmed by means of magnetic measurement results analysis using Curie-Weiss law. Conductivity was investigated using impedance spectroscopy. The conductivity of Bi26.4Mn0.6Mo9.6Fe0.4O69-d was 1.2*10-2 S*cm-1 at 973 K and 2.2*10-4 S*cm-1 at 623 K, and the conductivity of Bi26.4Mn0.6Mo9.2V0.8O69-d was 2.2*10-3 S*cm-1 at 973 K and 2.2*10-5 S*cm-1 at 623 K
Ethno-cultural component in Sochi residents’ geopolitical consciousness
The article concerns crucial issues of Sochi residents’ political consciousness features formation in the context of toleration and interethnic dialog development, analyses factors, having effect on cultures interpenetration in Sochi politics
Crystal structure and conductivity of bismuth-containing complex oxides
In the paper, a comprehensive systematic study of different classes of bismuth containing oxide compounds was carried out. The relationship between composition, temperature and concentration regions of existence of stable, specific structure and properties of solid solutions on the basis of vanadates, molybdates, niobates and bismuth was found. The general regularities of synthesis of solid solutions with different variants of solid-phase and soluble methods were determined. On this basis, the optimal conditions for obtaining
single-phase materials were formulated. For the first time the temperature and concentration boundaries of the regions of homogeneity and areas of stable existence of polymorphic modifications of solid solutions were defined and/or refined. The structural parameters of the synthesized phases were determined. By the method of electrochemical impedance spectroscopy the nature and features
of impedance spectra, the temperature and concentration dependences of electrical conductivity of ceramic materials based on bismuth containing complex oxides were identified
13. Association between EEG and Neuropsychological Disturbances in Patients with Idiopathic Parkinson\u27s disease and Sleep Disorders
Phytoconstituents and bioactivity of plants of the genus Spiraea L. (Rosaceae): A review
The genus Spiraea L. belongs to the Rosaceae Juss. family and includes more than 100 species distributed in the temperate zone and subtropical zone of the Northern Hemisphere at the center of species diversity in East Asia. Representatives of the genus are known as ornamental plants with many forms and varieties, are widely used in conventional medicine, and have a high resource potential. This review provides information on the diversity of phenolic compounds (flavonoids, phenolcarboxylic acids, and lignans), terpenoids, alkaloids, steroids, and other classes of secondary metabolites in the species of Spiraea worldwide. The article also presents little-known and hard-to-find data published in Russian concerning Spiraea phytochemistry. The biological activities of extracts and their fractions and of individual compounds having different types of biological activity (e.g., antioxidant, antibacterial, anti-inflammatory, and antifungal) are discussed. Data about biotechnological research on representatives of the genus Spiraea are presented too. The analysis of the literature showed that further chemical and pharmacological studies on Spiraea plants are quite promising
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