Phase space structures and ionization dynamics of hydrogen atom in elliptically polarized microwaves

The multiphoton ionization of hydrogen atoms in a strong elliptically polarized microwave field exhibits complex features that are not observed for ionization in circular and linear polarized fields. Experimental data reveal high sensitivity of ionization dynamics to the small changes of the field polarization. The multidimensional nature of the problem makes widely used diagnostics of dynamics, such as Poincar\'{e} surfaces of section, impractical. We analyze the phase space dynamics using finite time stability analysis rendered by the fast Lyapunov Indicators technique. The concept of zero--velocity surface is used to initialize the calculations and visualize the dynamics. Our analysis provides stability maps calculated for the initial energy at the maximum and below the saddle of the zero-velocity surface. We estimate qualitatively the dependence of ionization thresholds on the parameters of the applied field, such as polarization and scaled amplitude

Production of trans-Neptunian binaries through chaos-assisted capture

The recent discovery of binary objects in the Kuiper-belt opens an invaluable window into past and present conditions in the trans-Neptunian part of the Solar System. For example, knowledge of how these objects formed can be used to impose constraints on planetary formation theories. We have recently proposed a binary-object formation model based on the notion of chaos-assisted capture. Here we present a more detailed analysis with calculations performed in the spatial (three-dimensional) three- and four-body Hill approximations. It is assumed that the potential binary partners are initially following heliocentric Keplerian orbits and that their relative motion becomes perturbed as these objects undergo close encounters. First, the mass, velocity, and orbital element distribu- tions which favour binary formation are identified in the circular and elliptical Hill limits. We then consider intruder scattering in the circular Hill four-body problem and find that the chaos-assisted capture mechanism is consistent with observed, apparently randomly distributed, binary mutual orbit inclinations. It also predicts asymmetric distributions of retrograde versus prograde orbits. The time-delay induced by chaos on particle transport through the Hill sphere is analogous to the formation of a resonance in a chemical reaction. Implications for binary formation rates are considered and the 'fine-tuning' problem recently identified by Noll et al. (2007) is also addressed.Comment: submitted to MNRA

The Transition State in a Noisy Environment

Transition State Theory overestimates reaction rates in solution because conventional dividing surfaces between reagents and products are crossed many times by the same reactive trajectory. We describe a recipe for constructing a time-dependent dividing surface free of such recrossings in the presence of noise. The no-recrossing limit of Transition State Theory thus becomes generally available for the description of reactions in a fluctuating environment

Stochastic Transition States: Reaction Geometry amidst Noise

Classical transition state theory (TST) is the cornerstone of reaction rate theory. It postulates a partition of phase space into reactant and product regions, which are separated by a dividing surface that reactive trajectories must cross. In order not to overestimate the reaction rate, the dynamics must be free of recrossings of the dividing surface. This no-recrossing rule is difficult (and sometimes impossible) to enforce, however, when a chemical reaction takes place in a fluctuating environment such as a liquid. High-accuracy approximations to the rate are well known when the solvent forces are treated using stochastic representations, though again, exact no-recrossing surfaces have not been available. To generalize the exact limit of TST to reactive systems driven by noise, we introduce a time-dependent dividing surface that is stochastically moving in phase space such that it is crossed once and only once by each transition path

Reducing multiphoton ionization in a linearly polarized microwave field by local control

We present a control procedure to reduce the stochastic ionization of hydrogen atom in a strong microwave field by adding to the original Hamiltonian a comparatively small control term which might consist of an additional set of microwave fields. This modification restores select invariant tori in the dynamics and prevents ionization. We demonstrate the procedure on the one-dimensional model of microwave ionization.Comment: 8 page

Renormalization group approach to vibrational energy transfer in protein

Renormalization group method is applied to the study of vibrational energy transfer in protein molecule. An effective Lagrangian and associated equations of motion to describe the resonant energy transfer are analyzed in terms of the first-order perturbative renormalization group theory that has been developed as a unified tool for global asymptotic analysis. After the elimination of singular terms associated with the Fermi resonance, amplitude equations to describe the slow dynamics of vibrational energy transfer are derived, which recover the result obtained by a technique developed in nonlinear optics [S.J. Lade, Y.S. Kivshar, Phys. Lett. A 372 (2008) 1077].Comment: 11 page

Semiclassical ionization dynamics of the hydrogen molecular ion in an electric field of arbitrary orientation

Quasi-static models of barrier suppression have played a major role in our understanding of the ionization of atoms and molecules in strong laser fields. Despite their success, in the case of diatomic molecules these studies have so far been restricted to fields aligned with the molecular axis. In this paper we investigate the locations and heights of the potential barriers in the hydrogen molecular ion in an electric field of arbitrary orientation. We find that the barriers undergo bifurcations as the external field strength and direction are varied. This phenomenon represents an unexpected level of intricacy even on this most elementary level of the dynamics. We describe the dynamics of tunnelling ionization through the barriers semiclassically and use our results to shed new light on the success of a recent theory of molecular tunnelling ionization as well as earlier theories that restrict the electric field to be aligned with the molecular axis

Hydrogen atom in crossed electric and magnetic fields: Phase space topology and torus quantization via periodic orbits

A hierarchical ordering is demonstrated for the periodic orbits in a strongly coupled multidimensional Hamiltonian system, namely the hydrogen atom in crossed electric and magnetic fields. It mirrors the hierarchy of broken resonant tori and thereby allows one to characterize the periodic orbits by a set of winding numbers. With this knowledge, we construct the action variables as functions of the frequency ratios and carry out a semiclassical torus quantization. The semiclassical energy levels thus obtained agree well with exact quantum calculations

A Computational Procedure to Detect a New Type of High Dimensional Chaotic Saddle and its Application to the 3-D Hill's Problem

A computational procedure that allows the detection of a new type of high-dimensional chaotic saddle in Hamiltonian systems with three degrees of freedom is presented. The chaotic saddle is associated with a so-called normally hyperbolic invariant manifold (NHIM). The procedure allows to compute appropriate homoclinic orbits to the NHIM from which we can infer the existence a chaotic saddle. NHIMs control the phase space transport across an equilibrium point of saddle-centre-...-centre stability type, which is a fundamental mechanism for chemical reactions, capture and escape, scattering, and, more generally, ``transformation'' in many different areas of physics. Consequently, the presented methods and results are of broad interest. The procedure is illustrated for the spatial Hill's problem which is a well known model in celestial mechanics and which gained much interest e.g. in the study of the formation of binaries in the Kuiper belt.Comment: 12 pages, 6 figures, pdflatex, submitted to JPhys

The Cytotoxic T Lymphocyte Antigen-4+49A/G Single Nucleotide Polymorphism Association With Visceral Leishmaniasis

Background: Several lines of evidence approve that innate and adaptive immunity play key roles in the defense against visceral leishmaniasis (VL). The polymorphism within the cytotoxic T lymphocyte antigen 4 (CTLA-4) gene alters its expression. Objectives: The main aim of this study was to evaluate the polymorphism within the +49 position of the CTLA-4 gene of Iranian patients with VL in comparison with healthy controls. Materials and Methods: In this cross-sectional study, 88 patients with clinical presentations of VL, who were seropositive for Leishmania (group 1), 86 patients without clinical presentations but seropositive (group 2), and 115 healthy controls (group 3) were assessed with respect to the CTLA-4 +49A/G polymorphism, using polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP). The anti-Leishmania antibody titration was evaluated using an immunofluorescence method. Results: Our results indicated that both CTLA-4 +49A/G polymorphisms were significantly associated with VL. Conclusions: According to the results, the polymorphisms within the +49 position of CTLA-4 can be associated with VL and may be considered as risk factors for the disease