The Status of Natural Radioactivity and Heavy Metals Pollution on Marine Sediments Red Sea Coast, At Safaga, Egypt

Natural 226Ra, 232Th and 40K radio nuclides concentration in beach Sediments along Safaga coast of Red sea, Egypt has been carried out using a NaI (Tl) gamma ray spectrometric technique. The total average concentrations of radionuclides ± uncertainty of 226Ra, 232Th and 40K were 22.2 ± 1.7, 19.2 ± 2.5, and 477.6 ± 27.6 Bqkg-1, respectively. The total average absorbed dose rate is found to be 41.4 nGyh-1, whereas the annual effective dose rate has an average value of 54 μSvy-1. The total organic matter (TOC), carbonates (CaCo3) and Heavy metals distribution have been measured at some locations, the concentration for the investigated heavy metals overtake the allowable limits recommended by the Canadian Environmental Quality Guidelines, this assigned to the ratio of metals pollution is caused by anthropogenic activities (phosphate shipment as in Abu Tartour harbor and navigation as in Touristic harbor) and or by natural impacts such in mangrove interment. Statistical analyses were carried out between the parameters obtained from the radioactivity to know the existing relations and to study the spatial distribution of radionuclide

Assessment of natural radionuclides and heavy metal concentrations in marine sediments in view of tourism activities in Hurghada city, northern Red Sea, Egypt

The specific activity of 40K, 232Th and 226Ra in marine sediment samples collected from National Institute of Oceanography and Fisheries (NIOF) and Safier Hotel area in Hurghada city (the most important regions in Egypt), were measured by gamma ray spectrometry using NaI(Tl) detector. The values of specific activity varied from 7 ± 1 Bq kg-1 to 53 ± 4 Bq kg-1, 6 ± 1 Bq kg-1 to 32 ± 6 Bq kg-1, and from 167 ± 11 Bq kg-1 to 1120 ± 63 Bq kg-1 for 226Ra, 232Th and 40K, respectively. The heavy metals have been measured and analysed by atomic absorption spectrometer. The major range values of heavy metals concentrations in marine sediment samples were: Cu (10.5-78.0 μg g-1), Zn (21-150 μg g-1), Pb (30-53 μg g-1), Cd (2.50-4.00 μg g-1), Fe (5100-13150 μg g-1), Mn (118-298 μg g-1), Ni (17-36 μg g-1) and Co (16-18 μg g-1). The total organic matter (TOC) and carbonates (CaCo3) distribution have been measured at some locations. Also, the frequency distribution and the value of (232Th/226Ra), (232Th/40K) and (226Ra/40K) ratio for all measured samples were determined. Additionally, evaluations have been made of the radiological hazards and the results are diagrammed by Surfer program in maps. © Penerbit Universiti Sains Malaysia, 2019

Influence of Reaction Time, Reducing Agent and Zinc Precursors on the Morphological Structures of Zinc Oxide

ZnO either nanoparticles or nanorods were synthesized via sol-gel technique. Many factors were studied and optimized in order to obtain different morphological structures of nano-ZnO. Effect of reaction time (3, 6, 12, 24 and 48 hours) has been studied to optimize the best preparation condition. Reducing agent (NH3, NaOH and KOH) is one of the factors affect on morphological structures, which has been studied in this work. Other effect has been studied in this work is zinc precursors such as Zn(NO3)2, ZnAc2, ZnCl2, and ZnBr2. The morphological structures of prepared ZnO were revealed using scanning electron microscope (SEM) and the aspect ratios were calculated. x-ray diffraction (XRD) patternsexposed a highly crystallized wurtzite structure and used for identifying phase structure and chemical state of ZnO under different preparation conditions.Keywords: sol-gel, morphological structures, reducing agent, SEM, preparation conditions

Estimate the absolute efficiency by MATLAB for the NaI (Tl) detector using IAEA-314

This works amid to calculating the absolute efficiency at any interesting γ-energy in the energy range between 10 and 1764 keV. by using fit function which has been developed to calculate theoretically the absolute γ-ray detection efficiencies of a cylindrical NaI(Tl) crystal. Efficiency of the NaI(Tl) calculator is a program built in MATLAB by the author of this paper to make it easier to calculate the efficiency of standard source. The absolute γ-ray detection efficiencies have been calculated for detectors 3? x 3? inches NaI(Tl) crystal. The absolute efficiency of the NaI (Tl) detector was calculated using standard sources (IAEA-314) which have known activity of 226Ra (732 Bqkg-1) and 232Th (17.8 ppm). In this calculation, experimental and theoretical efficiencies have been calculated. The uncertainties of efficiency calibration have been calculated also for quality control. Measurements were performed with calibrated point source. Gamma-ray energies under consideration were 0.356, 0.662, 1.17 and 1.33 MeV. Efficiency function was obtained by applying Weibull Model equation to the experimental efficiency data which give Best agreement between experimental and theoretical absolute detection efficiencies of 3×3-inch detector for gamma energy. © 2019 Author(s)

Radiation Hazards and the Cancer Risk Assessments in the Sediments of Timsah Lake, Egypt

Timsah Lake is one of the most fish productive lakes in Egypt. It is located at the midpoint of Suez Canal with surface area of about 16 km2. The lake receives about 833,000 m3daily of wastewater and sewage wastes from agriculture, industry and domestic drains. The activity concentrations of the natural radionuclides; 238U, 232Th and 40K were measured using gamma-ray spectrophotometer at 24 stations covering the whole area of the lake and the Western Bay. The average activities of 238U, 232Th and 40K were; 21.66 ± 11.20, 21.42 ± 11.68 and 200.30 ± 141.10 Bq/kg respectively. The averages of radiation hazard parameters; the absorbed and effective dose rate (D), the annual effective dose equivalent (AEDE), radium equivalent (Raeq), the external hazard index (Hex) and the representative level index (Iγr) were; 30.85 nGy h-1, 37.84 μSv/y, 67.02 Bq/kg, 0.18 (lower than the unity) and 0.23 respectively. The distribution patterns showed significant high variations in the radionuclides activities and the hazard parameters between the investigated stations. The Western Bay stations and the path zone interlinked between the bay and the lake showed the high radionuclide activities and high radiation hazards indicating to the sewage wastes and wastewater runoff are the essential sources of the high natural radionuclide activities and radiation hazards. The average of the excess lifetime cancer risk (ELCR) was 132.43 × 10-6significantly lower than the worldwide average. The highest recorded level of ELCR was reached 308.38 × 10-6observed in the interlink zone between the bay and the lake away from fishing stations and recreational zones. Statistical analyses indicated that the radionuclides 238U and 232Th are the sources of the elevated radiation hazards with nearly equal intensities. © 2020. All Rights Reserved

Structure, Mössbauer, electrical, and γ-ray attenuation-properties of magnesium zinc ferrite synthesized co-precipitation method

For technical and radioprotection causes, it has become essential to find new trends of smart materials which used as protection from ionizing radiation. To overcome the undesirable properties in lead aprons and provide the proper or better shielding properties against ionizing radiation, the tendency is now going to use ferrite as a shielding material. The co-precipitation method was utilized to prevent any foreign phases in the investigated MZN nano-ferrite. X-ray diffraction (XRD) and Fourier transmission infrared spectroscopy (FTIR) methods were used to analyze the manufactured sample. As proven by XRD and FTIR, the studied materials have their unique spinel phase with cubic structure Fd3m space group. The DC resistivity of Mg–Zn ferrite was carried out in the temperature range (77–295 K), and its dependence on temperature indicates that there are different charge transport mechanisms. The Mössbauer spectra analysis confirmed that the ferrimagnetic to superparamagnetic phase transition behaviour depends on Zn concentration. The incorporation of Zn to MZF enhanced the nano-ferrite density, whereas the addition of different Zn-oxides reduced the density for nano-ferrite samples. This variation in density changed the radiation shielding results. The sample containing high Zn (MZF-0.5) gives us better results in radiation shielding properties at low gamma, so this sample is superior in shielding results for charged particles at low energy. Finally, the possibility to use MZN nano-ferrite with various content in different ionizing radiation shielding fields can be concluded. © 2022, The Author(s).PNURSP2022R173This work was funded by Princess Nourah bint, Abdulrahman University, Research Supporting Project number (PNURSP2022R173) Princess Nourah bint, Abdulrahman University Riyadh, Saudi Arabia

Influence of Reaction Time, Reducing Agent and Zinc Precursors on the Morphological Structures of Zinc Oxide

ZnO either nanoparticles or nanorods were synthesized via sol-gel technique. Many factors were studied and optimized in order to obtain different morphological structures of nano-ZnO. Effect of reaction time (3, 6, 12, 24 and 48 hours) has been studied to optimize the best preparation condition. Reducing agent (NH3, NaOH and KOH) is one of the factors affect on morphological structures, which has been studied in this work. Other effect has been studied in this work is zinc precursors such as Zn (NO3)2, ZnAc2, ZnCl2, and ZnBr2. The morphological structures of prepared ZnO were revealed using scanning electron microscope (SEM) and the aspect ratios were calculated. x-ray diffraction (XRD) patterns exposed a highly crystallized wurtzite structure and used for identifying phase structure and chemical state of ZnO under different preparation conditions

Distribution of Radionuclides and Radiological Health Assessment in Seih-Sidri Area, Southwestern Sinai

The current contribution goal is to measure the distribution of the radionuclide within the exposed rock units of southwestern Sinai, Seih-Sidri area, and assess the radiological risk. Gneisses, older granites, younger gabbro, younger granites, and post granitic dikes (pegmatites) are the main rock units copout in the target area. Radioactivity, as well as radiological implications, were investigated for forty-three samples from gneisses (seven hornblende biotite gneiss and seven biotite gneiss), older granites (fourteen samples), and younger granites (fifteen samples of syenogranites) using NaI (Tl) scintillation detector. External and internal hazard index (Hex, Hin), internal and external level indices (Iα, Iγ), absorbed dose rates in the air (D), the annual effective dose equivalent (AED), radium equivalent activity (Raeq), annual gonadal dose (AGDE), excess lifetime cancer risk (ELCR), and the value of Upper Continental Core 232Th/238U mass fractions were determined from the obtained values of 238U, 232Th and 40K for the examined rocks of Seih-Sidri area. The average 238U mg/kg in hornblende biotite gneiss and biotite gneiss, older granites, and syenogranites is 2.3, 2.1, 2.7, and 8.4 mg/kg, respectively, reflecting a relatively higher concentration of uranium content in syenogranites. The results suggest that using these materials may pose risks to one’s radiological health. © 2022 by the authors.PNURSP2022R173; Universitatea 'Dunărea de Jos' Galați, UDJGConceptualization, M.S.K.; data curation, M.S.K., E.S.R.L., A.E., H.A.A. and H.M.H.Z.; formal analysis, M.S.K., E.S.R.L., A.E., H.A.A. and H.M.H.Z.; funding acquisition, A.E., G.A.A. and H.M.H.Z.; investigation, M.S.K., E.S.R.L., A.E., H.A.A. and H.M.H.Z.; methodology, M.S.K., E.S.R.L., A.E., M.A.M.U., H.A.A., S.A.M.I. and H.M.H.Z.; project administration, A.E. and H.M.H.Z.; resources, M.S.K., E.S.R.L. and H.M.H.Z.; software, A.E. and H.M.H.Z.; supervision, A.E. and H.M.H.Z.; validation, G.A.A., M.S.K., E.S.R.L., M.A.M.U., H.A.A., S.A.M.I. and H.M.H.Z.; visualization, H.M.H.Z.; writing—original draft, M.S.K., E.S.R.L., A.E., H.A.A. and H.M.H.Z.; writing—review and editing, G.A.A., M.S.K., E.S.R.L., A.E., M.A.M.U., S.A.M.I., H.A.A. and H.M.H.Z. The researcher H.A.A. is funded by a scholarship under the Joint (Executive Program between Egypt and Russia). All authors have read and agreed to the published version of the manuscript

The Influence of CoO/P2O5 Substitutions on the Structural, Mechanical, and Radiation Shielding of Boro-Phosphate Glasses

A new glass system (50−x)P2 O5 –20B2 O3 –5Al2 O3 –25Na2 O–xCoO was manufactured using a standard melt quenching procedure, where 1≤ x ≤ 12 mol%. The characteristics of boro-phosphate-glasses containing CoO have been studied. The effect of CoO on the radiation-protective properties of glasses was established. The density of the prepared glasses as a function of CoO increased. XRD was used to check the vitreous structure of samples. Fourier-transform infrared (FTIR) spectroscopy was used to study the structure of each sample. FTIR demonstrated that connections grew as CoO/P2 O5 levels increased, and the FTIR spectra shifted to higher wavenumbers. The increment of CoO converts non-bridging oxygens associated with phosphate structural units into bridging oxygens. This process increases the concentration of BO4 structural units and creates new, strong and stable bonds B–O–P, i.e., there is polymerization of the boro-phosphate glass network. With an increase in the ratio of CoO/P2 O5 in the produced samples, ultrasonic velocities and elastic moduli were observed to increase. The coefficients of linear and mass attenuation, the transmittance of photons in relation to the photon energy, the efficiency of radiation protection in relation to the photon energy, and the thickness of the absorber were modeled using these two methods (experimental and theoretical). From the obtained values, it can be concluded that the 12Co sample containing 12 mol% will play the most influential role in radiation protection. An increase in the content of cobalt-I oxide led to a significant increase in the linear and mass attenuation coefficient values, which directly contributes to the development of the radiation-protective properties of glass. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.Funding: This work funding by Deanship of Scientific at Jouf University through research grant no (DSR2020-02-504)