Discrepancy between Sr isotope and biostratigraphic datings of the upper middle and upper Miocene successions (Eastern North Sea Basin, Denmark)

AbstractOne hundred and fifty-six 87Sr/86Sr analyses have been performed on 129 samples from 18 outcrops and boreholes in Oligocene–Miocene deposits from Jylland, Denmark. These analyses were mainly conducted on mollusc shells but foraminiferal tests, Bolboforma and one shark tooth were also analysed.The main purpose of the study is to compare the ages of the Danish succession suggested by the biostratigraphic zonation on dinoflagellate cysts (Dybkjær and Piasecki, 2010) with the ages based on analyses of the 87Sr/86Sr composition of marine calcareous fossils in the same succession.Analyses of samples from the Danish Brejning, Vejle Fjord, Klintinghoved, Arnum, Odderup, Hodde, Ørnhøj and Gram formations gave ages between 25.7My (late Oligocene) and 10.3My (late Miocene). The Sr isotope ages from the lower part of the succession, i.e. Brejning to Odderup formations, agree with the age estimates based on biostratigraphy. However, the 87Sr/86Sr ratios of fossil carbonates from the middle–upper Miocene, Hodde to Gram succession consistently indicate ages older than those recorded by biostratigraphy. Post-depositional processes as an explanation for this offset are inconsistent with good preservation of shell material and little reworking. A palaeoenvironmental cause for the observed mismatch is therefore indicated.Search for geological events that could explain the older ages obtained by Sr isotope compositions have not led to any conclusions and we had recognised the same problem in earlier reports and communications. We conclude that this is a general and possibly global, middle–late Miocene problem that has to be reconsidered and explained geologically

Coral-based climate records from tropical South Atlantic:2009/2010 ENSO event in C and O isotopes from <i>Porites </i>corals (Rocas Atoll, Brazil)

ABSTRACT Coral skeletons contain records of past environmental conditions due to their long life span and well calibrated geochemical signatures. C and O isotope records of corals are especially interesting, because they can highlight multidecadal variability of local climate conditions beyond the instrumental record, with high fidelity and sub-annual resolution. Although, in order to get an optimal geochemical signal in coral skeleton, sampling strategies must be followed. Here we report one of the first coral-based isotopic record from the Equatorial South Atlantic from two colonies of Porites astreoides from the Rocas Atoll (offshore Brazil), a new location for climate reconstruction. We present time series of isotopic variation from profiles along the corallite valley of one colony and the apex of the corallite fan of the other colony. Significant differences in the isotopic values between the two colonies are observed, yet both record the 2009/2010 El Niño event - a period of widespread coral bleaching - as anomalously negative δ18O values (up to −1 permil). δ13C is found to be measurably affected by the El Niño event in one colony, by more positive values (+0.39 ‰), and together with a bloom of endolithic algae, may indicate physiological alteration of this colony. Our findings indicate that corals from the Rocas Atoll can be used for monitoring climate oscillations in the tropical South Atlantic Ocean

Absolute seasonal temperature estimates from clumped isotopes in bivalve shells suggest warm and variable greenhouse climate

Seasonal variability in sea surface temperatures plays a fundamental role in climate dynamics and species distribution. Seasonal bias can also severely compromise the accuracy of mean annual temperature reconstructions. It is therefore essential to better understand seasonal variability in climates of the past. Many reconstructions of climate in deep time neglect this issue and rely on controversial assumptions, such as estimates of sea water oxygen isotope composition. Here we present absolute seasonal temperature reconstructions based on clumped isotope measurements in bivalve shells which, critically, do not rely on these assumptions. We reconstruct highly precise monthly sea surface temperatures at around 50 °N latitude from individual oyster and rudist shells of the Campanian greenhouse period about 78 million years ago, when the seasonal range at 50 °N comprised 15 to 27 °C. In agreement with fully coupled climate model simulations, we find that greenhouse climates outside the tropics were warmer and more seasonal than previously thought. We conclude that seasonal bias and assumptions about seawater composition can distort temperature reconstructions and our understanding of past greenhouse climates

Marine temperatures underestimated for past greenhouse climate

AbstractUnderstanding the Earth’s climate system during past periods of high atmospheric CO2 is crucial for forecasting climate change under anthropogenically-elevated CO2. The Mesozoic Era is believed to have coincided with a long-term Greenhouse climate, and many of our temperature reconstructions come from stable isotopes of marine biotic calcite, in particular from belemnites, an extinct group of molluscs with carbonate hard-parts. Yet, temperatures reconstructed from the oxygen isotope composition of belemnites are consistently colder than those derived from other temperature proxies, leading to large uncertainties around Mesozoic sea temperatures. Here we apply clumped isotope palaeothermometry to two distinct carbonate phases from exceptionally well-preserved belemnites in order to constrain their living habitat, and improve temperature reconstructions based on stable oxygen isotopes. We show that belemnites precipitated both aragonite and calcite in warm, open ocean surface waters, and demonstrate how previous low estimates of belemnite calcification temperatures has led to widespread underestimation of Mesozoic sea temperatures by ca. 12 °C, raising estimates of some of the lowest temperature estimates for the Jurassic period to values which approach modern mid-latitude sea surface temperatures. Our findings enable accurate recalculation of global Mesozoic belemnite temperatures, and will thus improve our understanding of Greenhouse climate dynamics.</jats:p