30 research outputs found
Pressure Effect and Specific Heat of RBa2Cu3Ox at Distinct Charge Carrier Concentrations: Possible Influence of Stripes
In YBa2Cu3Ox, distinct features are found in the pressure dependence of the
transition temperature, dTc/dp, and in DeltaCp*Tc, where DeltaCp is the jump in
the specific heat at Tc: dTc/dp becomes zero when DeltaCp*Tc is maximal,
whereas dTc/dp has a peak at lower oxygen contents where DeltaCp*Tc vanishes.
Substituting Nd for Y and doping with Ca leads to a shift of these specific
oxygen contents, since oxygen order and hole doping by Ca influences the hole
content nh in the CuO2 planes. Calculating nh from the parabolic Tc(nh)
behavior, the features coalesce for all samples at nh=0.11 and nh=0.175,
irrespective of substitution and doping. Hence, this behavior seems to reflect
an intrinsic property of the CuO2 planes. Analyzing our results we obtain
different mechanisms in three doping regions: Tc changes in the optimally doped
and overdoped region are mainly caused by charge transfer. In the slightly
underdoped region an increasing contribution to dTc/dp is obtained when well
ordered CuO chain fragments serve as pinning centers for stripes. This behavior
is supported by our results on Zn doped NdBa2Cu3Ox and is responsible for the
well known dTc/dp peak observed in YBa2Cu3Ox at x=6.7. Going to a hole content
below nh=0.11 our results point to a crossover from an underdoped
superconductor to a doped antiferromagnet, changing completely the physics of
these materials.Comment: 6 pages, 5 figures Proccedings of the 'Stripes 2000' Conference, Rome
(2000
Magneto-structural properties of the layered quasi-2D triangular-lattice antiferromagnets CsCuClBr for = 0,1,2 and 4
We present a study of the magnetic susceptibility under variable
hydrostatic pressure on single crystals of CsCuClBr. This
includes the border compounds \textit{x} = 0 and 4, known as good realizations
of the distorted triangular-lattice spin-1/2 Heisenberg antiferromagnet, as
well as the isostructural stoichiometric systems CsCuClBr and
CsCuClBr. For the determination of the exchange coupling
constants and , data were fitted by a
model \cite{Schmidt2015}. Its application, validated for the
border compounds, yields a degree of frustration / = 0.47 for
CsCuClBr and / 0.63 - 0.78 for
CsCuClBr, making these systems particular interesting
representatives of this family. From the evolution of the magnetic
susceptibility under pressure up to about 0.4\,GPa, the maximum pressure
applied, two observations were made for all the compounds investigated here.
First, we find that the overall energy scale, given by +
), increases under pressure, whereas the ratio
/ remains unchanged in this pressure range. These experimental
observations are in accordance with the results of DFT calculations performed
for these materials. Secondly, for the magnetoelastic coupling constants,
extraordinarily small values are obtained. We assign these observations to a
structural peculiarity of this class of materials
Superconductivity mediated by a soft phonon mode: specific heat, resistivity, thermal expansion and magnetization of YB6
The superconductor YB6 has the second highest critical temperature Tc among
the boride family MBn. We report measurements of the specific heat,
resistivity, magnetic susceptibility and thermal expansion from 2 to 300 K,
using a single crystal with Tc = 7.2 K. The superconducting gap is
characteristic of medium-strong coupling. The specific heat, resistivity and
expansivity curves are deconvolved to yield approximations of the phonon
density of states, the spectral electron-phonon scattering function and the
phonon density of states weighted by the frequency-dependent Grueneisen
parameter respectively. Lattice vibrations extend to high frequencies >100 meV,
but a dominant Einstein-like mode at ~8 meV, associated with the vibrations of
yttrium ions in oversized boron cages, appears to provide most of the
superconducting coupling and gives rise to an unusual temperature behavior of
several observable quantities. A surface critical field Hc3 is also observed.Comment: 29 pages, 5 tables, 17 figures. Accepted for publication in Phys.
Rev.
Magnetocaloric effect and magnetic cooling near a field-induced quantum-critical point
The presence of a quantum critical point (QCP) can significantly affect the
thermodynamic properties of a material at finite temperatures T. This is
reflected, e.g., in the entropy landscape S(T, r) in the vicinity of a QCP,
yielding particularly strong variations for varying the tuning parameter r such
as pressure or magnetic field B. Here we report on the determination of the
critical enhancement of near a B-induced QCP via
absolute measurements of the magnetocaloric effect (MCE), , and demonstrate that the accumulation of entropy around the QCP can be
used for efficient low-temperature magnetic cooling. Our proof of principle is
based on measurements and theoretical calculations of the MCE and the cooling
performance for a Cu-containing coordination polymer, which is a very
good realization of a spin-1/2 antiferromagnetic Heisenberg chain - one of the
simplest quantum-critical systems.Comment: 21 pages, 4 figure
Specific Heat Study of 1D and 2D Excitations in the Layered Frustrated Quantum Antiferromagnets CsCuClBr
We report an experimental and theoretical study of the low-temperature
specific heat and magnetic susceptibility of the layered anisotropic
triangular-lattice spin-1/2 Heisenberg antiferromagnets
CsCuClBr with = 0, 1, 2, and 4. We find that the ratio
of the exchange couplings ranges from 0.32 to , implying a
change (crossover or quantum phase transition) in the materials' magnetic
properties from one-dimensional (1D) behavior for to
two-dimensional (2D) behavior for behavior. For , realized for = 0, 1, and 4, we find a magnetic contribution to the
low-temperature specific heat, , consistent with spinon
excitations in 1D spin-1/2 Heisenberg antiferromagnets. Remarkably, for =
2, where implies a 2D magnatic character, we also observe
. This finding, which contrasts the prediction of made by standard spin-wave theories, shows that Fermi-like
statistics also plays a significant role for the magnetic excitations in
frustrated spin-1/2 2D antiferromagnets
Synthesis, structural and physical properties of -FeSe
We report on synthesis, structural characterization, resistivity, magnetic
and thermal expansion measurements on the as yet unexplored -phase of
FeSe, here synthesized under ambient- (AP) and high-pressure (HP)
conditions. We show that in contrast to -FeSe, monophasic
superconducting -FeSe can be obtained in off-stoichiometric
samples with excess Fe atoms preferentially residing in the van der Waals gap
between the FeSe layers. The AP -FeSe sample studied here
( 8.5\,K) possesses an unprecedented residual resistivity ratio
RRR 16. Thermal expansion data reveal a small feature around
90\,K, which resembles the anomaly observed at the structural and
magnetic transitions for other Fe-based superconductors, suggesting that some
kind of "magnetic state" is formed also in FeSe. %indicative of a fluctuating
magnetic ordering. For HP samples (RRR 3), the disorder within the
FeSe layers is enhanced through the introduction of vacancies, the saturated
magnetic moment of Fe is reduced and only spurious superconductivity is
observed.Comment: 7 pages, 8 figures, published versio
Phase Separation Models for Cuprate Stripe Arrays
An electronic phase separation model provides a natural explanation for a
large variety of experimental results in the cuprates, including evidence for
both stripes and larger domains, and a termination of the phase separation in
the slightly overdoped regime, when the average hole density equals that on the
charged stripes. Several models are presented for charged stripes, showing how
density waves, superconductivity, and strong correlations compete with quantum
size effects (QSEs) in narrow stripes. The energy bands associated with the
charged stripes develop in the middle of the Mott gap, and the splitting of
these bands can be understood by considering the QSE on a single ladder.Comment: significant revisions: includes island phase, 16 eps figures, revte