5,396 research outputs found
Magnetothermal transport in the spin-1/2 chains of copper pyrazine dinitrate
We present experiments on the thermal transport in the spin-1/2 chain
compound copper pyrazine dinitrate Cu(C_4 H_4 N_2)(NO_3)_2. The heat
conductivity shows a surprisingly strong dependence on the applied magnetic
field B, characterized at low temperatures by two main features. The first one
appearing at low B is a characteristic dip located at mu_B B ~ k_B T, that may
arise from Umklapp scattering. The second one is a plateau-like feature in the
quantum critical regime, mu_B |B-B_c| < k_B T, where B_c is the saturation
field at T=0. The latter feature clearly points towards a momentum and field
independent mean free path of the spin excitations, contrary to theoretical
expectations.Comment: 4 pages, 4 figure
Wilson ratio of a Tomonaga-Luttinger liquid in a spin-1/2 Heisenberg ladder
Using micromechanical force magnetometry, we have measured the magnetization
of the strong-leg spin-1/2 ladder compound (CHN)CuBr at
temperatures down to 45 mK. Low-temperature magnetic susceptibility as a
function of field exhibits a maximum near the critical field H_c at which the
magnon gap vanishes, as expected for a gapped one-dimensional antiferromagnet.
Above H_c a clear minimum appears in the magnetization as a function of
temperature as predicted by theory. In this field region, the susceptibility in
conjunction with our specific heat data yields the Wilson ratio R_W. The result
supports the relation R_W=4K, where K is the Tomonaga-Luttinger-liquid
parameter
Platinum(II) phosphonate complexes derived from endo-8-camphanylphosphonic acid
The reactions of cis-[PtCl₂L₂] [L = PPh₃, PMe₂Ph or L₂ = Ph₂P(CH₂)₂PPh₂ (dppe)] with endo-8-camphanylphosphonic acid (CamPO₃H₂) and Ag₂O in refluxing dichloromethane gave platinum(II) phosphonate complexes [Pt(O₃PCam)L₂]. The X-ray crystal structure of [Pt(O₃PCam)(PPh₃)₂]•₂CHCl₃ shows that the bulky camphanyl group, rather than being directed away from the platinum, is instead directed into a pocket formed by the Pt and the two PPh₃ ligands. This allows the O₃P–CH₂ group to have a preferred staggered conformation. The complexes were studied in detail by NMR spectroscopy, which demonstrates non-fluxional behaviour for the sterically bulky PPh₃ and dppe derivatives, which contain inequivalent phosphine ligands in their ³¹P NMR spectra. These findings are backed up by theoretical calculations on the PPh₃ and PPhMe₂ derivatives, which show, respectively, high and low energy barriers to rotation of the camphanyl group in the PPh₃ and PPhMe₂ complexes. The X-ray crystal structure of CamPO₃H₂ is also reported, and consists of hydrogen-bonded hexameric aggregates, which assemble to form a columnar structure containing hydrophilic phosphonic acid channels surrounded by a sheath of bulky, hydrophobic camphanyl groups
Field-induced Tomonaga-Luttinger liquid phase of a two-leg spin-1/2 ladder with strong leg interactions
We study the magnetic-field-induced quantum phase transition from a gapped
quantum phase that has no magnetic long-range order into a gapless phase in the
spin-1/2 ladder compound bis(2,3-dimethylpyridinium) tetrabromocuprate (DIMPY).
At temperatures below about 1 K, the specific heat in the gapless phase attains
an asymptotic linear temperature dependence, characteristic of a
Tomonaga-Luttinger liquid. Inelastic neutron scattering and the specific heat
measurements in both phases are in good agreement with theoretical
calculations, demonstrating that DIMPY is the first model material for an S=1/2
two-leg spin ladder in the strong-leg regime.Comment: 4.1 pages, 4 figures (Fig. 4 updated), to appear in Physical Review
Letter
Neutron scattering from a coordination polymer quantum paramagnet
Inelastic neutron scattering measurements are reported for a powder sample of
the spin-1/2 quantum paramagnet . Magnetic neutron
scattering is identified above an energy gap of 1.9 meV. Analysis of the sharp
spectral maximum at the onset indicates that the material is magnetically
quasi-one-dimensional. Consideration of the wave vector dependence of the
scattering and polymeric structure further identifies the material as a
two-legged spin-1/2 ladder. Detailed comparison of the data to various models
of magnetism in this material based on the single mode approximation and the
continuous unitary transformation are presented. The latter theory provides an
excellent account of the data with leg exchange meV and
rung exchange meV.Comment: 10 pages, 11 figures, 1 tabl
Extended quantum critical phase in a magnetized spin-1/2 antiferromagnetic chain
Measurements are reported of the magnetic field dependence of excitations in
the quantum critical state of the spin S=1/2 linear chain Heisenberg
antiferromagnet copper pyrazine dinitrate (CuPzN). The complete spectrum was
measured at k_B T/J <= 0.025 for H=0 and H=8.7 Tesla where the system is ~30%
magnetized. At H=0, the results are in quantitative agreement with exact
calculations of the dynamic spin correlation function for a two-spinon
continuum. At high magnetic field, there are multiple overlapping continua with
incommensurate soft modes. The boundaries of these continua confirm
long-standing predictions, and the intensities are consistent with exact
diagonalization and Bethe Ansatz calculations.Comment: 4 pages, 4 figure
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