A crossed beam study of the reaction N/plus/ plus O2 yields NO/plus/ plus O

Studying reaction N/plus/ plus O2 yields NO/plus/ plus O as function of collision energy using crossed beam

Nonadiabatic Dynamics in Open Quantum-Classical Systems: Forward-Backward Trajectory Solution

A new approximate solution to the quantum-classical Liouville equation is derived starting from the formal solution of this equation in forward-backward form. The time evolution of a mixed quantum-classical system described by this equation is obtained in a coherent state basis using the mapping representation, which expresses $N$ quantum degrees of freedom in a 2N-dimensional phase space. The solution yields a simple non-Hamiltonian dynamics in which a set of $N$ coherent state coordinates evolve in forward and backward trajectories while the bath coordinates evolve under the influence of the mean potential that depends on these forward and backward trajectories. It is shown that the solution satisfies the differential form of the quantum-classical Liouville equation exactly. Relations to other mixed quantum-classical and semi-classical schemes are discussed.Comment: 28 pages, 1 figur

Possible Local Spiral Counterparts to Compact Blue Galaxies at Intermediate Redshift

We identify nearby disk galaxies with optical structural parameters similar to those of intermediate-redshift compact blue galaxies. By comparing HI and optical emission-line widths, we show that the optical widths substantially underestimate the true kinematic widths of the local galaxies. By analogy, optical emission-line widths may underrepresent the masses of intermediate-z compact objects. For the nearby galaxies, the compact blue morphology is the result of tidally-triggered central star formation: we argue that interactions and minor mergers may cause apparently compact morphology at higher redshift.Comment: 5 pages, uses emulateapj5 and psfig. To appear in ApJ

Effects of surface crossing in chemical reactions - The H3/plus/ system

Potential energy surfaces for singlet states of H3/plus

The Scalar Sector in 331 Models

We calculate the exact tree-level scalar mass matrices resulting from symmetry breaking using the most general gauge-invariant scalar potential of the 331 model, both with and without the condition that lepton number is conserved. Physical masses are also obtained in some cases, as well as couplings to standard and exotic gauge bosons.Comment: LaTex, 15 page

Risk and protective factors for meningococcal disease in adolescents: matched cohort study

Objective: To examine biological and social risk factors for meningococcal disease in adolescents. Design: Prospective, population based, matched cohort study with controls matched for age and sex in 1:1 matching. Controls were sought from the general practitioner. Setting: Six contiguous regions of England, which represent some 65% of the country’s population. Participants: 15-19 year olds with meningococcal disease recruited at hospital admission in six regions (representing 65% of the population of England) from January 1999 to June 2000, and their matched controls. Methods: Blood samples and pernasal and throat swabs were taken from case patients at admission to hospital and from cases and matched controls at interview. Data on potential risk factors were gathered by confidential interview. Data were analysed by using univariate and multivariate conditional logistic regression. Results: 144 case control pairs were recruited (74 male (51%); median age 17.6). 114 cases (79%) were confirmed microbiologically. Significant independent risk factors for meningococcal disease were history of preceding illness (matched odds ratio 2.9, 95% confidence interval 1.4 to 5.9), intimate kissing with multiple partners (3.7, 1.7 to 8.1), being a university student (3.4, 1.2 to 10) and preterm birth (3.7, 1.0 to 13.5). Religious observance (0.09, 0.02 to 0.6) and meningococcal vaccination (0.12, 0.04 to 0.4) were associated with protection. Conclusions: Activities and events increasing risk for meningococcal disease in adolescence are different from in childhood. Students are at higher risk. Altering personal behaviours could moderate the risk. However, the development of further effective meningococcal vaccines remains a key public health priority

Elucidating glycosaminoglycan–protein–protein interactions using carbohydrate microarray and computational approaches

Glycosaminoglycan polysaccharides play critical roles in many cellular processes, ranging from viral invasion and angiogenesis to spinal cord injury. Their diverse biological activities are derived from an ability to regulate a remarkable number of proteins. However, few methods exist for the rapid identification of glycosaminoglycan–protein interactions and for studying the potential of glycosaminoglycans to assemble multimeric protein complexes. Here, we report a multidisciplinary approach that combines new carbohydrate microarray and computational modeling methodologies to elucidate glycosaminoglycan–protein interactions. The approach was validated through the study of known protein partners for heparan and chondroitin sulfate, including fibroblast growth factor 2 (FGF2) and its receptor FGFR1, the malarial protein VAR2CSA, and tumor necrosis factor-α (TNF-α). We also applied the approach to identify previously undescribed interactions between a specific sulfated epitope on chondroitin sulfate, CS-E, and the neurotrophins, a critical family of growth factors involved in the development, maintenance, and survival of the vertebrate nervous system. Our studies show for the first time that CS is capable of assembling multimeric signaling complexes and modulating neurotrophin signaling pathways. In addition, we identify a contiguous CS-E-binding site by computational modeling that suggests a potential mechanism to explain how CS may promote neurotrophin-tyrosine receptor kinase (Trk) complex formation and neurotrophin signaling. Together, our combined microarray and computational modeling methodologies provide a general, facile means to identify new glycosaminoglycan–protein–protein interactions, as well as a molecular-level understanding of those complexes

Coherent dynamics of photoinduced nucleation processes

We study the dynamics of initial nucleation processes of photoinduced structural change of molecular crystals. In order to describe the nonadiabatic transition in each molecule, we employ a model of localized electrons coupled with a fully quantized phonon mode, and the time-dependent Schr\"odinger equation for the model is numerically solved. We found a minimal model to describe the nucleation induced by injection of an excited state of a single molecule in which multiple types of intermolecular interactions are required. In this model coherently driven molecular distortion plays an important role in the successive conversion of electronic states which leads to photoinduced cooperative phenomena.Comment: 14 pages, 5 figure

Internal kinematics of spiral galaxies in distant clusters. Part II. Observations and data analysis

We have conducted an observing campaign with FORS at the ESO-VLT to explore the kinematical properties of spiral galaxies in distant galaxy clusters. Our main goal is to analyse transformation- and interaction processes of disk galaxies within the special environment of clusters as compared to the hierarchical evolution of galaxies in the field. Spatially resolved MOS-spectra have been obtained for seven galaxy clusters at 0.3<z<0.6 to measure rotation velocities of cluster members. For three of the clusters, Cl0303+17, Cl0413-65, and MS1008-12, for which we presented results including a TF-diagram in Ziegler et al. 2003, we describe here in detail the observations and data analysis. Each of them was observed with two setups of the standard FORS MOS-unit.With typical exposure times of >2 hours we reach an S/N>5 in the emission lines appropriate for the deduction of the galaxies' internal rotation velocities from [OII], Hbeta, or [OIII] profiles. Preselection of targets was done on the basis of available redshifts as well as from photometric and morphological information gathered from own observations, archive data, and from the literature. Emphasis was laid on the definition of suitable setups to avoid the typical restrictions of the standard MOS unit for this kind of observations. In total we assembled spectra of 116 objects of which 50 turned out to be cluster members. Position velocity diagrams, finding charts as well as tables with photometric, spectral, and structural parameters of individual galaxies are presented.Comment: 18 pages, 6 figures, accepted for publication in Astronomy and Astrophysics. A version with full resolution figures can be downloaded from http://www.uni-sw.gwdg.de/~vwgroup/publications.htm