72 research outputs found

    A modern network approach to revisiting the positive and negative affective schedule (PANAS) construct validity

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    Introduction: The factor structure of the Positive and Negative Affective Schedule (PANAS) is still a topic of debate. There are several reasons why using Exploratory Graph Analysis (EGA) for scale validation is advantageous and can help understand and resolve conflicting results in the factor analytic literature. Objective: The main objective of the present study was to advance the knowledge regarding the factor structure underlying the PANAS scores by utilizing the different functionalities of the EGA method. EGA was used to (1) estimate the dimensionality of the PANAS scores, (2) establish the stability of the dimensionality estimate and of the item assignments into the dimensions, and (3) assess the impact of potential redundancies across item pairs on the dimensionality and structure of the PANAS scores. Method: This assessment was carried out across two studies that included two large samples of participants. Results and Conclusion: In sum, the results are consistent with a two-factor oblique structure.Fil: Flores Kanter, Pablo Ezequiel. Universidad Empresarial Siglo XXI; Argentina. Consejo Nacional de Investigaciones CientĂ­ficas y TĂ©cnicas; ArgentinaFil: Garrido, Luis Eduardo. Pontificia Universidad CatĂłlica Madre y Maestra; RepĂșblica DominicanaFil: Moretti, Luciana SofĂ­a. Universidad Empresarial Siglo XXI; Argentina. Pontificia Universidad CatĂłlica Madre y Maestra; RepĂșblica Dominicana. Consejo Nacional de Investigaciones CientĂ­ficas y TĂ©cnicas; ArgentinaFil: Medrano, Leonardo. Universidad Empresarial Siglo XXI; Argentina. Pontificia Universidad CatĂłlica Madre y Maestra; RepĂșblica Dominicana. Consejo Nacional de Investigaciones CientĂ­ficas y TĂ©cnicas; Argentin

    Zirconium phosphate phosphonate multilayered films based on push-pull stilbazolium salt: synthesis, characterization and second harmonic generation

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    The preparation of materials featuring enhanced second harmonic generation (SHG) values by self-assembly of molecules characterized by high second-order non-linear optic (NLO) activity is nowadays an important and challenging field of research. In order to show SHG the material must have an acentric structure with the dipoles of the molecular components oriented in the same direction and this is synthetically fairly difficult to achieve. This study describes the synthesis of the push\u2013pull stilbazolium salt 1 and its assembly in multilayered acentric thin films, on quartz glass surface, by using the zirconium phosphate/phosphonate (Zr-POx) technique. A particular care has been paid to the optimization of the surface preparation and of the deposition conditions. This allows to obtain highly homogeneous lamellar inorganic\u2013organic materials showing satisfactory second harmonic generation (SHG) values together with high chemical, thermal and mechanical stabilities which are necessary for their integration in optoelectronic devices
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