143 research outputs found
Mechanical properties of crosslinked poly/methyl methacrylate/ polymers under space environmental conditions quarterly technical summary report no. 3, dec. 1, 1963 - may 31, 1964
Mechanical properties of crosslinked polymethyl methacryalate polymers under space environmental condition
The Effect of Pressure on the Mechanical Properties of Polymers
Stress relaxation measurements were made as a function of temperature and hydrostatic pressure on two lightly filled elastomers (Hypalon 40 and Viton B), one highly filled elastomer (Neoprene WB), and on an EPDM rubber. The latter was not piezorheologioally simple. The lightly filled elastomers showed piezorheologically simple behavior, i.e. their response curves under different hydrostatic pressures could be superposed empirically by a simple horizontal shift along the logarithmic axis. The filled elastomer was piezorheologically simple only in the rubbery region and in the beginning of the transition region. The dependence of the empirical shift distances, log a_p , on P could not be described by either the Ferry-Stratton or the Bueche-O'Reilly equation. By considering the bulk modulus to be linearly related to pressure, a new equation has been developed for log a_(T,P) which describes the pressure dependence well and contains the WLF equation as a limiting case. Published data on the response of poly(vinyl chloride) under superposed hydrostatic pressure are shown to obey the new equation also.
The theoretical importance of the new equation lies in the fact that combination of the usual isobaric measurements at atmospheric pressure as function of temperature with isothermal measurements as function of pressure allows, in principle, all the molecular parameters required by the free volume theory to be determined unambiguously
Mechanical Properties of Crosslinked Poly/methyl Methacrylate/ Polymers Under Space Environmental Conditions Final Report, Jun. 1, 1963 - Jan. 30, 1966
Mechanical properties determined for cross linked polymethyl methacrylate under stress-relaxation test metho
Direct conversion of rheological compliance measurements into storage and loss moduli
We remove the need for Laplace/inverse-Laplace transformations of
experimental data, by presenting a direct and straightforward mathematical
procedure for obtaining frequency-dependent storage and loss moduli
( and respectively), from time-dependent experimental
measurements. The procedure is applicable to ordinary rheological creep
(stress-step) measurements, as well as all microrheological techniques, whether
they access a Brownian mean-square displacement, or a forced compliance. Data
can be substituted directly into our simple formula, thus eliminating
traditional fitting and smoothing procedures that disguise relevant
experimental noise.Comment: 4 page
Active Microrheology of Networks Composed of Semiflexible Polymers. II. Theory and comparison with simulations
Building on the results of our computer simulation (ArXiv cond-mat/0503573)we
develop a theoretical description of the motion of a bead, embedded in a
network of semiflexible polymers, and responding to an applied force. The
theory reveals the existence of an osmotic restoring force, generated by the
piling up of filaments in front of the moving bead and first deduced through
computer simulations. The theory predicts that the bead displacement scales
like x ~ t^alfa with time, with alfa=0.5 in an intermediate- and alfa=1 in a
long-time regime. It also predicts that the compliance varies with
concentration like c^(-4/3) in agreement with experiment.Comment: 18 pages and 2 figure
A new elastic potential function for rubbery materials
A new four-parameter elastic potential function is proposed which represents data on the elastic deformation of rubbery materials with the same parameters in various deformation fields up to break
Steady shear flow thermodynamics based on a canonical distribution approach
A non-equilibrium steady state thermodynamics to describe shear flows is
developed using a canonical distribution approach. We construct a canonical
distribution for shear flow based on the energy in the moving frame using the
Lagrangian formalism of the classical mechanics. From this distribution we
derive the Evans-Hanley shear flow thermodynamics, which is characterized by
the first law of thermodynamics relating infinitesimal
changes in energy , entropy and shear rate with kinetic
temperature . Our central result is that the coefficient is given by
Helfand's moment for viscosity. This approach leads to thermodynamic stability
conditions for shear flow, one of which is equivalent to the positivity of the
correlation function of . We emphasize the role of the external work
required to sustain the steady shear flow in this approach, and show
theoretically that the ensemble average of its power must be
non-negative. A non-equilibrium entropy, increasing in time, is introduced, so
that the amount of heat based on this entropy is equal to the average of
. Numerical results from non-equilibrium molecular dynamics simulation
of two-dimensional many-particle systems with soft-core interactions are
presented which support our interpretation.Comment: 23 pages, 7 figure
The macroscopic yield behaviour of polymers
A yield criterion, not previously compared with the actual macroscopic behaviour of polymers, is herein compared with the pressure-modified octahedral shear stress criterion earlier suggested by others. This new relation, which is a version of the von Mises criterion, accommodates differences in tensile and compressive yield strengths and accounts for any dependence of yielding on the hydrostatic component of the applied stress state.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/44784/1/10853_2004_Article_BF00550671.pd
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