Ultrafast Transient Dynamics of Adsorbates on Surfaces Deciphered: The Case of CO on Cu(100)

Time-resolved vibrational spectroscopy constitutes an invaluable experimental tool for monitoring hot-carrier induced surface reactions. However, the absence of a full understanding on the precise microscopic mechanisms causing the transient spectral changes has been limiting its applicability. Here we introduce a robust first-principles theoretical framework that successfully explains both the nonthermal frequency and linewidth changes of the CO internal stretch mode on Cu(100) induced by femtosecond laser pulses. Two distinct processes engender the changes: electron-hole pair excitations underlie the nonthermal frequency shifts, while electron-mediated vibrational mode coupling gives rise to linewidth changes. Furthermore, the origin and precise sequence of coupling events are finally identified.Comment: Article as accepted for publication in Physical Review Letters; 5 pages, 2 figures, 1 tabl

Pairing dynamics in strongly correlated superconductivity

Confirmation of the phononic origin of Cooper pair formation in superconductors came with the demonstration that the interaction was retarded and that the corresponding energy scales were associated with phonons. Using cellular dynamical mean-field theory for the two-dimensional Hubbard model, we identify such retardation effects in d-wave pairing and associate the corresponding energy scales with short-range spin fluctuations. We find which frequencies are relevant for pairing as a function of interaction strength and doping and show that the disappearance of superconductivity on the overdoped side coincides with the disappearance of the low energy feature in the antiferromagnetic fluctuations, as observed in neutron scattering experiments.Comment: LaTeX, 8 pages, 8 figure

Health and Information Technology

The healthcare industry continues to grow to meet demands of a changing environment and a growing number of people. Moreover, the Information Technology space continues to expand to meet customer’s needs and the continuing desire of people and companies to be the most technologically advanced. In order to allow the healthcare industry [or any industry] to continue to grow, it has to allow itself to expand with technology to help serve its customers more effectively. Through this partnership, it is possible for healthcare to become something more to its customers through more efficient and effective healthcare management

Recent Migration Patterns in Rural and Small Town Canada

Community/Rural/Urban Development, Labor and Human Capital,