295 research outputs found
Performance-Determining Factors for SiâGraphite Electrode Evaluation: The Role of Mass Loading and Amount of Electrolyte Additive
The mass loading of Siâgraphite electrodes is often considered as a parameter of secondary importance when testing their electrochemical performance. However, if a sacrificial additive is present in the electrolyte to improve the electrochemical performance, the electrode loading becomes the battery cycle-life-determining factor. The correlation between mass-loading, electrolyte additive, and binder type was investigated by analyzing the cycling behavior of Siâgraphite electrodes, prepared with water-based binders, with mass loading ranging from 3 to 9.5 mg cm and cycled with FEC electrolyte additive, while keeping electrolyte amount constant. A lower loading was obtained by keeping slurry preparation steps unchanged from binder to binder and resulted in a longer lifetime for some of the binders. When the final loading was kept constant instead, the performance became independent of the binder used. Since such results can lead to the misinterpretation of the influence of electrode components on the cycling stability (and to a preference of one binder over another in our case), we propose that a comparison of long-term electrochemical performance data of Siâgraphite electrodes needs to be always collected by using the same mass-loading with the constant electrolyte and additive
1 H Chemical Shift Imaging Methodenevaluation und Anwendung in vivo: Untersuchung der Hirnasymmetrie
Interphase formation with carboxylic acids as slurry additives for Si electrodes in Li-ion batteries. Part 1: performance and gas evolution
Rendering the solid electrolyte interphase and the inter-particle connections more resilient to volume changes of the active material is a key challenge for silicon electrodes. The slurry preparation in a buffered aqueous solution offers a strategy to increase the cycle life and capacity retention of silicon electrodes considerably. So far, studies have mostly been focused on a citrate buffer at pH = 3, and therefore, in this study a series of carboxylic acids is examined as potential buffers for slurry preparation in order to assess which chemical and physical properties of carboxylic acids are decisive for maximizing the capacity retention for Si as active material. In addition, the cycling stability of buffer-containing electrodes was tested in dependence of the buffer content. The results were complemented by analysis of the gas evolution using online electrochemical mass spectrometry in order to understand the SEI layer formation in presence of carboxylic acids and effect of high proton concentration
Hyperpolarized xenon nuclear spins detected by optical atomic magnetometry
We report the use of an atomic magnetometer based on nonlinear
magneto-optical rotation with frequency modulated light (FM NMOR) to detect
nuclear magnetization of xenon gas. The magnetization of a
spin-exchange-polarized xenon sample (cm at a pressure of bar,
natural isotopic abundance, polarization 1%), prepared remotely to the
detection apparatus, is measured with an atomic sensor (which is insensitive to
the leading field of 0.45 G applied to the sample; an independent bias field at
the sensor is G). An average magnetic field of nG induced by
the xenon sample on the 10-cm diameter atomic sensor is detected with
signal-to-noise ratio , limited by residual noise in the magnetic
environment. The possibility of using modern atomic magnetometers as detectors
of nuclear magnetic resonance and in magnetic resonance imaging is discussed.
Atomic magnetometers appear to be ideally suited for emerging low-field and
remote-detection magnetic resonance applications.Comment: 4 pages, 4 figure
Interphase formation with carboxylic acids as slurry additives for Si electrodes in Li-ion batteries. Part 2: a photoelectron spectroscopy study
The mass loading of Siâgraphite electrodes is often considered as a parameter of secondary importance when testing their electrochemical performance. However, if a sacrificial additive is present in the electrolyte to improve the electrochemical performance, the electrode loading becomes the battery cycle-life-determining factor. The correlation between mass-loading, electrolyte additive, and binder type was investigated by analyzing the cycling behavior of Siâgraphite electrodes, prepared with water-based binders, with mass loading ranging from 3 to 9.5 mg cm-2 and cycled with FEC electrolyte additive, while keeping electrolyte amount constant. A lower loading was obtained by keeping slurry preparation steps unchanged from binder to binder and resulted in a longer lifetime for some of the binders. When the final loading was kept constant instead, the performance became independent of the binder used. Because such results can lead to the misinterpretation of the influence of electrode components on the cycling stability (and to a preference of one binder over another in our case), we propose that a comparison of long-term electrochemical performance data of Siâgraphite electrodes needs to be always collected by using the same mass-loading with the constant electrolyte and additive
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