Heterogeneous physicochemistry of the winter polar stratosphere

Present chemical theories of the Antarctic ozone hole assume that heterogeneous reactions involving polar stratospheric clouds (PSCs) are the precursor of springtime ozone depletions. However, none of the theories quantify the rates of proposed heterogeneous processed, and none utilize the extensive data base on PSC's. Thus, all of the theories must be considered incomplete until the heterogeneous mechanisms are properly defined. A unified treatment developed of the cloud related processes, both physical and chemical, and the importance of these processes using observation data is calibrated. The rates are compared competitive heterogeneous processes to place reasonable limits on critical mechanisms such as the denitrification and dechlorination of the polar winter stratosphere. Among the subjects addressed here are the physical/chemical properties of PSC's including their relevant microphysical, optical and compositional characteristics, mass transfer rates of gaseous constituents to cloud particles, adsorption, accommodation and sticking coefficients on cloud particles, time constants for condensation, absorption and other microphysical processes, effects of solubility and vapor pressure on cloud composition, the statistics of cloud processing of chemically active condensible species, rate limiting steps in heterogeneous chemical reactions, and the nonlinear dependence of ozone loss on physical and chemical parameters

Topology, Quantum Gravity and Particle Physics

It is argued that quantum gravity has an interpretation as a topological field theory provided a certain constraint from the path intergral measure is respected. The constraint forces us to couple gauge and matter fields to gravity for space - time dimensions different from 3. We then discuss possible models which may be relevant to our universe.Comment: 18 pages, LaTeX. Replaced version corrects typos and has additional reference

Long term time-lapse microgravity and geotechnical monitoring of relict salt-mines, Marston, Cheshire, UK.

The area around the town of Northwich in Cheshire, U. K., has a long history of catastrophic ground subsidence caused by a combination of natural dissolution and collapsing abandoned mine workings within the underlying Triassic halite bedrock geology. In the village of Marston, the Trent and Mersey Canal crosses several abandoned salt mine workings and previously subsiding areas, the canal being breached by a catastrophic subsidence event in 1953. This canal section is the focus of a long-term monitoring study by conventional geotechnical topographic and microgravity surveys. Results of 20 years of topographic time-lapse surveys indicate specific areas of local subsidence that could not be predicted by available site and mine abandonment plan and shaft data. Subsidence has subsequently necessitated four phases of temporary canal bank remediation. Ten years of microgravity time-lapse data have recorded major deepening negative anomalies in specific sections that correlate with topographic data. Gravity 2D modeling using available site data found upwardly propagating voids, and associated collapse material produced a good match with observed microgravity data. Intrusive investigations have confirmed a void at the major anomaly. The advantages of undertaking such long-term studies for near-surface geophysicists, geotechnical engineers, and researchers working in other application areas are discussed

The NASA-Ames Research Center stratospheric aerosol model. 2. Sensitivity studies and comparison with observatories

Sensitivity tests were performed on a one-dimensional, physical-chemical model of the unperturbed stratospheric aerosols, and model calculations were compared with observations. The tests and comparisons suggest that coagulation controls the particle number mixing ratio, although the number of condensation nuclei at the tropopause and the diffusion coefficient at high altitudes are also important. The sulfur gas source strength and the aerosol residence time are much more important than the supply of condensation nuclei in establishing mass and large particle concentrations. The particle size is also controlled mainly by gas supply and residence time. In situ observations of the aerosols and laboratory measurements of aerosols, parameters that can provide further information about the physics and chemistry of the stratosphere and the aerosols found there are provided

The NASA-AMES Research Center Stratospheric Aerosol Model. 1. Physical Processes and Computational Analogs

A time-dependent one-dimensional model of the stratospheric sulfate aerosol layer is presented. In constructing the model, a wide range of basic physical and chemical processes are incorporated in order to avoid predetermining or biasing the model predictions. The simulation, which extends from the surface to an altitude of 58 km, includes the troposphere as a source of gases and condensation nuclei and as a sink for aerosol droplets. The size distribution of aerosol particles is resolved into 25 categories with particle radii increasing geometrically from 0.01 to 2.56 microns such that particle volume doubles between categories

Ice in the Antarctic polar stratosphere

On six occasions during the 1987 Airborne Antarctic Ozone Experiment, the Polar Stratospheric Cloud (PSC) ice crystals were replicated over the Palmer Peninsula at approximately 70 deg South. The sampling altitude was approximately 60 to 65 thousand feet, the temperature range was -83.5 to -72C and the atmosphere was subsaturated in all cases. The collected crystals were predominantly complete and hollow prismatic columns with maximum dimensions up to 217 microns. Evidence of scavenging of submicron particles was detected on several crystals. While the replicated crystal sizes were larger than anticipated, their relatively low concentration results in a total surface area less than one tenth that of the sampled aerosol particles. The presence of large crystals suggest that PSC ice crystals can play a very important role in stratospheric dehydration processes

Stratospheric aerosol modification by supersonic transport operations with climate implications

The potential effects on stratospheric aerosois of supersonic transport emissions of sulfur dioxide gas and submicron size soot granules are estimated. An interactive particle-gas model of the stratospheric aerosol is used to compute particle changes due to exhaust emissions, and an accurate radiation transport model is used to compute the attendant surface temperature changes. It is shown that a fleet of several hundred supersonic aircraft, operating daily at 20 km, could produce about a 20% increase in the concentration of large particles in the stratosphere. Aerosol increases of this magnitude would reduce the global surface temperature by less than 0.01 K

Comparative Planetary Atmospheres: Models of TrES-1 and HD209458b

We present new self-consistent atmosphere models for transiting planets TrES-1 and HD209458b. The planets were recently observed with the Spitzer Space Telescope in bands centered on 4.5 and 8.0 $\mu$m, for TrES-1, and 24 $\mu$m, for HD209458b. We find that standard solar metallicity models fit the observations for HD209458b. For TrES-1, which has an T_eff ~300 K cooler, we find that models with a metallicity 3-5 times enhanced over solar abundances can match the 1$\sigma$ error bar at 4.5 $\mu$m and 2$\sigma$ at 8.0$\mu$m. Models with solar abundances that included energy deposition into the stratosphere give fluxes that fall within the 2$\sigma$ error bars in both bands. The best-fit models for both planets assume that reradiation of absorbed stellar flux occurs over the entire planet. For all models of both planets we predict planet/star flux ratios in other Spitzer bandpasses.Comment: Accepted to the Astrophysical Journal Letters, May 17, 200

New observations of stratospheric N2O5

The unequivocal detection of N2O5 in the stratosphere was reported by Toon et al. based on measurements of the absorption by the N2O5 bands at 1246 and 1720/cm in solar occulation spectra recorded at sunrise near 47 S latitude by the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment during the Spacelab 3 (SL3) shuttle mission. Additional measurements and analysis of stratospheric N2O5 derived from the ATMOS/SL3 spectra are reported. The primary results are the detection and measurement of N2O5 absorption at sunset in the lower stratosphere, the inversion of a precise (approximately 10 percent) N2O5 sunrise vertical distribution between 25.5 and 37.5 km altitude, and the identification and measurement of absorption by the N2O5 743/cm band at sunrise. Assuming 4.32 x 10(sup -17) and 4.36 x 10(sup -17)/cm/molecule/sq cm respectively for the integrated intensities of the 1246 and 743/cm bands at stratospheric temperatures, retrieved volume mixing ratios in parts per billion by volume (ppbv) at sunrise (47 S latitude) are 1.32 + or - 0.34 at 37.5 km, 1.53 + or - 0.35 at 35.5 km, 1.63 + or - 0.36 at 33.5 km, 1.60 + or - 0.34 at 31.5 km, 1.43 + or - 0.30 at 29.5 km, 1.15 + or - 0.24 at 27.5 km, and 0.73 + or - 0.15 at 25.5 km. Retrieved VMRs in ppbv at sunset (30 N latitude) are 0.13 + or - 0.05 at 29.5 km, 0.14 + or - 0.05 at 27.5 km, and 0.10 + or - 0.04 at 25.5 km. Quoted error limits (1 sigma) include the error in the assumed band intensities (approximately 20 percent). Within the error limits of the measurements, the inferred mixing ratios at sunrise agree with diurnal photochemical model predictions obtained by two groups using current photochemical data. The measured mixing ratios at sunset are lower than the model predictions with differences of about a factor of 2 at 25 km altitude

Nitric acid scavenging by mineral and biomass burning aerosols

The abundance of gas phase nitric acid in the upper troposphere is overestimated by global chemistry-transport models, especially during the spring and summer seasons. Recent aircraft data obtained over the central US show that mineral aerosols were abundant in the upper troposphere during spring. Chemical reactions on mineral dust may provide an important sink for nitric acid. In regions where the mineral dust abundance is low in the upper troposphere similar HNO3 removal processes may occur on biomass burning aerosols. We propose that mineral and biomass burning aerosols may provide an important global sink for gas phase nitric acid, particularly during spring and summer when aerosol composition in the upper troposphere may be greatly affected by dust storms from east Asia or tropical biomass burning plumes