Prospective Life Cycle Assessment of a Model Magnesium Battery

Energy-storage systems are considered as a key technology for energy and mobility transition. Because traditional batteries have many drawbacks, there are tremendous efforts to develop so-called postlithium systems. The magnesium-sulfur (MgS) battery emerges as one alternative. Previous studies of Mg-S batteries have addressed the environmental footprint of its production. However, the potential impacts of the use-phase are not considered yet, due to its premature stage of development. Herein, a first prospective look at the potential environmental performance of a theoretical Mg-S battery for different use-phase applications is given to fill this gap. By means of the life cycle assessment (LCA) methodology, an analysis of different scenarios and a comparison with other well-established technologies are conducted. The results suggest that the environmental footprint of the Mg-S is comparable with that of the commercially available counterparts and potentially outperforms them in several impact categories. However, this can only be achieved if a series of technical challenges are first overcome

Environmental assessment of a new generation battery: The magnesium-sulfur system

As environmental concerns mostly drive the electrification of our economy and the corresponding increase in demand for battery storage systems, information about the potential environmental impacts of the different battery systems is required. However, this kind of information is scarce for emerging post-lithium systems such as the magnesium-sulfur (MgS) battery. Therefore, we use life cycle assessment following a cradle-to-gate perspective to quantify the cumulative energy demand and potential environmental impacts per Wh of the storage capacity of a hypothetical MgS battery (46 Wh/kg). Furthermore, we also estimate global warming potential (0.33 kg CO2 eq/Wh) , fossil depletion potential (0.09 kg oil eq / Wh), ozone depletion potential (2.5E-08 kg CFC-11/Wh) and metal depletion potential (0.044 kg Fe eq/Wh), associated with the MgS battery production. The battery is modelled based on an existing prototype MgS pouch cell and hypothetically optimised according to the current state of the art in lithium-ion batteries (LIB), exploring future improvement potentials. It turns out that the initial (non-optimised) prototype cell cannot compete with current LIB in terms of energy density or environmental performance, mainly due to the high share of non-active components, decreasing its performance substantially. Therefore, if the assumed evolutions of the MgS cell composition are achieved to overcome current design hurdles and reach a comparable lifespan, efficiency, cost and safety levels to that of existing LIB; then the MgS battery has significant potential to outperform both existing LIB, and lithium-sulfur batteries