Symmetry relations in chemical kinetics arising from microscopic reversibility

It is shown that the kinetics of time-reversible chemical reactions having the same equilibrium constant but different initial conditions are closely related to one another by a directly measurable symmetry relation analogous to chemical detailed balance. In contrast to detailed balance, however, this relation does not require knowledge of the elementary steps that underlie the reaction, and remains valid in regimes where the concept of rate constants is ill-defined, such as at very short times and in the presence of low activation barriers. Numerical simulations of a model of isomerization in solution are provided to illustrate the symmetry under such conditions, and potential applications in protein folding-unfolding are pointed out.Comment: 4 pages, 1 figure, accepted to Phys Rev Let

T-spheres as a limit of Lemaitre-Tolman-Bondi solutions

In the Tolman model there exist two quite different branches of solutions - generic Lemaitre-Tolman-Bondi (LTB) ones and T-spheres as a special case. We show that, nonetheless, T-spheres can be obtained as a limit of the class of LTB solutions having no origin and extending to infinity with the areal radius approaching constant. It is shown that all singularities of T-models are inherited from those of corresponding LBT solutions. In doing so, the disc type singularity of a T-sphere is the analog of shell-crossing.Comment: 6 pages. 1 Reference added. To appear in Phys. Rev.

Entropic Accelerating Universe

To accommodate the observed accelerated expansion of the universe, one popular idea is to invoke a driving term in the Friedmann-Lemaitre equation of dark energy which must then comprise 70% of the present cosmological energy density. We propose an alternative interpretation which takes into account the entropy and temperature intrinsic to the horizon of the universe due to the information holographically stored there. Dark energy is thereby obviated and the acceleration is due to an entropic force naturally arising from the information storage on the horizon surface screen. We consider an additional quantitative approach inspired by surface terms in general relativity and show that this leads to the entropic accelerating universe.Comment: 14 pages, 1 figure, extended and clarifie

Quintessence and phantom cosmology with non-minimal derivative coupling

We investigate cosmological scenarios with a non-minimal derivative coupling between the scalar field and the curvature, examining both the quintessence and the phantom cases in zero and constant potentials. In general, we find that the universe transits from one de Sitter solution to another, determined by the coupling parameter. Furthermore, according to the parameter choices and without the need for matter, we can obtain a Big Bang, an expanding universe with no beginning, a cosmological turnaround, an eternally contracting universe, a Big Crunch, a Big Rip avoidance and a cosmological bounce. This variety of behaviors reveals the capabilities of the present scenario.Comment: 8 pages, 8 figure

Persistence of black holes through a cosmological bounce

We discuss whether black holes could persist in a universe which recollapses and then bounces into a new expansion phase. Whether the bounce is of classical or quantum gravitational origin, such cosmological models are of great current interest. In particular, we investigate the mass range in which black holes might survive a bounce and ways of differentiating observationally between black holes formed just after and just before the last bounce. We also discuss the consequences of the universe going through a sequence of dimensional changes as it passes through a bounce.Comment: 8 pages, 1 figur

Alternative Methods of Describing Structure Formation in the Lemaitre-Tolman Model

We describe several new ways of specifying the behaviour of Lemaitre-Tolman (LT) models, in each case presenting the method for obtaining the LT arbitrary functions from the given data, and the conditions for existence of such solutions. In addition to our previously considered `boundary conditions', the new ones include: a simultaneous big bang, a homogeneous density or velocity distribution in the asymptotic future, a simultaneous big crunch, a simultaneous time of maximal expansion, a chosen density or velocity distribution in the asymptotic future, only growing or only decaying fluctuations. Since these conditions are combined in pairs to specify a particular model, this considerably increases the possible ways of designing LT models with desired properties.Comment: Accepted by Phys Rev D. RevTeX 4, 13 pages, no figures. Part of a series: gr-qc/0106096, gr-qc/0303016, gr-qc/0309119. Replacement contains very minor correction

Energy dependence on fractional charge for strongly interacting subsystems

The energies of a pair of strongly-interacting subsystems with arbitrary noninteger charges are examined from closed and open system perspectives. An ensemble representation of the charge dependence is derived, valid at all interaction strengths. Transforming from resonance-state ionicity to ensemble charge dependence imposes physical constraints on the occupation numbers in the strong-interaction limit. For open systems, the chemical potential is evaluated using microscopic and thermodynamic models, leading to a novel correlation between ground-state charge and an electronic temperature.Comment: 4 pages, 3 figs.; as accepted (Phys. Rev. Lett.