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    ИССЛЕДОВАНИЕ ВЗАИМОСВЯЗИ МЕЖДУ ЭЛЕМЕНТНЫМ СОСТАВОМ ВИНОГРАДА И ПОЧВОЙ РЕГИОНА ЕГО ПРОИЗРАСТАНИЯ

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    The influence of the grape variety and the viticultural area soils on the element content of gathered grapes was investigated, and their correlation was examined. The possible transition of metal mobile forms from the soils to the grapes was investigated based on the multi element analysis of the commercial grape samples including Cabernet Sauvignon, Riesling, Merlot and Muscat Ottonel, which were gathered from the grape fields of Krasnodar Region wineries, and soils of their cultivation. The methodical features, related to the determination of elements in the analyzed samples by ICP-AES, were discussed. The discriminant analysis was applied to the gathered data which allowed separating different viticultural areas and grape varieties with probabilities of 97 % и 94 % respectively. The canonical analysis was applied for the investigation of the correlation between the various levels in the multidimensional data. It showed the existence of the significant correlation (R = 0.95; p 0.001) between multi element contents of soil-grape systems. The relationship between the elemental contents of soil and grapes was defined, and it could be used for the determination of the production region origin for the specific grape variety.Keywords: grapes and soil, regional origin, discriminant and canonical analysis.(Russian)DOI: http://dx.doi.org/10.15826/analitika.2016.20.2.004 V.O. Titarenko1, A.A. Kaunova1, Z.A. Temerdashev1*, V. G. Popandopulo 2 1Kuban State University, ul. Stavropol’skaia., 149, Krasnodar, 350040, Russian Federation2JSC APF "Fanagoria",  ul. Mira St,49, Sennoi, Temriuk Rayon, Krasnodar Krai, 353540, Russian FederationИсследовано влияние сорта и почвы региона возделывания на элементный состав собранного винограда, рассмотрена их взаимосвязь. На основе многоэлементного анализа образцов винограда технических сортов Каберне Совиньон, Рислинг, Мерло и Мускат Оттонель, собранных с полей винодельческих предприятий Краснодарского края, а также почв, используемых для их возделывания, изучен возможный переход подвижных форм металлов из почв в виноград. Обсуждены методические особенности, связанные с определением элементов в анализируемых образцах методом ИСП-АЭС. К полученным данным применен дискриминантный анализ, позволивший с вероятностью 97 и 94 % разделить различные изучаемые участки виноградарства и сорта винограда, соответственно. Для изучения корреляции между различными данными на многомерном уровне применен канонический анализ, показавший наличие значимой корреляции (R = 0.95; p 0.001) между многоэлементными составами системы «почва – виноград». Выявлена взаимосвязь между элементным составом почв и винограда, которая может быть использована для установления региональной принадлежности продукции, полученной из конкретного сорта винограда.Ключевые слова: виноград и почвы, региональная принадлежность, дискриминантный и канонический анализ. DOI: http://dx.doi.org/10.15826/analitika.2016.20.2.00

    Явление социопатичного поведения как проблема для существования и развития современного украинского общества. Задание и возможности социальной работы и коррекции

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    Головна ідея запропонованої статті полягає у тому, аби привернути увагу до такого феномену соціального буття сьогодення як соціопатична (психопатична) поведінка окремих особистостей. Складний, суперечливий характер вищезазначеного явища потребує інноваційного системного підходу з боку усіх безпосередньо задіяних у профілактиці та корекції небажаних опцій фахівців – чільне місце серед яких посідають соціальні працівники.The main idea of this article concerns the complex and sophisticated character of such danger mode of the social behaviour like so-called “public killer” with their antisocial activity. The main direction of the solving these questions are exists in the new systems of quality preparations for social worker as a consulter and manager person in our everyday common practice.Основной идеей данной статьи выступает утверждение авторов о сложном комплексном характере такого вида отклоняющегося поведения, как социопатическое. Для предупреждения и управления угрозами, которые оно несет с собою, необходимо по-новому подходить к вопросам подготовки специалистов по социальной работе, сосредоточившись на профессиональных качествах их квалификационного роста

    Investigation of the correlation between the elemental content of grapes and the soil of the region of its growth

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    Исследовано влияние сорта и почвы региона возделывания на элементный состав собранного винограда, рассмотрена их взаимосвязь. На основе многоэлементного анализа образцов винограда технических сортов Каберне Совиньон, Рислинг, Мерло и Мускат Оттонель, собранных с полей винодельческих предприятий Краснодарского края, а также почв, используемых для их возделывания, изучен возможный переход подвижных форм металлов из почв в виноград. Обсуждены методические особенности, связанные с определением элементов в анализируемых образцах методом ИСП-АЭС. К полученным данным применен дискриминантный анализ, позволивший с вероятностью 97 и 94 % разделить различные изучаемые участки виноградарства и сорта винограда, соответственно. Для изучения корреляции между различными данными на многомерном уровне применен канонический анализ, показавший наличие значимой корреляции ( R = 0.95; p < 0.001) между многоэлементными составами системы «почва - виноград». Выявлена взаимосвязь между элементным составом почв и винограда, которая может быть использована для установления региональной принадлежности продукции, полученной из конкретного сорта винограда.The influence of the grape variety and the viticultural area soils on the element content of gathered grapes was investigated, and their correlation was examined. The possible transition of metal mobile forms from the soils to the grapes was investigated based on the multi element analysis of the commercial grape samples including Cabernet Sauvignon, Riesling, Merlot and Muscat Ottonel, which were gathered from the grape fields of Krasnodar Region wineries, and soils of their cultivation. The methodical features, related to the determination of elements in the analyzed samples by ICP-AES, were discussed. The discriminant analysis was applied to the gathered data which allowed separating different viticultural areas and grape varieties with probabilities of 97 % и 94 % respectively. The canonical analysis was applied for the investigation of the correlation between the various levels in the multidimensional data. It showed the existence of the significant correlation ( R = 0.95; p < 0.001) between multi element contents of soil-grape systems. The relationship between the elemental contents of soil and grapes was defined, and it could be used for the determination of the production region origin for the specific grape variety

    ВИНОГРАДНЫЕ ВИНА, ПРОБЛЕМЫ ОЦЕНКИ ИХ КАЧЕСТВА И РЕГИОНАЛЬНОЙ ПРИНАДЛЕЖНОСТИ

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    The analysis of articles and normative documents for quality control and regional origin of wines was carried out. Chemical composition of the grapes and the wine has been considered, qualitative and quantitative changes during vinification, maturation and aging of wine were shown. The basic group of compounds contents and ratios which determine the qualitative characteristics of wines, as well as have an important role in the formation of aroma and taste of the drink was found. The prerequisites for the development of the market of counterfeit products and wine falsification methods were discussed. The analysis of scientific literature and regulatory framework governing the quality of the wines on the territory of Russia and the European Union and the existing approaches to determine their authenticity was conducted, the advantages and disadvantages are shown. The examples of using different criteria for the establishment of natural and adulterated wines have been discussed, as well as their approaches to identify and create a comprehensive system of wine production quality evaluation using methods of physicochemical analysis. The main methodological approaches to establish a wine regional origin, combining the capabilities of modern methods of analysis, mathematical modeling and statistics are analyzed, examples of their use in practice are shown.Keywords: wine, methods of analysis, quality, authenticity, regional origin, falsification, mathematical modeling (Russian)DOI: http://dx.doi.org/10.15826/analitika.2014.18.4.001 Yu.F. Yakuba1, A.A. Kaunova2, Z.A. Temerdashev2, V.O. Titarenko2, A.A. Halafjan2 1North Caucasian Regional Research Institute of Horticulture and Viticulture of the Russian Academy of Agricultural Sciences, Krasnodar, Russian Federation2 Kuban State University, Krasnodar, Russian FederationREFERENCES1. 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Compositional changes during the storage of red wines treated with pectolytic enzymes: low molecular-weight phenols and flavan-3-ol derivative levels. Food Chemistry, 2003, vol. 80, pp. 205-214.44. Piermattei B., Amatti A., Castellari M. Preliminary studies on the use of dried grape stems in red winemaking. Vitis: Viticult., 2000, vol. 39, no. 1-2, pp. 4-46.45. Oganesiants L.A. Dub i vinodelie [Oak and winemaking]. Moscow, Agropishchepromizdat, 2001. 359 p. (in Russian).46. del Alamo Sanza M., Dominguez I. Nevares, Corcel L.M. Analysis for low molecular weight phenolic compounds in a red wine aged in oak chips. Anal. Chim. Acta, 2004, vol. 513, pp. 229-237.47. Atanasova V., Fulcrand H., Cheynier V. Effect of oxygenation on polyphenol changes occurring in the course of wine-making. Anal. Chim. Acta, 2002, vol. 458, pp. 15-27.48. Mateus N., Freitas V. De Evolution and stability of anthycyanin-derived pigments during port wine aging. J. Agr. and Food Chem., 2001, vol. 49, no. 11, pp. 5217-5222.49. Magomedov Z.B., Makuev G.A. [Coloring and phenolics substances varieties of grapes and the dynamics of their content in wines with aging]. Khranenie i pererabotka sel‘khozsyr‘ia [Storage and processing of agricultural], 2001, no. 10, pp. 51-50 (in Russian).50. GOST R 55242-2012. Vina zashchishchennykh geograficheskikh ukazanii i vina zashchishchennykh naimenovanii mesta proiskhozhdeniia. Obshchie tekhnicheskie usloviia [State Standard 55242-2012. Wines from protected geographical indications and wines with a protected place of origin. General specifications]. Moscow, Standartinform Publ., 2013. 12 p. (in Russian).51. GOST R 52523–2006. Vina stolovye i vinomaterialy stolovye. Obshchie tekhnicheskie usloviia [State Standard 52523–2006. Table wines and wine materials. General specifications]. Moscow, Standartinform Publ., 2008. 12 p. (in Russian).52. GOST R 52195–2003. Vina aromatizirovannye. Obshchie tekhnicheskie usloviia [State Standard 52195–2003. Flavored wine. General specifications]. Moscow, Standartinform Publ., 2009. 8 p. (in Russian).53. GOST R 52404–2005. Vina spetsial‘nye i vinomaterialy spetsial‘nye. Obshchie tekhnicheskie usloviia [State Standard 52404–2005. Wines and special wine materials. General specifications]. Moscow, Standartinform Publ., 2006. 8 p. (in Russian).54. GOST R 51158–2009. Vina igristye. Obshchie tekhnicheskie usloviia [State Standard 51158–2009. Sparkling wines. General specifications]. Moscow, Standartinform Publ., 2009. 8 p. (in Russian).55. SanPiN 2.3.2.1078–01. Gigienicheskie trebovaniia bezopasnosti i pishchevoi tsennosti pishchevykh produktov [Sanitary Standard 2.3.2.1078–01. Hygienic safety and nutritional value of foods]. 144 p. (in Russian).56. Nikolaeva M.A., Polozhishnikova M.A. Identifikatsiia i obnaruzhenie fal‘sifikatsii prodovol‘stvennykh tovarov: uchebnoe posobie [Identification and determination of falsification of food products: a tutorial]. Moscow, «FORUM»: INFRA-M Publ., 2009. 464 p. (in Russian).57. Holmberg L. Wine fraud. International Journal of Wine Research, 2010, vol. 2, pp. 105-113. doi: 10.2147/IJWR.S14102.58. Martin G.J. The chemistry of chaptalization. Endowour, New Series, 1990, vol. 14, no. 3. pp. 137-143. doi: 10.1016/0160-9327(90)90007-E.59. Ogrinc N., Kosir I.J., Spangenberg J.E., Kidric J. The application of NMR and MS methods for detection of adulteration of wine, fruit juices, and olive oil. A review. Anal. Bioanal. Chem., 2003, vol. 376, pp. 424-430. doi: 10.1007/s00216-003-1804-6.60. Savchuk S.A., Vlasov V.N. [Identification of wine products using high performance liquid chromatography and spectrometry]. Vinograd i vino Rossii [Grapes and wine Russia], 2000, no. 5, pp. 5-13 (in Russian).61. GOST R 51149–98. Produkty vinodel‘cheskoi promyshlennosti. Upakovka, markirovka, transportirovanie i khranenie [State Standard 51149–98. Wine industry products. Packaging, labeling, transportation and storage]. Moscow, Standartinform Publ., 2009. 6 p. (in Russian).62. GOST R 51074-2003. Produkty pishchevye. Informatsiia dlia potrebitelia. Obshchie trebovaniia [State Standard 51074-2003. Foodstuffs. Information for Consumers. general requirements]. Moscow, Standartinform Publ., 2006. 23 p. (in Russian).63. GOST R 51653-2000. Alkogol‘naia produktsiia i syr‘e dlia ee proizvodstva. Metod opredeleniia ob«emnoi doli еtilovogo spirta [State Standard 51653-2000. Alcoholic products and raw materials for its production. Method of determining of the ethanol volume fraction]. Moscow, Standartinform Publ., 2009. 6 p. (in Russian).64. GOST 13192-73. Vina, vinomaterialy i kon‘iaki. Metod opredeleniia sakharov [State Standard 13192-73. Wine, brandy and wine materials. Method of sugars determination]. Moscow, Standartinform Publ., 2011. 10 p. (in Russian).65. GOST R 51621-2000. Alkogol‘naia produktsiia i syr‘e dlia ee proizvodstva. Metody opredeleniia massovoi kontsentratsii titruemykh kislot [State Standard 51621-2000. Alcoholic products and raw materials for its production. Methods of determination of the mass concentration of titratable acid]. Moscow, Standartinform Publ., 2009. 5 p. (in Russian).66. GOST R 51654-2000. Alkogol‘naia produktsiia i syr‘e dlia ee proizvodstva. Metod opredeleniia massovoi kontsentratsii letuchikh kislot [State Standard 51654-2000. Alcoholic products and raw materials for its production. Method of determination of the mass concentration of volatile acids]. Moscow, Standartinform Publ., 2009. 7 p. (in Russian).67. GOST R 51620-2000. Alkogol‘naia produktsiia i syr‘e dlia ee proizvodstva. Metod opredeleniia massovoi kontsentratsii privedennogo еkstrakta [State Standard 51620-2000. Alcoholic products and raw materials for its production. Method of determination of the mass concentration of the powered extract]. Moscow, Standartinform Publ., 2009. 6 p. (in Russian).68. GOST R 52391-2005. Produktsiia vinodel‘cheskaia. Metod opredeleniia massovoi kontsentratsii limonnoi kisloty [State Standard 52391-2005. Wine products. Method of determination of the mass concentration of citric acid]. Moscow, Standartinform Publ., 2007. 8 p. (in Russian).69. GOST R 51655-2000. Alkogol‘naia produktsiia i syr‘e dlia ee proizvodstva. Metod opredeleniia massovoi kontsentratsii svobodnogo i obshchego dioksida sery [State Standard 51655-2000. Alcoholic products and raw materials for its production. Method of determination of free and total sulfur dioxide]. Moscow, Standartinform Publ., 2009. 6 p. (in Russian).70. GOST R 51766-2001. Syr‘e i produkty pishchevye. Atomno-absorbtsionnyi metod opredeleniia mysh‘iaka [State Standard 51766-2001. Raw materials and food products. Determination of arsenic using Atomic absorption spectroscopy]. 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