Radiolytic reactions in the coolant of helium cooled reactors

The success of helium cooled reactors is dependent upon the ability to prevent significant reaction between the coolant and the other components in the reactor primary circuit. Since the thermal reaction of graphite with oxidizing gases is rapid at temperatures of interest, the thermal reactions are limited primarily by the concentration of impurity gases in the helium coolant. On the other hand, the rates of radiolytic reactions in helium are shown to be independent of reactive gas concentration until that concentration reaches a very low level. Calculated steady-state concentrations of reactive species in the reactor coolant and core burnoff rates are presented for current U. S. designed, helium cooled reactors. Since precise base data are not currently available for radiolytic rates of some reactions and thermal reaction rate data are often variable, the accuracy of the predicted gas composition is being compared with the actual gas compositions measured during startup tests of the Fort Saint Vrain high temperature gas-cooled reactor. The current status of these confirmatory tests is discussed. 12 references. (auth

Elevated CO2 and O3 Effects on Fine-Root Life Span in Ponderosa Pine

Atmospheric carbon dioxide (CO2) and ozone (O3) concentrations are rising, which may have opposing effects on tree C balance and allocation to fine roots. More information is needed on interactive CO2 and O3 effects on roots, particularly fine-root life span, a critical demographic parameter and determinant of soil C and N pools and cycling rates. We conducted a study in which ponderosa pine (Pinus ponderosa) seedlings were exposed to two levels of CO2 and O3 in sun-lit controlled-environment terracosms for three years. Minirhizotrons were used to monitor individual fine roots in three soil horizons every 28 days. Proportional hazards regression was used to analyze effects of CO2, O3, diameter, depth, and season of root initiation on fine-root survivorship. More fine roots were produced in the elevated CO2 treatment than in ambient CO2. Median life spans varied from 140-448 days depending on the season of root initiation. Elevated CO2, increasing root diameter, and increasing root depth all significantly increased fine-root survivorship and median life span. Life span was slightly, but not significantly, lower in elevated O3, and increased O3 did not reduce the effect of elevated CO2. These results indicate the potential for elevated CO2 to increase the number of fine roots and their residence time in the soil, which is also affected by root diameter, root depth, and phenology

Isotope powered Stirling generator for terrestrial applications

An electric power supply, small enough to be man-portable, is being developed for remote, terrestrial applications. This system is designed for an operating lifetime of five years without maintenance or refueling. A small Radioisotope Stirling Generator (RSG) has been developed. The energy source of the generator is a 60 watt plutonium-238 fuel clad used in the General Purpose Heat Sources (GPHS) developed for space applications. A free piston Stirling Engine drives a linear alternator to convert the heat to power. The system weighs about 7.5 kg and produces 11 watts AC power with a conversion efficiency of 18.5%. Two engine models have been designed, fabricated, and tested to date: (a) a developmental model instrumented to confirm and test parameters, and (b) an electrically heated model with an electrical heater equipped power input leads. Critical components have been tested for 10,000 to 20,000 hours. One complete generator has been operating for over 11,000 hours. Radioisotope heated prototypes are expected to be fabricated and tested in late 1995

Ion implantation of krypton in sputter-deposited metal matrices

Krypton 85 has been successfully stored in a metal matrix by bombarding the metal surface with krypton ions while the metal is being deposited by sputtering. The krypton is thus incorporated into the metal in concentrations approaching 200 cm/sup 3/ of Kr(STP)cm/sup 3/ of deposit. Cost estimates of a facility to perform this work are given. (GHT

Compressional and extensional tectonics in low-medium pressure granulites from the Larsemann Hills, east Antarctica

AbstractMeta-sediments in the Larsemann Hills that preserve a coherent stratigraphy, form a cover sequence deposited upon basement of mafic–felsic granulite. Their outcrop pattern defines a 10 kilometre wide east–west trending synclinal trough structure in which basement–cover contacts differ in the north and the south, suggesting tectonic interleaving during a prograde, D1 thickening event. Subsequent conditions reached low-medium pressure granulite grade, and structures can be divided into two groups, D2 and D3, each defined by a unique lineation direction and shear sense. D2 structures which are associated with the dominant gneissic foliation in much of the Larsemann Hills, contain a moderately east-plunging lineation indicative of west-directed thrusting. D2 comprises a colinear fold sequence that evolved from early intrafolial folds to late upright folds. D3 structures are associated with a high-strain zone, to the south of the Larsemann Hills, where S3 is the dominant gneissic layering and folds sequences resemble D2 folding. Outside the D3 high-strain zone occurs a low-strain D3 window, preserving low-strain D3 structures (minor shear bands and upright folds) that partly re-orient D2 structures. All structures are truncated by a series of planar pegmatites and parallel D4 mylonite zones, recording extensional dextral displacements.D2 assemblages include coexisting garnet–orthopyroxene pairs recording peak conditions of ∼ 7 kbar and ∼ 780°C. Subsequent retrograde decompression textures partly evolved during both D2 and D3 when conditions of ∼ 4–5 kbar and ∼ 750°C were attained. This is followed by D4 shear zones which formed around 3 kbar and ∼ 550°C.It is tempting to combine D2–4 structures in one tectonic cycle involving prograde thrusting and thickening followed by retrograde extension and uplift. The available geochronological data, however, present a number of interpretations. For example, D2 was possibly associated with a clockwise P–T path at medium pressures around ∼ 1000 Ma, by correlation with similar structures developed in the Rauer Group, whilst D3 and D4 events occurred in response to extension and heating at low pressures at ∼ 550 Ma, associated with the emplacement of numerous granitoid bodies. Thus, decompression textures typical for the Larsemann Hills granulites maybe the combined effect of two separate events.C. J. Carson, P. G. H. M. Dirks, M. Hand, J. P. Sims & C. J. L. Wilso

Analysis of sludge from Hanford K East Basin canisters

Sludge samples from the canisters in the Hanford K East Basin fuel storage pool have been retrieved and analyzed. Both chemical and physical properties have been determined. The results are to be used to determine the disposition of the bulk of the sludge and to assess the impact of residual sludge on dry storage of the associated intact metallic uranium fuel elements. This report is a summary and review of the data provided by various laboratories. Although raw chemistry data were originally reported on various bases (compositions for as-settled, centrifuged, or dry sludge) this report places all of the data on a common comparable basis. Data were evaluated for internal consistency and consistency with respect to the governing sample analysis plan. Conclusions applicable to sludge disposition and spent fuel storage are drawn where possible

Soil Respiration in Relation to Photosynthesis of Quercus mongolica Trees at Elevated CO2

Knowledge of soil respiration and photosynthesis under elevated CO2 is crucial for exactly understanding and predicting the carbon balance in forest ecosystems in a rapid CO2-enriched world. Quercus mongolica Fischer ex Ledebour seedlings were planted in open-top chambers exposed to elevated CO2 (EC = 500 µmol mol−1) and ambient CO2 (AC = 370 µmol mol−1) from 2005 to 2008. Daily, seasonal and inter-annual variations in soil respiration and photosynthetic assimilation were measured during 2007 and 2008 growing seasons. EC significantly stimulated the daytime soil respiration by 24.5% (322.4 at EC vs. 259.0 mg CO2 m−2 hr−1 at AC) in 2007 and 21.0% (281.2 at EC vs. 232.6 mg CO2 m−2 hr−1 at AC) in 2008, and increased the daytime CO2 assimilation by 28.8% (624.1 at EC vs. 484.6 mg CO2 m−2 hr−1 at AC) across the two growing seasons. The temporal variation in soil respiration was positively correlated with the aboveground photosynthesis, soil temperature, and soil water content at both EC and AC. EC did not affect the temperature sensitivity of soil respiration. The increased daytime soil respiration at EC resulted mainly from the increased aboveground photosynthesis. The present study indicates that increases in CO2 fixation of plants in a CO2-rich world will rapidly return to the atmosphere by increased soil respiration

Medicago truncatula contains a second gene encoding a plastid located glutamine synthetase exclusively expressed in developing seeds

<p>Abstract</p> <p>Background</p> <p>Nitrogen is a crucial nutrient that is both essential and rate limiting for plant growth and seed production. Glutamine synthetase (GS), occupies a central position in nitrogen assimilation and recycling, justifying the extensive number of studies that have been dedicated to this enzyme from several plant sources. All plants species studied to date have been reported as containing a single, nuclear gene encoding a plastid located GS isoenzyme per haploid genome. This study reports the existence of a second nuclear gene encoding a plastid located GS in <it>Medicago truncatula</it>.</p> <p>Results</p> <p>This study characterizes a new, second gene encoding a plastid located glutamine synthetase (GS2) in <it>M. truncatula</it>. The gene encodes a functional GS isoenzyme with unique kinetic properties, which is exclusively expressed in developing seeds. Based on molecular data and the assumption of a molecular clock, it is estimated that the gene arose from a duplication event that occurred about 10 My ago, after legume speciation and that duplicated sequences are also present in closely related species of the Vicioide subclade. Expression analysis by RT-PCR and western blot indicate that the gene is exclusively expressed in developing seeds and its expression is related to seed filling, suggesting a specific function of the enzyme associated to legume seed metabolism. Interestingly, the gene was found to be subjected to alternative splicing over the first intron, leading to the formation of two transcripts with similar open reading frames but varying 5' UTR lengths, due to retention of the first intron. To our knowledge, this is the first report of alternative splicing on a plant GS gene.</p> <p>Conclusions</p> <p>This study shows that <it>Medicago truncatula </it>contains an additional GS gene encoding a plastid located isoenzyme, which is functional and exclusively expressed during seed development. Legumes produce protein-rich seeds requiring high amounts of nitrogen, we postulate that this gene duplication represents a functional innovation of plastid located GS related to storage protein accumulation exclusive to legume seed metabolism.</p

Estimate of Hanford Waste Rheology and Settling Behavior

The U.S. Department of Energy (DOE) Office of River Protection’s Waste Treatment and Immobilization Plant (WTP) will process and treat radioactive waste that is stored in tanks at the Hanford Site. Piping, pumps, and mixing vessels have been selected to transport, store, and mix the high-level waste slurries in the WTP. This report addresses the analyses performed by the Rheology Working Group (RWG) and Risk Assessment Working Group composed of Pacific Northwest National Laboratory (PNNL), Bechtel National Inc. (BNI), CH2M HILL, DOE Office of River Protection (ORP) and Yasuo Onishi Consulting, LLC staff on data obtained from documented Hanford waste analyses to determine a best-estimate of the rheology of the Hanford tank wastes and their settling behavior. The actual testing activities were performed and reported separately in referenced documentation. Because of this, many of the required topics below do not apply and are so noted