Towards a radiocarbon calibration for oxygen isotope stage 3 using New Zealand kauri (Agathis australis)

It is well known that radiocarbon years do not directly equate to calendar time. As a result, considerable effort has been devoted to generating a decadally resolved calibration curve for the Holocene and latter part of the last termination. A calibration curve that can be unambiguously attributed to changes in atmospheric ¹⁴C content has not, however, been generated beyond 26 kyr cal BP, despite the urgent need to rigorously test climatic, environmental, and archaeological models. Here, we discuss the potential of New Zealand kauri (Agathis australis) to define the structure of the ¹⁴C calibration curve using annually resolved tree rings and thereby provide an absolute measure of atmospheric ¹⁴C. We report bidecadally sampled ¹⁴C measurements obtained from a floating 1050-yr chronology, demonstrating repeatable ¹⁴C measurements near the present limits of the dating method. The results indicate that considerable scope exists for a high-resolution ¹⁴C calibration curve back through OIS-3 using subfossil wood from this source

Record of ³H and ³⁶Cl from the Fukushima nuclear accident recovered from soil water in the unsaturated zone at Koriyama

The opportunity to measure the concentrations of ³H and ³⁶Cl released by the Fukushima nuclear accident in 2011 directly in rain was lost in the early stage of the accident. We have, however, been able to reconstruct the deposition record of atmospheric ³H and ³⁶Cl following the accident using a bore hole that was drilled in 2014 at Koriyama at a distance of 60 km from the accident. The contributions of ³H and ³⁶Cl from the accident are 1.4 × 10¹³ and 2.0 × 10¹² atoms m⁻² respectively at this site. Very high concentrations of both ³H (46 Bq L⁻¹) and ³⁶Cl (3.36 × 10¹¹ atoms L⁻¹) were found in the unsaturated soil at depths between 300 and 350 cm. From these, conservative estimates for the ³H and ³⁶Cl concentrations in the precipitation in the ～ 6 weeks following the accident were 607 Bq L⁻¹ and 4.74 × 10¹⁰ atoms L⁻¹, respectively. A second hole drilled in 2016 showed that ³H concentrations in the unsaturated soil and shallow groundwater had returned to close to natural levels, although the ³⁶Cl concentrations were still significantly elevated above natural levels

Continuous transport of Pacific-derived anthropogenic radionuclides towards the Indian Ocean

Unusually high concentrations of americium and plutonium have been observed in a sediment core collected from the eastern Lombok Basin between Sumba and Sumbawa Islands in the Indonesian Archipelago. Gamma spectrometry and accelerator mass spectrometry data together with radiometric dating of the core provide a high-resolution record of ongoing deposition of anthropogenic radionuclides. A plutonium signature characteristic of the Pacific Proving Grounds (PPG) dominates in the first two decades after the start of the high yield atmospheric tests in 1950’s. Approximately 40–70% of plutonium at this site in the post 1970 period originates from the PPG. This sediment record of transuranic isotopes deposition over the last 55 years provides evidence for the continuous long-distance transport of particle-reactive radionuclides from the Pacific Ocean towards the Indian Ocean

Limits on Supernova-Associated Fe 60/Al 26 Nucleosynthesis Ratios from Accelerator Mass Spectrometry Measurements of Deep-Sea Sediments

We searched for the presence of Al26 in deep-sea sediments as a signature of supernova influx. Our data show an exponential dependence of Al26 with the sample age that is fully compatible with radioactive decay of terrigenic Al26. The same set of samples demonstrated a clear supernova Fe60 signal between 1.7 and 3.2 Myr ago. Combining our Al26 data with the recently reported Fe60 data results in a lower limit of 0.18-0.08+0.15 for the local interstellar Fe60/Al26 isotope ratio. It compares to most of the ratios deduced from nucleosynthesis models and is within the range of the observed average galactic Fe60/Al26 flux ratio of (0.15±0.05).This work was funded in part by the Austrian Science Fund (FWF), Projects No. P20434 and No. I428 (EUROCORES project EuroGENESIS, subproject CoDustMas), by BMBF Project No. 05K2016, DAAD (56266169), and by the University of Vienna

Fat, fibre and cancer risk in African Americans and rural Africans

Rates of colon cancer are much higher in African Americans (65: 100,000) than in rural South Africans (Peer reviewe

Fat, fibre and cancer risk in African Americans and rural Africans

Rates of colon cancer are much higher in African Americans (65: 100,000) than in rural South Africans (Peer reviewe

Progress in AMS measurement of natural 32 Si for glacier ice dating

AMS measurement of 32Si can allow for ice core dating over the last thousand years. Technique developments are reported. Necessary negative-ion yields of 20-30% can now be consistently achieved, and permit an overall efficiency from ice sample to detector of ∼1%. A 30Si-spike technique has overcome the problem of extremely low intrinsic silicon concentration, with the added benefit of allowing determination of ppb-level silicon via isotope dilution. Improvements have also been made to the ionization detector in the gas-filled magnet that separates the accelerated 32Si ions from the intense flux of 32S ions. Preliminary 32Si AMS results of snow and ice samples from Mt. Cook National Park, New Zealand, are reproducible, and with 32Si concentrations 1.2-7.2 mBq/m3 comparable to results from mid-latitude snow samples measured previously via the radiometric technique, demonstrating the feasibility of the method. With these developments, the potential of 32Si as ice core dating tool is close to being realized, and attempts to determine chronologies for both alpine and Antarctic glaciers are underway

Plutonium as a chronomarker in Australian and New Zealand sediments: A comparison with 137 Cs

The construction of high resolution chronologies of sediment profiles corresponding to the last 50-100 years usually entails the measurement of fallout radionuclides 210Pb and 137Cs. The anthropogenic radionuclide, 137Cs, originating from atmospheric nuclear weapons testing can provide an important "first appearance" horizon of known age (1954-1955), providing much-needed validation for the sometimes uncertain interpretations associated with 210Pb geochronology. However, while 137Cs usually provides a strong signal in sediment in the northern hemisphere, total fallout of 137Cs in the southern hemisphere was only 25% that of the north and the low activities of 137Cs seen in Australian and New Zealand sediments can make its horizon of first appearance somewhat arguable. Low 137Cs fallout also limited the size of the 1963-1964 fallout peak, a peak that is usually seen in northern hemisphere sediment profiles but is often difficult to discern south of the equator. This paper shows examples of the use of nuclear weapons fallout Pu as a chronomarker in sediment cores from Australia (3 sites) and New Zealand (1 site). The Pu profiles of five cores are examined and compared with the corresponding 137Cs profiles and 210Pb geochronologies. We find that Pu has significant advantages over 137Cs, including greater measurement sensitivity using alpha spectrometry and mass spectrometric techniques compared to 137Cs measurements by gamma spectrometry. Moreover, Pu provides additional chronomarkers associated with changes in the Pu isotopic composition of fallout during the 1950s and 1960s. In particular, the 238Pu/ 239+240Pu activity ratio shows distinct shifts in the early 1950s and the mid to late 1960s, providing important known-age horizons in southern hemisphere sediments. For estuarine and near-shore sediments Pu sometimes has another significant advantage over 137Cs due to its enrichment in bottom sediment relative to 137Cs resulting from the more efficient scavenging of dissolved Pu in seawater by sediment particles

Late Pleistocene glacial stratigraphy of the Kumara-Moana region, West Coast of South Island, New Zealand

On the South Island of New Zealand, large piedmont glaciers descended from an ice cap on the Southern Alps onto the coastal plain of the West Coast during the late Pleistocene. The series of moraine belts and outwash plains left by the Taramakau glacier are used as a type section for interpreting the glacial geology and timing of major climatic events of New Zealand and also as a benchmark for comparison with the wider Southern Hemisphere. In this paper we review the chronology of advances by the Taramakau glacier during the last or Otira Glaciation using a combination of exposure dating using the cosmogenic nuclides 10Be and 36Cl, and tephrochronology. We document three distinct glacial maxima, represented by the Loopline, Larrikins and Moana Formations, separated by brief interstadials. We find that the Loopline Formation, originally attributed to Oxygen Isotope Chronozone 4, is much younger than previously thought, with an advance culminating around 24,900 ± 800 yr. The widespread late Pleistocene Kawakawa/Oruanui tephra stratigraphically lies immediately above it. This Formation has the same age previously attributed to the older part of the Larrikins Formation. Dating of the Larrikins Formation demonstrates there is no longer a basis for subdividing it into older and younger phases with an advance lasting about 1000 years between 20,800 ± 500 to 20,000 ± 400 yr. The Moana Formation represents the deposits of the last major advance of ice at 17,300 ± 500 yr and is younger than expected based on limited previous dating. The timing of major piedmont glaciation is restricted to between ~25,000 and 17,000 yr and this interval corresponds to a time of regionally cold sea surface temperatures, expansion of grasslands at the expense of forest on South Island, and hemisphere wide glaciation