Ultrathin Au-Alloy Nanowires at the Liquid–Liquid Interface

Ultrathin bimetallic nanowires are of importance and interest for applications in electronic devices such as sensors and heterogeneous catalysts. In this work, we have designed a new, highly reproducible and generalized wet chemical method to synthesize uniform and monodispersed Au-based alloy (AuCu, AuPd, and AuPt) nanowires with tunable composition using microwave-assisted reduction at the liquid–liquid interface. These ultrathin alloy nanowires are below 4 nm in diameter and about 2 μm long. Detailed microstructural characterization shows that the wires have an face centred cubic (FCC) crystal structure, and they have low-energy twin-boundary and stacking-fault defects along the growth direction. The wires exhibit remarkable thermal and mechanical stability that is critical for important applications. The alloy wires exhibit excellent electrocatalytic activity for methanol oxidation in an alkaline medium

Correction to Ultrathin Au-Alloy Nanowires at the Liquid–Liquid Interface

Correction to Ultrathin Au-Alloy Nanowires at the Liquid–Liquid Interfac

Screening Precursor–Solvent Combinations for Li₄Ti₅O₁₂ Energy Storage Material Using Flame Spray Pyrolysis

The development and industrial application of advanced lithium based energy-storage materials are directly related to the innovative production techniques and the usage of inexpensive precursor materials. Flame spray pyrolysis (FSP) is a promising technique that overcomes the challenges in the production processes such as scalability, process control, material versatility, and cost. In the present study, phase pure anode material Li₄Ti₅O₁₂ (LTO) was designed using FSP via extensive systematic screening of lithium and titanium precursors dissolved in five different organic solvents. The effect of precursor and solvent parameters such as chemical reactivity, boiling point, and combustion enthalpy on the particle formation either via gas-to-particle (evaporation/nucleation/growth) or via droplet-to-particle (precipitation/incomplete evaporation) is discussed. The presence of carboxylic acid in the precursor solution resulted in pure (>95 mass %) and homogeneous LTO nanoparticles of size 4–9 nm, attributed to two reasons: (1) stabilization of water sensitive metal alkoxides precursor and (2) formation of volatile carboxylates from lithium nitrate evidenced by attenuated total reflection Fourier transform infrared spectroscopy and single droplet combustion experiments. In contrast, the absence of carboxylic acids resulted in larger inhomogeneous crystalline titanium dioxide (TiO₂) particles with significant reduction of LTO content as low as ∼34 mass %. In-depth particle characterization was performed using X-ray diffraction with Rietveld refinement, thermogravimetric analysis coupled with differential scanning calorimetry and mass spectrometry, gas adsorption, and vibrational spectroscopy. High-resolution transmission electron microscopy of the LTO product revealed excellent quality of the particles obtained at high temperature. In addition, high rate capability and efficient charge reversibility of LTO nanoparticles demonstrate the vast potential of inexpensive gas-phase synthesis for energy-storage materials