Influence of electric field on the Eu+3 photolumiscence in lead-free ferroelectric Na1/2Bi1/2TiO3

Eu modified Na1/2Bi1/2TiO3 (NBT) was investigated for electric-field induced Eu+3 photoluminescence (PL) and structural changes. Detailed analysis revealed that below a critical Eu composition electric field irreversibly suppresses the structural heterogeneity inherent of the host matrix NBT and brings about a long range ferroelectric state with rhombohedral (R3c) distortion. PL study revealed that structural disorder on the nano-scale opens new channels of radiative transitions which can be suppressed by electric field. This study suggests that Eu+3 luminescence can be used to probe the relative degree of field induced structural ordering in relaxor ferroelectrics and also in high performance piezoelectric alloys where electric field couples very strongly with the lattice and structural degrees of freedom.Comment: 19 pages, 9 figure

Size Control and Magnetic Property Trends in Cobalt Ferrite Nanoparticles Synthesized Using an Aqueous Chemical Route

Cobalt ferrite (CoFe2O4) is an engineering material which is used for applications such as magnetic cores, magnetic switches, hyperthermia based tumor treatment, and as contrast agents for magnetic resonance imaging. Utility of ferrites nanoparticles hinges on its size, dispersibility in solutions, and synthetic control over its coercivity. In this work, we establish correlations between room temperature co-precipitation conditions, and these crucial materials parameters. Furthermore, post-synthesis annealing conditions are correlated with morphology, changes in crystal structure and magnetic properties. We disclose the synthesis and process conditions helpful in obtaining easily sinterable CoFe2O4 nanoparticles with coercive magnetic flux density (H-c) in the range 5.5-31.9 kA/m and M-s in the range 47.9-84.9 A.m(2)Kg(-1). At a grain size of similar to 54 +/- 2 nm (corresponding to 1073 K sintering temperature), multi-domain behavior sets in, which is indicated by a decrease in H-c. In addition, we observe an increase in lattice constant with respect to grain size, which is the inverse of what is expected of in ferrites. Our results suggest that oxygen deficiency plays a crucial role in explaining this inverse trend. We expect the method disclosed here to be a viable and scalable alternative to thermal decomposition based CoFe2O4 synthesis. The magnetic trends reported will aid in the optimization of functional CoFe2O4 nanoparticle

Surface oxidation for enhancing the hydrogen evolution reaction of metal nitrides: a theoretical study on vanadium nitride

A single oxide layer acts as a surface oxide activation layer (SOAL) on top of the VN surface toward the HER. VN is a simple model nitride, and this picture can be used for designing enhanced nitride-based catalysts with controlled oxidation of surfaces

Efficient Motion Retrieval in Large Motion Databases

There has been a recent paradigm shift in the computer animation industry with an increasing use of pre-recorded motion for animating virtual characters. A fundamental requirement to using motion capture data is an efficient method for indexing and retrieving motions. In this paper, we propose a flexible, efficient method for searching arbitrarily complex motions in large motion databases. Motions are encoded using keys which represent a wide array of structural, geometric and, dynamic features of human motion. Keys provide a representative search space for indexing motions and users can specify sequences of key values as well as multiple combination of key sequences to search for complex motions. We use a trie-based data structure to provide an efficient mapping from key sequences to motions. The search times (even on a single CPU) are very fast, opening the possibility of using large motion data sets in real-time applications

Interface engineering of mesoporous triphasic cobalt-copper phosphides as active electrocatalysts for overall water splitting

Efficient electrocatalysts for water splitting are essential for viable generation of highly purified hydrogen. Hence there is a need to develop robust catalysts to eliminate barriers associated with sluggish kinetics associated with both anodic oxygen and cathodic hydrogen evolution reactions. Herein, we report a two-step nanocasting-solid phase phosphorization approach to generate ordered mesoporous triphasic phosphides CoP@Cu2P-Cu3P. We show that it is a highly efficient bifunctional electrocatalyst useful for overall water splitting. The mesoporous triphasic CoP@Cu2P-Cu3P only requires a low overpotential of 255 mV and 188 mV to achieve 10 mA cm(-2) for oxygen and hydrogen evolution reactions, respectively. The combination of mesoporous pores (similar to 5.6 nm) with very thin walls (similar to 3.7 nm) and conductive networks in triphasic CoP@Cu2P-Cu3P enable rapid rate of electron transfer and mass transfer. In addition, when CoP@Cu2P-Cu3P is used to fabricate symmetric electrodes, the high surface area mesoporous structure and synergetic effects between phases together contribute to a low cell voltage of 1.54 V to drive a current density 10 mA cm(-2). This performance is superior to noble-metal-based Pt/C-IrO2/C. This work provides a new approach for the facile design and application of multiphase phosphides as highly active bifunctional and stable electrocatalysts for water-alkali electrolyzers