Determination of diffusion coefficients of glycerol and glucose from starch based thermoplastic compounds on simulated physiological solution

Blends of corn starch with poly(ethylene-vinylalcohol) copolymer (SEVA-C) have been studied and reported as biodegradable. These materials are known to be sensitive to enzymatic action, evidencing a degradation of the starch phase in α-amylase assays. However, from the physical-chemical point of view the degradation of the blend is mainly associated with the leaching of glycerol, since other compounds are not released and no carbohydrates were found in the degradation solution. Based on these results, the present work attempts to determinate the respective diffusion coefficients. Four different experiments were performed, using samples with different thicknesses that were immersed in a simulated physiological solution. High performance liquid chromatography (HPLC) was used to separate the sugar derivatives and glycerol from the degradation solutions. The obtained data were fitted to an empirical model to allow the estimation of the diffusion coefficient for glycerol and glucose, based on the analytical solution for Fick’s law of diffusion, and a good agreement was found (R² ≈ 1). The glycerol leaches quickly out during the first few days of immersion, stabilizing thereafter, presenting greater diffusion coefficients for thicker samples. As the quantity of saccharides in the solution remains almost invariable along the experiments, this work also confirms that the degradation process is difficult without the action of enzymes

Three prong tau decays with charged kaons

Final states with charged kaons in three-prong τ decays are studied by exploiting the particle identification from the dE/dx measurement. The results are based on a sample of about 1.6 × 105 detected τ pairs collected with the ALEPH detector between 1991 and 1995 around the Z peak. The following branching ratios have been measured: B(τ- → K−K+π−ντ) = (1.63 ± 0.21 ± 0.17) × 10−3, B(τ− → K−π+π−ντ) = (2.14 ± 0.37 ± 0.29) × 10−3, B(τ− → K−K+π−π0ντ) = (0.75 ± 0.29 ± 0.15) × 10−3, and B(τ− → K−π+π−π0ντ) = (0.61 ± 0.39 ± 0.18) × 10−3. The first two measurements are more precise than the current world averages, while the last two channels are investigated for the first time. The 95% C.L. upper limit on the branching ratio for the decay τ− → K−K+K−ντ is 0.19 × 10−3. A study of intermediate states occurring in the K−K+π−ντ and K−π+π−ντ decays is also presented