Density functional theory study of the nematic-isotropic transition in an hybrid cell

We have employed the Density Functional Theory formalism to investigate the nematic-isotropic capillary transitions of a nematogen confined by walls that favor antagonist orientations to the liquid crystal molecules (hybrid cell). We analyse the behavior of the capillary transition as a function of the fluid-substrate interactions and the pore width. In addition to the usual capillary transition between isotropic-like to nematic-like states, we find that this transition can be suppressed when one substrate is wet by the isotropic phase and the other by the nematic phase. Under this condition the system presents interface-like states which allow to continuously transform the nematic-like phase to the isotropic-like phase without undergoing a phase transition. Two different mechanisms for the disappearance of the capillary transition are identified. When the director of the nematic-like state is homogeneously planar-anchored with respect to the substrates, the capillary transition ends up in a critical point. This scenario is analogous to the observed in Ising models when confined in slit pores with opposing surface fields which have critical wetting transitions. When the nematic-like state has a linearly distorted director field, the capillary transition continuously transforms in a transition between two nematic-like states.Comment: 31 pages, 10 figures, submitted to J. Chem. Phy

Vortex waves in trapped Bose-Einstein condensates

We have theoretically studied vortex waves of Bose-Einstein condensates in elongated harmonic traps. Our focus is on the axisymmetric varicose waves and helical Kelvin waves of singly quantized vortex lines. Growth and decay dynamics of both types of vortex waves are discussed. We propose a method to experimentally create these vortex waves on demand.Comment: minor changes, 7 pages, 7 figure

Quantized vortices and superflow in arbitrary dimensions: Structure, energetics and dynamics

The structure and energetics of superflow around quantized vortices, and the motion inherited by these vortices from this superflow, are explored in the general setting of the superfluidity of helium-four in arbitrary dimensions. The vortices may be idealized as objects of co-dimension two, such as one-dimensional loops and two-dimensional closed surfaces, respectively, in the cases of three- and four-dimensional superfluidity. By using the analogy between vorticial superflow and Ampere-Maxwell magnetostatics, the equilibrium superflow containing any specified collection of vortices is constructed. The energy of the superflow is found to take on a simple form for vortices that are smooth and asymptotically large, compared with the vortex core size. The motion of vortices is analyzed in general, as well as for the special cases of hyper-spherical and weakly distorted hyper-planar vortices. In all dimensions, vortex motion reflects vortex geometry. In dimension four and higher, this includes not only extrinsic but also intrinsic aspects of the vortex shape, which enter via the first and second fundamental forms of classical geometry. For hyper-spherical vortices, which generalize the vortex rings of three dimensional superfluidity, the energy-momentum relation is determined. Simple scaling arguments recover the essential features of these results, up to numerical and logarithmic factors.Comment: 35 pages, 7 figure

Kelvin Modes of a fast rotating Bose-Einstein Condensate

Using the concept of diffused vorticity and the formalism of rotational hydrodynamics we calculate the eigenmodes of a harmonically trapped Bose-Einstein condensate containing an array of quantized vortices. We predict the occurrence of a new branch of anomalous excitations, analogous to the Kelvin modes of the single vortex dynamics. Special attention is devoted to the excitation of the anomalous scissors mode.Comment: 7 pages, 3 figures, submitted to Phys. Rev.

From one cell to the whole froth: a dynamical map

We investigate two and three-dimensional shell-structured-inflatable froths, which can be constructed by a recursion procedure adding successive layers of cells around a germ cell. We prove that any froth can be reduced into a system of concentric shells. There is only a restricted set of local configurations for which the recursive inflation transformation is not applicable. These configurations are inclusions between successive layers and can be treated as vertices and edges decorations of a shell-structure-inflatable skeleton. The recursion procedure is described by a logistic map, which provides a natural classification into Euclidean, hyperbolic and elliptic froths. Froths tiling manifolds with different curvature can be classified simply by distinguishing between those with a bounded or unbounded number of elements per shell, without any a-priori knowledge on their curvature. A new result, associated with maximal orientational entropy, is obtained on topological properties of natural cellular systems. The topological characteristics of all experimentally known tetrahedrally close-packed structures are retrieved.Comment: 20 Pages Tex, 11 Postscript figures, 1 Postscript tabl

Physics of solid–liquid interfaces: From the Young equation to the superhydrophobicity (Review Article)

The state-of-art in the field of physics of phenomena occurring at solid/liquid interfaces is presented. The notions of modern physics of wetting are introduced and discussed including: the contact angle hysteresis, disjoining pressure and wetting transitions. The physics of low temperature wetting phenomena is treated. The general variational approach to interfacial problems, based on the application of the transversality conditions to variational problems with free endpoints is presented. It is demonstrated that main equations, predicting contact angles, namely the Young, Wenzel, and Cassie–Baxter equations arise from imposing the transversality conditions on the appropriate variational problem of wetting. Recently discovered effects such as superhydrophobicity, the rose petal effect and the molecular dynamic of capillarity are reviewed