Chemical Cleaning of Coal with Hot Alkaline Solutions

Various bituminous coals were demineralized by an experimental two-step leaching process in which the ballmilled coals were first treated with a hot alkaline solution and then with a dilute mineral acid. Different alkalis and acids were studied to determine their relative effectiveness. In addition, the effects of alkali concentration, treatment temperature, and treatment time were evaluated. Under the best conditions, the process reduced the ash content of the coals by 85-90% and the total sulfur content by 70-90%. As the temperature of the alkaline treatment was raised from 150 to 345°C, the removal of sulfur increased greatly whereas the recovery of organic matter declined. When a 1 M sodium carbonate solution was employed for the treatment, the recovery of organic matter was 91-97% for various coals treated at 250°C and 79-89% for the same coals treated at 300°C

Desulfurizing Coal with Alkaline Solutions Containing Dissolved Oxygen

The extraction of pyritic sulfur from coal by leaching the comminuted material with hot aqueous solutions containing dissolved oxygen has been demonstrated in numerous laboratory experiments (1-6). Although acidic solutions have generally been used for such experiments, basic solutions appear to offer several important advantages. Thus Majima and Peters (7) showed that the rate of extraction of sulfur from relatively pure pyrite is much greater in basic solutions containing dissolved oxygen than in neutral solutions. Moreover it has been shown recently that basic solutions containing ammonium hydroxide and oxygen can extract a significant portion of the organic sulfur as well as most of the inorganic sulfur from coal at relatively moderate temperatures (e.g., 130°C) (4,5) whereas higher temperatures (150°-200°C) seem to be required with acidic solutions to remove organic sulfur (6). Furthermore some types of basic solutions are much less corrosive towards the common materials of construction than acidic solutions.Reprinted (adapted) with permission from Coal Desulfurization Chapter 15, pp 182–197 DOI: 10.1021/bk-1977-0064.ch015. Copyright 1977 American Chemical Society.</p

Possible Molecular States of Ds∗Dˉs∗D^{*}_s\bar{D}^{*}_s System and Y(4140)

The interpretation of Y(4140) as a $D^{*}_s\bar{D}^{*}_s$ molecule is studied dynamically in the one boson exchange approach, where $\sigma$, $\eta$ and $\phi$ exchange are included. Ten allowed $D^{*}_s\bar{D}^{*}_s$ states with low spin parity are considered, we find that the $J^{PC}=0^{++}$, $1^{+-}$, $0^{-+}$, $2^{++}$ and $1^{--}$ $D^{*}_s\bar{D}^{*}_s$ configurations are most tightly bound. We suggest the most favorable quantum numbers are $J^{PC}=0^{++}$ for Y(4140) as a $D^{*}_s\bar{D}^{*}_s$ molecule, however, $J^{PC}=0^{-+}$ and $2^{++}$ can not be excluded. We propose to search for the $1^{+-}$ and $1^{--}$ partners in the $J/\psi\eta$ and $J/\psi\eta'$ final states, which is an important test of the molecular hypothesis of Y(4140) and the reasonability of our model. The $0^{++}$ $B^{*}_s\bar{B}^{*}_s$ molecule is deeply bound, experimental search in the $\Upsilon(1S)\phi$ channel at Tevatron and LHC is suggested.Comment: 13 pages,2 figure

First principles studies of a Xe atom adsorbed on Nb(110) surface

We study adsorption sites of a single Xe adatom on Nb(110) surface using a density functional theory approach: The on-top site is the most favorable position for the adsorption. We compare the binding features of the present study to earlier studies of a Xe adatom on close-packed (111) surface of face-centered cubic metals. The different features are attributed through a microscopic picture to the less than half filled d-states in Nb.Comment: 15 pages, 4 figure

Cooling Properties of Cloudy Bag Strange Stars

As the chiral symmetry is widely recognized as an important driver of the strong interaction dynamics, current strange stars models based on MIT bag models do not obey such symmetry. We investigate properties of bare strange stars using the Cloudy Bag Model, in which a pion cloud coupled to the quark-confining bag is introduced such that chiral symmetry is conserved. We find that in this model the decay of pions is a very efficient cooling way. In fact it can carry out most the thermal energy in a few milliseconds and directly convert them into 100MeV photons via pion decay. This may be a very efficient $\gamma$-ray burst mechanism. Furthermore, the cooling behavior may provide a possible way to distinguish a compact object between a neutron star, MIT strange star and Cloudy Bag strange star in observations.Comment: 23 pages, 14 figures, accepted by Astroparticle Physics, abstract appeared here has been shortene

Vitamin D metabolites are associated with musculoskeletal injury in young adults: a prospective cohort study.

The relationship between vitamin D metabolites and lower body (pelvis and lower limb) overuse injury is unclear. In a prospective cohort study, we investigated the association between vitamin D metabolites and incidence of lower body overuse musculoskeletal and bone stress injury in young adults undergoing initial military training during all seasons. In 1637 men and 530 women (age, 22.6 ± 7.5 years; BMI, 24.0 ± 2.6 kg∙m−2; 94.3% white ethnicity), we measured serum 25-hydroxyvitamin D (25(OH)D) and 24,25-dihydroxyvitamin D (24,25(OH)2D) by high-performance liquid chromatography tandem mass spectrometry, and 1,25-dihydroxyvitamin D (1,25(OH)2D) by immunoassay during week 1 of training. We examined whether the relationship between 25(OH)D and 1,25(OH)2D:24,25(OH)2D ratio was associated with overuse injury. During 12 weeks training, 21.0% sustained ≥1 overuse musculoskeletal injury, and 5.6% sustained ≥1 bone stress injury. After controlling for sex, BMI, 2.4 km run time, smoking, bone injury history, and Army training course (Officer, standard, or Infantry), lower body overuse musculoskeletal injury incidence was higher for participants within the second lowest versus highest quartile of 24,25(OH)2D (OR: 1.62 [95%CI 1.13–2.32; P = 0.009]) and lowest versus highest cluster of 25(OH)D and 1,25(OH)2D:24,25(OH)2D (OR: 6.30 [95%CI 1.89–21.2; P = 0.003]). Lower body bone stress injury incidence was higher for participants within the lowest versus highest quartile of 24,25(OH)2D (OR: 4.02 [95%CI 1.82–8.87; P < 0.001]) and lowest versus highest cluster of 25(OH)D and 1,25(OH)2D:24,25(OH)2D (OR: 22.08 [95%CI 3.26–149.4; P = 0.001]), after controlling for the same covariates. Greater conversion of 25(OH)D to 24,25(OH)2D, relative to 1,25(OH)2D (i.e., low 1,25(OH)2D:24,25(OH)2D), and higher serum 24,25(OH)2D were associated with a lower incidence of lower body overuse musculoskeletal and bone stress injury. Serum 24,25(OH)2D may have a role in preventing overuse injury in young adults undertaking arduous physical training

Hierarchy of Temporal Responses of Multivariate Self-Excited Epidemic Processes

We present the first exact analysis of some of the temporal properties of multivariate self-excited Hawkes conditional Poisson processes, which constitute powerful representations of a large variety of systems with bursty events, for which past activity triggers future activity. The term "multivariate" refers to the property that events come in different types, with possibly different intra- and inter-triggering abilities. We develop the general formalism of the multivariate generating moment function for the cumulative number of first-generation and of all generation events triggered by a given mother event (the "shock") as a function of the current time $t$. This corresponds to studying the response function of the process. A variety of different systems have been analyzed. In particular, for systems in which triggering between events of different types proceeds through a one-dimension directed or symmetric chain of influence in type space, we report a novel hierarchy of intermediate asymptotic power law decays $\sim 1/t^{1-(m+1)\theta}$ of the rate of triggered events as a function of the distance $m$ of the events to the initial shock in the type space, where $0 < \theta <1$ for the relevant long-memory processes characterizing many natural and social systems. The richness of the generated time dynamics comes from the cascades of intermediate events of possibly different kinds, unfolding via a kind of inter-breeding genealogy.Comment: 40 pages, 8 figure

Au+Au Reactions at the AGS: Experiments E866 and E917

Particle production and correlation functions from Au+Au reactions have been measured as a function of both beam energy (2-10.7AGeV) and impact parameter. These results are used to probe the dynamics of heavy-ion reactions, confront hadronic models over a wide range of conditions and to search for the onset of new phenomena.Comment: 12 pages, 14 figures, Talk presented at Quark Matter '9