Butterfly Hysteresis and Slow Relaxation of the Magnetization in (Et4N)3Fe2F9: Manifestations of a Single-Molecule Magnet

(Et4N)3Fe2F9 exhibits a butterfly--shaped hysteresis below 5 K when the magnetic field is parallel to the threefold axis, in accordance with a very slow magnetization relaxation in the timescale of minutes. This is attributed to an energy barrier Delta=2.40 K resulting from the S=5 dimer ground state of [Fe2F9]^{3-} and a negative axial anisotropy. The relaxation partly occurs via thermally assisted quantum tunneling. These features of a single-molecule magnet are observable at temperatures comparable to the barrier height, due to an extremely inefficient energy exchange between the spin system and the phonons. The butterfly shape of the hysteresis arises from a phonon avalanche effect.Comment: 18 pages, 5 eps figures, latex (elsart

On the combined effects of surface tension force calculation and interface advection on spurious currents within Volume of Fluid and Level Set frameworks

This paper deals with the comparison of Eulerian methods to take into account the capillary contribution in the vicinity of a fluid–fluid interface. Eulerian methods are well- known to produce additional vorticity close to the interface that leads to non-physical spurious currents. Numerical equilibrium between pressure gradient and capillary force for the static bubble test case within a VOF framework has been reached in [35] with the height-function technique [14,35]. However, once the bubble is translated in a uniform flow, spurious currents are maintained by slight errors induced by translation schemes. In this work, two main points are investigated: the ability of Volume of Fluid and Level Set methods to accurately calculate the curvature, and the magnitude of spurious currents due to errors in the calculation of the curvature after advection in both translating and rotating flows. The spurious currents source term is expressed from the vorticity equation and used to discuss and compare the methods. Simulations of gas–liquid Taylor flow at low capillary number show that the flow structure and the bubble velocity can be significantly affected by spurious currents

Generative Roles: Assessing Sustained Involvement in Generativity

Abstract Generative roles refer to observable, behavioral community positions that embody aspects of teaching and nurturing that are central to the concept of generativity. Two studies are presented that describe generative roles in a community sample and provide psychometric data for a short index of generative roles. The first study also provides reliability and validity data from a second informant. The second study examines generative roles at different stages of adolescence and adulthood. Participants were asked 8 yes/no questions about a variety of community roles. The validity of the GRI was supported by significant correlations with the Loyola Generativity Scale, a widely used measure of generative concern (r=.33), and measures of related constructs. The correlations were similar across age categories. The Generative Roles Index has good psychometric qualities and complements existing measures of generativity by providing behavioral, observable data on roles

Quantum tunneling in a three dimensional network of exchange coupled single-molecule magnets

A Mn4 single-molecule magnet (SMM) is used to show that quantum tunneling of magnetization (QTM) is not suppressed by moderate three dimensional exchange coupling between molecules. Instead, it leads to an exchange bias of the quantum resonances which allows precise measurements of the effective exchange coupling that is mainly due to weak intermolecular hydrogen bounds. The magnetization versus applied field was recorded on single crystals of [Mn4]2 using an array of micro-SQUIDs. The step fine structure was studied via minor hysteresis loops.Comment: 4 pages, 4 figure

Phase structure of SU(3) gauge theory with two flavors of symmetric-representation fermions

We have performed numerical simulations of SU(3) gauge theory coupled to Nf=2 flavors of symmetric representation fermions. The fermions are discretized with the tadpole-improved clover action. Our simulations are done on lattices of length L=6, 8, and 12. In all simulation volumes we observe a crossover from a strongly coupled confined phase to a weak coupling deconfined phase. Degeneracies in screening masses, plus the behavior of the pseudoscalar decay constant, indicate that the deconfined phase is also a phase in which chiral symmetry is restored. The movement of the confinement transition as the volume is changed is consistent with avoidance of the basin of attraction of an infrared fixed point of the massless theory.Comment: 12 pages, 11 figure