Impact of grazing intensity on seasonal variations of soil organic carbon and soil CO₂ efflux in two semi-arid grasslands in southern Botswana

Biological soil crusts (BSCs) are an important source of organic carbon, and affect a range of ecosystem functions in arid and semiarid environments. Yet the impact of grazing disturbance on crust properties and soil CO(2) efflux remain poorly studied, particularly in African ecosystems. The effects of burial under wind-blown sand, disaggregation and removal of BSCs on seasonal variations in soil CO(2) efflux, soil organic carbon, chlorophyll a and scytonemin were investigated at two sites in the Kalahari of southern Botswana. Field experiments were employed to isolate CO(2) efflux originating from BSCs in order to estimate the C exchange within the crust. Organic carbon was not evenly distributed through the soil profile but concentrated in the BSC. Soil CO(2) efflux was higher in Kalahari Sand than in calcrete soils, but rates varied significantly with seasonal changes in moisture and temperature. BSCs at both sites were a small net sink of C to the soil. Soil CO(2) efflux was significantly higher in sand soils where the BSC was removed, and on calcrete where the BSC was buried under sand. The BSC removal and burial under sand also significantly reduced chlorophyll a, organic carbon and scytonemin. Disaggregation of the soil crust, however, led to increases in chlorophyll a and organic carbon. The data confirm the importance of BSCs for C cycling in drylands and indicate intensive grazing, which destroys BSCs through trampling and burial, will adversely affect C sequestration and storage. Managed grazing, where soil surfaces are only lightly disturbed, would help maintain a positive carbon balance in African drylands

Assessing Potential Shale Gas Impacts on Groundwater Resources: Recommendations for Groundwater Monitoring and Definition of Baseline Conditions

Exploitation of shale gas by hydraulic fracturing (fracking) is highly controversial and concerns have been raised regarding induced risks from this extraction technique. The SHEER project, an EU Horizon 2020-funded project, is developing best practice to understand, prevent and mitigate the potential short- and long-term environmental impacts and risks of shale gas exploration and exploitation. Three major potential impacts were identified: groundwater contamination, air pollution and induced seismicity. This presentation will deal with the hydrogeological aspect. As part of the SHEER project, baseline and operational groundwater monitoring was carried out at an extraction site in Wysin, Northern Poland. Baseline monitoring was carried out from December 2015 to June 2016 in four monitoring wells intercepting the main drinking water aquifer located in Quaternary sediments. Fracking operations occurred in two deviated horizontal wells in June and July 2016. Monitoring continued for 1.5 years post-fracking although no significant gas production occurred during this period. Collected data include measurements of groundwater level, electrical conductivity and temperature at 15-min intervals, field measurements of groundwater physico-chemical parameters and frequent sampling for laboratory analyses. Groundwater samples were analysed for a range of constituents including dissolved gases and stable isotopes. This presentation will provide an overview of the monitoring results and the ensuing recommendations for groundwater monitoring in the context of shale gas exploitation. These recommendations relate to: (1) site characterisation prior to any activity, (2) baseline and on-going groundwater monitoring, and (3) relationships between regulators, operators and general public. During the presentation, we will particularly focus on the monitoring methodology and establishing accurate background values for key parameters for baseline monitoring, including suggestions on how to clearly communicate the information to the general public. We will conclude on techniques to identify deviations from baseline values

EVALUATING OPTIMAL PRODUCT MIX USING DYNAMIC SIMULATION: A TOMATO PROCESSING CASE

Technology-driven change is everywhere and value-capture from new technology is challenging for business managers. Also rival firms may use technology as part of major success strategies. This situation leads managers to be keenly interested in evaluation of alternative technologies prior to making a sunk investment in physical facilities. In contemplating new or added-capacity processing facilities, managers and investors must evaluate return on investment (ROI). Evaluation of ROI is complex because it varies by alternative technology and the resultant potential product mix alternatives associated with that technology at the time the investment capital is committed to build the processing plant. This research examines optimal alternative product mix from a processing plant technology that is fixed at the time of commitment to building or adding capacity. Evaluating the optimal product mix is of vital concern in any start-up processing environment. In this research the optimal product mix is evaluated by using a sophisticated evaluative tool known as PowerSim. This economic simulation software is used to model a start-up tomato processing plant in Ohio. The model evaluates the effects of various output, or tomato product mix, on plant profitability measured by ROI. Results indicate that an increase in plant profitability is expected when the tomato product mix consists of products that have a lower soluble solids concentration. The lower the soluble solids concentration of a tomato product, the less the processor will benefit from tomato varieties with high soluble solids. The processing operation achieves a RIO of 26.5 percent when the plant'Â’s product mix is 50 percent tomato paste (31 degrees brix) and 50 percent diced tomatoes. This product mix optimizes processor net income and realizes a plant return on equity of 50.6 percent.Agribusiness,

Production and state-selective detection of ultracold, ground state RbCs molecules

Using resonance-enhanced two-photon ionization, we detect ultracold, ground-state RbCs molecules formed via photoassociation in a laser-cooled mixture of 85Rb and 133Cs atoms. We obtain extensive bound-bound excitation spectra of these molecules, which provide detailed information about their vibrational distribution, as well as spectroscopic data on the RbCs ground a^3\Sigma^+ and excited (2)^3\Sigma^+, (1)^1\Pi states. Analysis of this data allows us to predict strong transitions from observed excited levels to the absolute vibronic ground state of RbCs, potentially allowing the production of stable, ultracold polar molecules at rates as large as 10^7 s^{-1}

Effect of hydrogen on the strength and microstructure of selected ceramics

Ceramics in monolithic form and as composite constituents in the form of fibers, matrices, and coatings are currently being considered for a variety of high-temperature applications in aeronautics and space. Many of these applications involve exposure to a hydrogen-containing environment. The compatibility of selected ceramics in gaseous high-temperature hydrogen is assessed. Environmental stability regimes for the long term use of ceramic materials are defined by the parameters of temperature, pressure, and moisture content. Thermodynamically predicted reactions between hydrogen and several monolithic ceramics are compared with actual performance in a controlled environment. Morphology of hydrogen attack and the corresponding strength degradation is reported for silicon carbide, silicon nitride, alumina, magnesia, and mullite

Carbon dioxide fluxes from biologically-crusted Kalahari Sands after simulated wetting

We report surface CO2 efflux and subsoil CO2 concentrations in biologically-crusted soils from the Kalahari. Fluxes were determined in-situ using a closed chamber coupled to a portable gas chromatograph on dry soils and on soils subject to simulated light and heavy rainfall. Surface efflux was measured in an artificially darkened environment in order to determine by difference, whether photosynthesis was occurring. Dry soil efflux rates were 2.8–14.8 mg C m2 h−1 throughout a diurnal cycle. Light rainfall led to an immediate increase in efflux to a peak of 65.6 mg C m2 h−1. Heavy rainfall resulted in a large pulse of CO2 with efflux rates of 339.2 mg C m2 h−1 over the first hour after wetting. Peak rates remained high over the following 2 days (87.8 and 87.0 mg C m2 h−1). Given sufficient moisture, fluxes increased with temperature. We believe hydration of the subsoil stimulates microorganisms which repsire available C either from extracellular polysaccharide sheaths (EPS) or released into the soil through lysis of microbial cells. Higher fluxes from the soil kept in the dark suggests photosynthesis occurs in wetted crusts during the daytime but net C uptake is masked by respiration from other microorganisms