Effect of Composition on Electrical and Optical Properties of Thin Films of Amorphous GaxSe100−x Nanorods

We report the electrical and optical studies of thin films of a-GaxSe100−x nanorods (x = 3, 6, 9 and 12). Thin films of a-GaxSe100−x nanorods have been synthesized thermal evaporation technique. DC electrical conductivity of deposited thin films of a-GaxSe100−x nanorods is measured as a function of temperature range from 298 to 383 K. An exponential increase in the dc conductivity is observed with the increase in temperature, suggesting thereby a semiconducting behavior. The estimated value of activation energy decreases on incorporation of dopant (Ga) content in the Se system. The calculated value of pre-exponential factor (σ0) is of the order of 101 Ω−1 cm−1, which suggests that the conduction takes place in the band tails of localized states. It is suggested that the conduction is due to thermally assisted tunneling of the carriers in the localized states near the band edges. On the basis of the optical absorption measurements, an indirect optical band gap is observed in this system, and the value of optical band gap decreases on increasing Ga concentration

Magmatism and crustal extension: Constraining activation of the ductile shearing along the Gediz detachment, Menderes Massif (western Turkey)

The Menderes Massif of western Turkey is a key area to study feedback relationships between magma generation/emplacement and activation of extensional detachment tectonics. Here, we present new textural analysis and in situ U–(Th)–Pb titanite dating from selected samples collected in the transition from the undeformed to the mylonitized zones of the Salihli granodiorite at the footwall of the Neogene, ductile-to-brittle, top-to-the-NNE Gediz–Alaşheir (GDF) detachment fault. Ductile shearing was accompanied by the fluid-mediated sub-solidus transformation of the granodiorite to orthogneiss, which occurred at shallower crustal levels and temperatures compatible with the upper greenschist-to-amphibolite facies metamorphic conditions (530–580 °C and P < 2 GPa). The syn-tectonic metamorphic overgrowth of REE-poor titanite on pristine REE-rich igneous titanite offers the possibility to constrain the timing of magma crystallisation and solid-state shearing at the footwall of the Gediz detachment. The common Pb corrected 206Pb/238U (206Pb*/238U) ages and the REE re-distribution in titanite that spatially correlates with the Th/U zoning suggests that titanite predominantly preserve open-system ages during fluid-assisted syn-tectonic re-crystallisation in the transition from magma crystallization and emplacement (at ~ 16–17 Ma) to the syn-tectonic, solid-state shearing (at ~ 14-15 Ma). A minimum time lapse of ca. 1–2 Ma is then inferred between the crustal emplacement of the Salihli granodiorite and nucleation of the ductile extensional shearing along the Gediz detachment. The reconstruction of the cooling history of the Salihli granodiorite documents a punctuated evolution dominated by two episodes of rapid cooling, between ~ 14 Ma and ~ 12 Ma (~ 100 °C/Ma) and between ~ 3 and ~ 2 Ma (~ 105 °C/Ma). We relate the first episode to nucleation and development of post-emplacement of ductile shearing along the GDF and the second to brittle high-angle faulting, respectively. Our dataset suggests that in the Menderes Massif the activation of ductile extension was a consequence, rather than the cause, of magma emplacement in the extending crust

Tectonic setting and geochronology of the Cadomian (Ediacaran-Cambrian) magmatism in Central Iran, Kuh-e-Sarhangi region (NW Lut Block)

The structure, age and petrogenesis of plutonic basement rocks from the Kuh-e-Sarhangi region, located in the Kashmar-Kerman tectonic zone of Central Iran are described. These intrusive rocks consist of a sub-alkaline, dominantly high-K calc-alkaline acidic suite, characterised by high SiO2 (72.60–77.17 wt%), and alkalis (up to 8 wt%) and low Mg# (07-35). They are also enriched in Th, U and light rare earth elements, and depleted in Nb, Ta, and Ti, thus showing a geochemical fingerprint compatible with arc magmatism. The U–Pb zircon geochronology constrains magma crystallisation and emplacement during Ediacaran-Cambrian (ca. 575–535 Ma) times, under a tectonic regime dominated by transpressional tectonics as constrained by analysis of field structures. Combined inverse and forward modelling thermobarometry indicates pluton emplacement occurred in a thickened crustal environment, suggesting the Kuh-e-Sarhangi magmatic belt exposes the exhumed roots of a volcanic arc. This magmatism is interpreted as part of the Cadomian, subduction-related magmatism and framed within an oblique convergence scenario during formation of an Andean-type active margin all along the northern (proto-Tethyan) margin of the Gondwana Supercontinent

Tectonic setting and geochronology of the Cadomian (Ediacaran-Cambrian) magmatism in Central Iran, Kuh-e-Sarhangi region (NW Lut Block)

The structure, age and petrogenesis of plutonic basement rocks from the Kuh-e-Sarhangi region, located in the Kashmar-Kerman tectonic zone of Central Iran are described. These intrusive rocks consist of a sub-alkaline, dominantly high-K calc-alkaline acidic suite, characterised by high SiO2 (72.60–77.17 wt%), and alkalis (up to 8 wt%) and low Mg# (07-35). They are also enriched in Th, U and light rare earth elements, and depleted in Nb, Ta, and Ti, thus showing a geochemical fingerprint compatible with arc magmatism. The U–Pb zircon geochronology constrains magma crystallisation and emplacement during Ediacaran-Cambrian (ca. 575–535 Ma) times, under a tectonic regime dominated by transpressional tectonics as constrained by analysis of field structures. Combined inverse and forward modelling thermobarometry indicates pluton emplacement occurred in a thickened crustal environment, suggesting the Kuh-e-Sarhangi magmatic belt exposes the exhumed roots of a volcanic arc. This magmatism is interpreted as part of the Cadomian, subduction-related magmatism and framed within an oblique convergence scenario during formation of an Andean-type active margin all along the northern (proto-Tethyan) margin of the Gondwana Supercontinent