Bifurcation analysis based on a material model with stress-rate dependency and non-associated flow rule for fracture prediction in metal forming

Recent increasing application of advanced high-strength metals causes grow-ing demand for accurate fracture prediction in metal forming simulation. However, since the construction of objective and reliable fracture prediction method is generally difficult, essential progress in fundamental theory that supports evolution of fracture rediction framework is required. In this study, a fracture prediction framework based on the bifurcation theory is pre- sented. The main achievement is a novel material model based on stress-rate dependency related with non-associate flow rule. This model is based on non-associated flow rule with independent arbitrary higher-order yield function and plastic potential function for any anisotropic materials. And this formulation is combined with the stress-rate depen- dency plastic constitutive equation, which is known as Ito-Goya model, to construct a generalized plastic constitutive model in which non-normality and non-associativity are reasonably considered. Then, by adopting the three-dimensional bifurcation theory, which is known as the 3D localized bifurcation theory, more accurate prediction of the initiation of shear band is realized, leading to general and reliable construction of forming limit dia- gram. Then, by using virtual material data, numerical simulation is carried out to exhibit fracture limit diagram for demonstrating the generality and reliability of the proposed methodology. In particular, the effect of stress-rate dependency on the bifurcation analy- sis is investigated, and the order of the yield function is used to investigate the influence on the forming limit prediction

Neural magnetic field dependent fMRI toward direct functional connectivity measurements: A phantom study

Recently, the main issue in neuroscience has been the imaging of the functional connectivity in the brain. No modality that can measure functional connectivity directly, however, has been developed yet. Here, we show the novel MRI sequence, called the partial spinlock sequence toward direct measurements of functional connectivity. This study investigates a probable measurement of phase differences directly associated with functional connectivity. By employing partial spinlock imaging, the neural magnetic field might influence the magnetic resonance signals. Using simulation and phantom studies to model the neural magnetic fields, we showed that magnetic resonance signals vary depending on the phase of an externally applied oscillating magnetic field with non-right flip angles. These results suggest that the partial spinlock sequence is a promising modality for functional connectivity measurements

トショ ショウカイ ヨコガワ キミコ ヘン オオムラ シゲ キョウト マチヤ グラシ

横川公子編　『大村しげ　京都町家ぐらし』　河出書房新社　200

Synthesis of 2-Azulenyl-1,1,4,4-tetracyano-3-ferrocenyl-1,3-butadienes by [2+2] Cycloaddition of (Ferrocenylethynyl)azulenes with Tetracyanoethylene

1-, 2-, and 6-(Ferrocenylethynyl)azulene derivatives 1016 have been prepared by palladium-catalyzed alkynylation of ethynylferrocene with the corresponding haloazulenes under SonogashiraHagihara conditions. Compounds 1016 reacted with tetracyanoethylene (TCNE) in a [2+2] cycloadditioncycloreversion reaction to afford the corresponding 2-azulenyl-1,1,4,4,-tetracyano-3-ferrocenyl-1,3-butadiene chromophores 1723 in excellent yields. The redox behavior of the novel azulene chromophores 1723 was examined by using cyclic voltammetry (CV) and differential pulse voltammetry (DPV), which revealed their multistep electrochemical reduction properties. Moreover, a significant color change was observed by visible spectroscopy under electrochemical reduction conditions.ArticleCHEMISTRY-A EUROPEAN JOURNAL. 19(18):5721-5730 (2013)journal articl

Synthesis of push-pull chromophores by the sequential [2+2] cycloaddition of 1-azulenylbutadiynes with tetracyanoethylene and tetrathiafulvalene

Azulene-substituted butadiynes have been prepared by Cu-mediated cross- and homo-coupling reactions. The azulene-substituted butadiynes reacted with tetracyanoethylene in a formal [2 + 2] cycloaddition reaction to afford the corresponding 1,1,4,4-tetracyanobutadiene chromophores, in excellent yields. Further [2 + 2] cycloaddition with TTF and TCNE gave novel donor-acceptor chromophores and novel azulene-substituted 6,6-dicyanofulvene derivatives.ArticleORGANIC & BIOMOLECULAR CHEMISTRY. 10(41):8308-8313 (2012)journal articl

Self-Duality and Phase Structure of the 4D Random-Plaquette Z_2 Gauge Model

In the present paper, we shall study the 4-dimensional Z_2 lattice gauge model with a random gauge coupling; the random-plaquette gauge model(RPGM). The random gauge coupling at each plaquette takes the value J with the probability 1-p and -J with p. This model exhibits a confinement-Higgs phase transition. We numerically obtain a phase boundary curve in the (p-T)-plane where T is the "temperature" measured in unit of J/k_B. This model plays an important role in estimating the accuracy threshold of a quantum memory of a toric code. In this paper, we are mainly interested in its "self-duality" aspect, and the relationship with the random-bond Ising model(RBIM) in 2-dimensions. The "self-duality" argument can be applied both for RPGM and RBIM, giving the same duality equations, hence predicting the same phase boundary. The phase boundary curve obtained by our numerical simulation almost coincides with this predicted phase boundary at the high-temperature region. The phase transition is of first order for relatively small values of p < 0.08, but becomes of second order for larger p. The value of p at the intersection of the phase boundary curve and the Nishimori line is regarded as the accuracy threshold of errors in a toric quantum memory. It is estimated as p=0.110\pm0.002, which is very close to the value conjectured by Takeda and Nishimori through the "self-duality" argument.Comment: 14 pages, 7 figure

Expectation Management in a Global Collaboration Project Using a Deterministic Design Approach

Expectation management in product engineering design aims at setting achievable goals for both customers and designers, while leaving room for creativity and passion. This is especially challenging in the global workplace. Using an example of a design project, the Dental Headrest project (DHR), this paper reviews how expectations were managed in a successful, collaborative project between the University of Tokushima (UT) and Massachusetts Institute of Technology (MIT). The goal of the project was to design an innovative mechanism for the positioning a dental chair headrest so satisfy both the needs of a patient for comfort and a clinician for flexibility and access. The design team was formed with six students from the MIT MechE’s Precision Machine Design class, while the challenge proposed by a UT team of dentists and design engineers. The team followed a deterministic design procedure inducing understating the challenge and reviewing prior art, strategy and concept generation, detailed module design and fabrication and testing, culminating in presentation and documentation. Through the process was coordinated by online communication and collaborative working spaces which ensured real-time information transfer between the continents. The conclusion was a face-to-face meeting between the two institutions. This DHR project resulted in an innovative design of headrest adjusting mechanism that was implemented in a prototype. Moreover, the students, faculty and clinicians benefitted from the experience of innovative design collaboration in a multidisciplinary, global team.CIMIT: Center for Integration of Medicine and Innovative TechnologyJ. Morita Corporatio

Synthesis of 2-and 6-thienylazulenes by palladium-catalyzed direct arylation of 2-and 6-haloazulenes with thiophene derivatives

Preparation of 2- and 6-thienylazulene derivatives was established by the palladium-catalyzed direct cross-coupling reaction of 2- and 6-haloazulenes with the corresponding thiophene derivatives in good yield. Several thienylazulene derivatives were also used in the reaction with 2-chloroazulene derivatives in the presence of the palladium-catalyst to afford the thiophene derivatives with two azulene functions in good yield.ArticleORGANIC & BIOMOLECULAR CHEMISTRY. 23(66):10191-10197 (2015)journal articl