A review of cleaner production in electroplating industries using electrodialysis

[EN] Cleaner production is an industrial preventive strategy created to promote benefits for the environment and for human beings. Its basic principle lies in using natural energy resources in an efficient way and yet in reducing risks and impacts on the environment and on human beings throughout the life cycle of a product. Electrodialysis is a membrane separation process which uses an electrical potential difference as a driving force to promote ionic separation in aqueous solutions. The technique was initially developed for the production of drinking water from brackish water. However, the use of electrodialysis in the treatment of industrial wastewaters is becoming more attractive, due to its characteristics. The technique is considered a clean process, since it allows the reuse of water and the recovery of substances. In this work, the advancement of electrodialysis applied to cleaner production in electroplating industry will be discussed. The aim of this work is to present electrodialysis as a technology which can fulfill the requirements of cleaner production concepts in the electroplating industry. The research was performed starting from a predefined question: "how is electrodialysis becoming a cleaner production strategy in the electroplating industry?". The research was divided in two main themes. The first search was related to the most important cleaner production practices applied for the plating industry. The second search was associated with the electrodialysis application in the electroplating industry. The results obtained from the collected publications were compared in order to propose an answer to the research question. The results showed that almost a half of the published articles evaluated the improvement of the wastewater treatment as a cleaner production strategy to be applied in plating industries. In addition, the wastewater treatment was the most cited application of electrodialysis in the plating industry, especially for copper, nickel and zinc recovery and for chromium VI removal. Results shows that electrodialysis is becoming an important and solid strategy to promote cleaner production in the plating industry. The two most important issues to be improved for this application are the system efficiency for macromolecules and the energy waste when dilute solutions are used. For the latter, the use of hybrid techniques such as electrodeionization was the most evaluated alternative. (C) 2017 Elsevier Ltd. All rights reserved.Authors would like to thank the Institute for Technological Research (IPT), the Institute for Technological Research Foundation (FIPT) and to The Sao Paulo Research Foundation (Fapesp - grants 2012/51871-9; 2014/13351-9 and 2014/21943-3).Scarazzato, T.; Panossian, Z.; Tenório, J.; Pérez-Herranz, V.; Espinosa, D. (2017). A review of cleaner production in electroplating industries using electrodialysis. Journal of Cleaner Production. 168:1590-1602. https://doi.org/10.1016/j.jclepro.2017.03.152S1590160216

Evaluation of the transport properties of copper ions through a heterogeneous ion-exchange membrane in etidronic acid solutions by chronopotentiometry

[EN] The transport properties of copper chelates across an anion-exchange membrane were investigated by means of chronopotentiometry. Several solutions containing etidronic acid, copper sulfate and potassium chloride were evaluated. Tests were accomplished in a three-compartment reactor using a heterogeneous membrane containing quaternary ammonium functional groups. Results showed a strong relation between the amount of chelated anions and the limiting current density, the electrical resistance and the concentration polarization. An increase in the anionic equivalent charge of the solutions modified the three regions of the current-voltage curves. The acid medium was found to be less favorable because of the possibility of the formation of non-charged species in overlimiting regions. The presence of chloride anions increased the limiting current density, especially when the chloride concentration exceeded the etidronic acid concentration.Authors would like to thank the Institute for Technological Research (IPT), the Institute for Technological Research Foundation (FIPT), to the São Paulo Research Foundation (Fapesp - processes 2012/51871-9, 2014/21943-3 and 2014/13351-9) and the National Council for Scientific and Technological Development.Scarazzato, T.; Panossian, Z.; García Gabaldón, M.; Ortega Navarro, EM.; Tenório, J.; Pérez-Herranz, V.; Espinosa, D. (2017). Evaluation of the transport properties of copper ions through a heterogeneous ion-exchange membrane in etidronic acid solutions by chronopotentiometry. Journal of Membrane Science. 535:268-278. https://doi.org/10.1016/j.memsci.2017.04.048S26827853

Ion transport through homogeneous and heterogeneous ion-exchange membranes in single salt and multicomponent electrolyte solutions

The increasing demand for clean industrial processes has intensified the use of electrodialysis in the treatment of metal containing effluents and encourages the investigation of the different phenomena involved in the transport of metal ions through cation-exchange membranes. Ion sorption, chronopotentiometric and current–voltage characteristics have been obtained to characterize the transport of sodium and iron through homogeneous and heterogeneous cation-exchange membranes. The heterogeneous membranes having a broader pore size distribution showed increased electrical resistances with solutions of trivalent iron, which may be caused by the blockage of the smallest pores by multivalent ions. However, for both types of membranes an unexpected decrease of the electrical resistance with increasing current densities was verified with concentrated solutions of Fe2(SO4)3. This behavior was explained to be a consequence of the dissociation of FeSO4+ ions into more conductive Fe3+ and SO42− ions as the depleting solution layer becomes diluted. When tested with multicomponent mixtures, the homogeneous perfluorosulfonic membranes show an increased preference for Na+ ions at low current densities and, once Na+ ions are depleted from the membrane surface Fe3+ ions are transported preferentially at higher current densities. On the contrary, both Na+ ions and Fe(III) species are responsible for the ion transport through the heterogeneous membranes within the ohmic regime of currents.This work was supported by the Ministerio de Economia y Competitividad (Spain) with the Project number CTQ2012-37450-C02-01/PPQ. M.C. Marti-Calatayud is grateful to the Universitat Politecnica de Valencia for a postgraduate grant (Ref. 2010-12). D.C. Buzzi wants to express her gratitude to CAPES (Brazil) for a postgraduate grant (Proc. BEX 8747/11-3).Martí Calatayud, MC.; Buzzi, DC.; García Gabaldón, M.; Bernardes, AM.; Tenório, JAS.; Pérez Herranz, V. (2014). Ion transport through homogeneous and heterogeneous ion-exchange membranes in single salt and multicomponent electrolyte solutions. Journal of Membrane Science. 466:45-57. https://doi.org/10.1016/j.memsci.2014.04.033S455746