NH2 fluorescence efficiencies and the NH3 abundance in Comet Halley

If NH3 is the dominant source of the NH2 observed in comet spectra, then the NH3 abundance can in principle be accurately determined. Fluorescence efficiencies for the (0, v-prime/2/, O) to (0, 0, 0) progression of NH2 bands are calculated for NH2 bands likely to be observed in the 4500-8200-A region of comets. The results differ from previous determinations of the NH2 band fluorescence efficiencies by factors in the range 1.4-5.9, leading t6o significant changes in previously reported NH2 production rates in comets. A recalculation of the NH3/H2O abundance ratio in Comet Halley gives about (0.5 + or - 0.2) percent in better agreement with the Giotto ion-mass-spectrometer results of Allen et al (1987)

The dust coma of Comet Austin (1989c1)

Thermal-infrared (10 and 20 micron) images of Comet Austin were obtained on UT 30.6 Apr., 1.8, 2.8, and 3.6 May 1990. The NASA-Marshall Space Flight Center 20 pixel bolometer array at the NASA 3 meter Infrared Telescope Facility in Hawaii was used. The 10.8 micron (FWHM = 5.3 microns) maps were obtained with maximum dimensions of 113 arcsec (57,500 km) in RA and 45 arcsec (23,000 km) in declination, with a pixel size of 4.2 x 4.2 arcsec. A smaller, 45 x 18 arcsec, map was obtained in the 19.2 micron (FWHM = 5.2 microns) bandpass. At the time of these observations Comet Austin's heliocentric and geocentric distances were 0.7 and 0.5 AU respectively. The peak flux density (within the brightest pixel) was 23 + or - 2 Janskys for the first three dates and only marginally lower the last day; i.e., within the observational uncertainties no evidence was found for day-to-day variability like that observed in Comet Halley. A dynamical analysis of the morphology of the extended dust emission is used to constrain the size distribution and production rate of the dust particles. The results of this analysis are compared with similar studies carried out on comets P/Giacobini-Zinner, P/Brorsen-Metcalf, P/Halley, P/Tempel 2, and Wilson (1987)

Spectrophotometry of comets Giacobini-Zinner and Halley

Optical window spectrophotometry was performed on comets Giacobini-Zinner and Halley over the interval 300-1000 nm. Band and band-sequence fluxes were obtained for the brightest features of OH, CN, NH, and C2, special care having been given to determinations of extinction, instrumental sensitivities, and corrections for Fraunhofer lines. C2 Swan band-sequence flux ratios were determined with unprecedented accuracy and compared with the predictions of the detailed equilibrium models of Krishna Swamy et al. (1977, 1979, 1981, and 1987). It is found that these band sequences do not agree with the predictions, which calls into question the assumptions made in deriving the model, namely resonance fluorescence statistical equilibrium. Suggestions are made as to how to resolve this discrepancy

Spectra of comet P/Halley at R = 4 - 8 AU

Spectra of Comet Halley (lambda lambda = 3400-6500 A) were acquired at pre- and post-perihelion distances of 4.8 AU on 1985 Feb. 17 (Coma V equals 18.9 mag) and 1987 Feb. 1 (coma V = 15.9 mag) using the 4.5-m Multiple-Mirror Telescope (MMT) and the CTIO 4.0-m telescope, respectively. The CN(0,0) violet system band flux at 4.8 AU was approx. 15 times greater at the post-perhelion phase compared to pre-perihelion. Additional post-perihelion spectra, obtained on 1986 Nov. 28 to 30 with the MTT, showed CN(0,0) and very weak C3 4040 A emission. The MMT data are one-dimensional spectra (aperture: 5 arc sec diameter) obtained with an intensified Reticon while the CTIO data are two-dimensional spectra (slit length = 280 arc sec) obtained with a 2D-Frutti photon counting system. Extended CN(0,0) emission was detected in the 1987 Feb. 1 (at 4.8 AU) spectra to a distance of at least 70 arc sec in the solar and anti-solar directions. Additional CCD spectra obtained with the KPNO 2.2-meter telescope on 1988 Feb. 20 (at 7.9 AU) show scattered solar continuum approx. 32 arc sec diameter. However, no emission features were detected at 7.9 AU

Long slit spectroscopy of NH2 in comets Halley, Wilson, and Nishikawa-Takamizawa-Tago

Long-slit spectra of comets Halley, Wilson and Nishikawa-Takamizawa-Tago were obtained with the 3.9 meter Anglo-Australian Telescope. Spectra of comets Halley and Wilson were obtained with the IPCS at a spectral resolution of 0.5 A and a spatial resolution of 10(exp 3) km. Spectra of comets Wilson and Nishikawa-Takamizawa-Tago were obtained with a CCD at a spectral resolution of 1.5 A and a spatial resolution of approximately 3 x 10(exp 3) km. Surface brightness profiles for NH2 were extracted from the long-slit spectra of each comet. The observed surface brightness profiles extend along the slit to approximately 6 x 10(exp 4) km from the nucleus in both sunward and tailward directions. By comparing surface distribution calculated from an appropriate coma model with observed surface brightness distributions, the photodissociation timescale of the parent molecule of NH2 can be inferred. The observed NH2 surface brightness profiles in all three comets compares well with a surface brightness profile calculated using the vectorial model, an NH3 photodissociation timescale of 7 x 10(exp 3) seconds, and an NH2 photodissociation timescale of 34,000 seconds

Simultaneous visible and near-infrared spectrophotometry of Comet Austin 1989c

Simultaneous visible and near-infrared spectra of Comet Austin were obtained wit the 1.5 m and 2.3 m telescopes of the University of Arizona Observatories on 1990 May 16. The visible spectrum obtained with the IHW spectrograph covers the 3126-9490 A wavelength interval, while the near-infrared spectrum obtained with the germanium spectrometer covers the 9036-12794 A wavelength interval. Simultaneous measurements of integrated band fluxes are presented for the CN B 2Sigma(+) - X 2Sigma(+) (violet) and A 2Pi - X 2Sigma(+) (red) systems. A CN spectrum and CN band flux ratios calculated from a fluoresence equilibrium model are also presented. From a comparison between the observed and calculated CN spectra and band flux ratios, it is found that red system oscillator strengths determined from recent ab initio calculations appropriately describe the radiative properties of CN molecules

Comet outbursts and polymers of HCN

Dramatic cometary outbursts have been noted by observers for many years. These outbursts can sometimes increase the apparent brightness of a comet up to 9 mag and release energy on the order of 10 exp 19 ergs. A number of mechanisms have been suggested for outburst activity; however, none has been generally accepted. HCN is a known constituent of both interstellar icy grain mantles and cometary nuclei, and HCN polymers have been postulated to exist on the dark surface of comets such as P/Halley. Since polymerization is a strongly exothermic process, we investigate the possibility that HCN polymerization can provide the energy needed for outbursts. Polymerization may be continuing in the inhomogeneous interior of comets. In addition, the reactive CN groups in these oligomers can be hydrolyzed and may contribute to CO2 and CO pressure buildup in the interior of comets

Nitrogen abundance in Comet Halley

Data on the nitrogen-containing compounds that observed spectroscopically in the coma of Comet Halley are summarized, and the elemental abundance of nitrogen in the Comet Halley nucleus is derived. It is found that 90 percent of elemental nitrogen is in the dust fraction of the coma, while in the gas fraction, most of the nitrogen is contained in NH3 and CN. The elemental nitrogen abundance in the ice component of the nucleus was found to be deficient by a factor of about 75, relative to the solar photosphere, indicating that the chemical partitioning of N2 into NH3 and other nitrogen compounds during the evolution of the solar nebula cannot account completely for the low abundance ratio N2/NH3 = 0.1, observed in the comet. It is suggested that the low N2/NH3 ratio in Comet Halley may be explained simply by physical fractionation and/or thermal diffusion

NH3 and NH2 in the coma of Comet Brorsen-Metcalf

Evidence consistent with NH3 ice in the nucleus of Comet Brorsen-Metcalf as the source of the NH2 observed in the comet coma is presented. The distribution of NH2 is symmetric and shows no evidence for jet structure at the 3-sigma significance level above background emission. An azimuthal average of the NH2 image produces an NH2 surface brightness profile for Comet Brorsen-Metcalf which yields a factor of about-10 improvement in the signal-to-noise ratio over previous 1D long-slit NH2 observations, and provides a significant constraint on the NH2 photodissociation time scale in comets. A Monte Carlo simulation of the comet coma, assuming that NH2 is the primary source of NH2, is described and compared with the observations. For an observed production rate, Q(H2O) is approximately equal to 7 x 10 exp 28 molecules/s, collisional effects on the NH3 and NH2 outflow had at most an approximately 10-percent effect on the NH2 surface brightness profile. Because Comet Brorsen-Metcalf showed no significant dust or gas production rate variability, it is argued that steady state conditions best match the comet at the time of the observations