Lamellar order, microphase structures and glassy phase in a field theoretic model for charged colloids

In this paper we present a detailed analytical study of the phase diagram and of the structural properties of a field theoretic model with a short-range attraction and a competing long-range screened repulsion. We provide a full derivation and expanded discussion and digression on results previously reported briefly in M. Tarzia and A. Coniglio, Phys. Rev. Lett. 96, 075702 (2006). The model contains the essential features of the effective interaction potential among charged colloids in polymeric solutions. We employ the self-consistent Hartree approximation and a replica approach, and we show that varying the parameters of the repulsive potential and the temperature yields a phase coexistence, a lamellar and a glassy phase. Our results suggest that the cluster phase observed in charged colloids might be the signature of an underlying equilibrium lamellar phase, hidden on experimental time scales, and emphasize that the formation of microphase structures may play a prominent role in the process of colloidal gelation.Comment: 16 pages, 7 figure

Explicit solution for a two--phase fractional Stefan problem with a heat flux condition at the fixed face

A generalized Neumann solution for the two-phase fractional Lam\'e--Clapeyron--Stefan problem for a semi--infinite material with constant initial temperature and a particular heat flux condition at the fixed face is obtained, when a restriction on data is satisfied. The fractional derivative in the Caputo sense of order \al \in (0,1) respect on the temporal variable is considered in two governing heat equations and in one of the conditions for the free boundary. Furthermore, we find a relationship between this fractional free boundary problem and another one with a constant temperature condition at the fixed face and based on that fact, we obtain an inequality for the coefficient which characterizes the fractional phase-change interface obtained in Roscani--Tarzia, Adv. Math. Sci. Appl., 24 (2014), 237-249. We also recover the restriction on data and the classical Neumann solution, through the error function, for the classical two-phase Lam\'e-Clapeyron-Stefan problem for the case \al=1.Comment: 19 pages, 1 figur

One-Phase Stefan-Like Problems with Latent Heat Depending on the Position and Velocity of the Free Boundary and with Neumann or Robin Boundary Conditions at the Fixed Face

A one-phase Stefan-type problem for a semi-infinite material which has as its main feature a variable latent heat that depends on the power of the position and the velocity of the moving boundary is studied. Exact solutions of similarity type are obtained for the cases when Neumann or Robin boundary conditions are imposed at the fixed face. Required relationships between data are presented in order that these problems become equivalent to the problem where a Dirichlet condition at the fixed face is considered. Moreover, in the case where a Robin condition is prescribed, the limit behaviour is studied when the heat transfer coefficient at the fixed face goes to infinity.Fil: Bollati, Julieta. Universidad Austral. Facultad de Ciencias Empresariales. Departamento de Matemáticas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario; ArgentinaFil: Tarzia, Domingo Alberto. Universidad Austral. Facultad de Ciencias Empresariales. Departamento de Matemáticas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario; Argentin

Exact solution for a two-phase Stefan problem with variable latent heat and a convective boundary condition at the fixed face

Recently it was obtained in [Tarzia, Thermal Sci. 21A (2017) 1-11] for the classical two-phase Lam\'e-Clapeyron-Stefan problem an equivalence between the temperature and convective boundary conditions at the fixed face under a certain restriction. Motivated by this article we study the two-phase Stefan problem for a semi-infinite material with a latent heat defined as a power function of the position and a convective boundary condition at the fixed face. An exact solution is constructed using Kummer functions in case that an inequality for the convective transfer coefficient is satisfied generalizing recent works for the corresponding one-phase free boundary problem. We also consider the limit to our problem when that coefficient goes to infinity obtaining a new free boundary problem, which has been recently studied in [Zhou-Shi-Zhou, J. Engng. Math. (2017) DOI 10.1007/s10665-017-9921-y].Comment: 16 pages, 0 figures. arXiv admin note: text overlap with arXiv:1610.0933

Convergence of optimal control problems governed by second kind parabolic variational inequalities

We consider a family of optimal control problems where the control variable is given by a boundary condition of Neumann type. This family is governed by parabolic variational inequalities of the second kind. We prove the strong convergence of the optimal controls and state systems associated to this family to a similar optimal control problem. This work solves the open problem left by the authors in IFIP TC7 CSMO2011