GT2010-23809 SINTERING BEHAVIOR OF PLASMA-SPRAYED Sm 2 Zr 2 O 7 COATING

ABSTRACT Plasma-sprayed thermal barrier coating (TBC) systems are widely used in gas turbine blades to increase turbine entry temperature (TET) and better efficiency. Yttria stabilized zirconia (YSZ) has been the conventional thermal barrier coating material because of its low thermal conductivity, relative high thermal expansion coefficient and good corrosion resistance. However the YSZ coatings can hardly fulfill the harsh requirements in future for higher reliability and the lower thermal conductivity at higher temperatures. Among the interesting TBC candidates, materials with pyrochlore structure show promising thermo-physical properties for use at temperatures exceeding 1200 ºC. Sm 2 Zr 2 O 7 bulk material does not only have high temperature stability, sintering resistance but also lower thermal conductivity and higher thermal expansion coefficient. The sintering characteristics of ceramic thermal barrier coatings under high temperature conditions are complex phenomena. In this paper, samarium zirconate (Sm 2 Zr 2 O 7 , SZ) powder and coatings were prepared by solid state reaction and atmosphere plasma spraying process, respectively. The microstructure development of coatings derived from sintering after heat-treated at 1200-1500 ºC for 50 h have been investigated. The microstructure was examined by scanning electron microscopy (SEM) and the grain growth was analyzed in this paper as well

The substrate cooling effect of ion beam post treatment on ZAO films properties

ZAO thin films with low surface roughness and low sheet resistance are required in the touch panels and display panels. In this work, we investigated the substrate cooling effect of ion beam post treatment on ZAO films properties, and one new way of obtain low surface roughness and low sheet resistance same time was proposed. The more exciting find of this paper is that, comparing to the samples without cooling during the process of ion beam post treatment, samples with proper cooling voltage show a sheet resistance decrease of 26% (from 11.9 Ω/□ to 8.8 Ω/□) and a roughness decrease of 35.5% (from 13.389 nm to 8.637 nm) without transparency losing. And the viewpoint that substrate cooling has the effect of weakening the crystallization, especially for the sub-face and internal parts of samples is deduced

A Pyrazolate Osmium(VI) Nitride Exhibits Anticancer Activity through Modulating Protein Homeostasis in HepG2 Cells

Interest in the third-row transition metal osmium and its compounds as potential anticancer agents has grown in recent years. Here, we synthesized the osmium(VI) nitrido complex Na[OsVI(N)(tpm)2] (tpm = [5-(Thien-2-yl)-1H-pyrazol-3-yl]methanol), which exhibited a greater inhibitory effect on the cell viabilities of the cervical, ovarian, and breast cancer cell lines compared with cisplatin. Proteomics analysis revealed that Na[OsVI(N)(tpm)2] modulates the expression of protein-transportation-associated, DNA-metabolism-associated, and oxidative-stress-associated proteins in HepG2 cells. Perturbation of protein expression activity by the complex in cancer cells affects the functions of the mitochondria, resulting in high levels of cellular oxidative stress and low rates of cell survival. Moreover, it caused G2/M phase cell cycle arrest and caspase-mediated apoptosis of HepG2 cells. This study reveals a new high-valent osmium complex as an anticancer agent candidate modulating protein homeostasis