820 research outputs found
Cross-linked CoMoO4/rGO nanosheets as oxygen reduction catalyst
Development of inexpensive and robust electrocatalysts towards oxygen reduction reaction
(ORR) is crucial for the cost-affordable manufacturing of metal-air batteries and fuel cells. Here
we show that cross-linked CoMoO4 nanosheets and reduced graphene oxide (CoMoO4/rGO) can
be integrated in a hybrid material under one-pot hydrothermal conditions, yielding a composite
material with promising catalytic activity for oxygen reduction reaction (ORR). Cyclic voltammetry
(CV) and linear sweep voltammetry (LSV) were used to investigate the efficiency of the fabricated
CoMoO4/rGO catalyst towards ORR in alkaline conditions. The CoMoO4/rGO composite revealed
the main reduction peak and onset potential centered at 0.78 and 0.89 V (vs. RHE), respectively.
This study shows that the CoMoO4/rGO composite is a highly promising catalyst for the ORR under
alkaline conditions, and potential noble metal replacement cathode in fuel cells and metal-air batteries
Observation of Active Sites for Oxygen Reduction Reaction on Nitrogen-doped Multilayer Graphene
Active sites and catalytic mechanism of nitrogen-doped graphene in oxygen
reduction reaction (ORR) have been extensively studied but are still
inconclusive, partly due to the lack of an experimental method that can detect
the active sites. It is proposed in this report that the active sites on
nitrogen-doped graphene can be determined via the examination of its chemical
composition change before and after ORR. Synchrotron-based X-ray photoelectron
spectroscopy analyses of three nitrogen-doped multilayer graphene samples
reveal that oxygen reduction intermediate OH(ads) which should chemically
attach to the active sites remains on the carbon atoms neighboring pyridinic
nitrogen after ORR. In addition, a high amount of the OH(ads) attachment after
ORR corresponds to a high catalytic efficiency and vice versa. These pinpoint
that the carbon atoms close to pyridinic nitrogen are the main active sites
among the different nitrogen doping configurations
The Physical Properties of Star-Forming Galaxies with Strong [O III] Lines at z=3.25
We present an analysis of physical properties of 34 [O III] emission-line
galaxies (ELGs) at z=3.2540.029 in the Extended Chandra Deep Field South
(ECDFS). These ELGs are selected from deep narrow H2S(1) and broad Ks imaging
of 383 arcmin obtained with CFHT/WIRCam. We construct spectral energy
distributions (SEDs) from U to Ks to derive the physical properties of ELGs.
These [O III] ELGs are identified as starburst galaxies with strong [O III]
lines of L([O III]) ~ 10 - 10 erg s, and have stellar
masses of M* ~ 10-10 M and star formation rates of ~
10-210 M yr. Our results show that 24% of our sample galaxies
are dusty with Av > 1 mag and EW(OIII) ~ 70-500 , which are often
missed in optically selected [O III] ELG samples. Their rest-frame UV and
optical morphologies from HST/ACS and HST/WFC3 deep imaging reveal that these
[O III] ELGs are mostly multiple-component systems (likely mergers) or compact.
And 20% of them are nearly invisible in the rest-frame UV owing to heavy dust
attenuation. Interestingly, we find that our samples reside in an overdensity
consisting of two components: one southeast (SE) with an overdensity factor of
~ 41 over a volume of 13 cMpc and the other
northwest (NW) with ~ 38 over a volume of 10 cMpc.
The two overdense substructures are expected to be virialized at z=0 with a
total mass of ~ 1.1 x 10 M and ~ 4.8 x 10 M, and
probably merge into a Coma-like galaxy cluster.Comment: 22 pages, 11 figures, 3 tables. Accepted for publication in Ap
Calibration of the Timing Performance of GECAM-C
As a new member of the Gravitational wave high-energy Electromagnetic
Counterpart All-sky Monitor (GECAM) after GECAM-A and GECAM-B, GECAM-C
(originally called HEBS), which was launched on board the SATech-01 satellite
on July 27, 2022, aims to monitor and localize X-ray and gamma-ray transients
from 6 keV to 6 MeV. GECAM-C utilizes a similar design to GECAM but
operates in a more complex orbital environment. In this work, we utilize the
secondary particles simultaneously produced by the cosmic-ray events on orbit
and recorded by multiple detectors, to calibrate the relative timing accuracy
between all detectors of GECAM-C. We find the result is 0.1 , which
is the highest time resolution among all GRB detectors ever flown and very
helpful in timing analyses such as minimum variable timescale and spectral
lags, as well as in time delay localization. Besides, we calibrate the absolute
time accuracy using the one-year Crab pulsar data observed by GECAM-C and
Fermi/GBM, as well as GECAM-C and GECAM-B. The results are and , respectively. Finally, we investigate the
spectral lag between the different energy bands of Crab pulsar observed by
GECAM and GBM, which is .Comment: submitte
Ground calibration of Gamma-Ray Detectors of GECAM-C
As a new member of GECAM mission, GECAM-C (also named High Energy Burst
Searcher, HEBS) was launched onboard the SATech-01 satellite on July 27th,
2022, which is capable to monitor gamma-ray transients from 6 keV to 6
MeV. As the main detector, there are 12 gamma-ray detectors (GRDs) equipped for
GECAM-C. In order to verify the GECAM-C GRD detector performance and to
validate the Monte Carlo simulations of detector response, comprehensive
on-ground calibration experiments have been performed using X-ray beam and
radioactive sources, including Energy-Channel relation, energy resolution,
detection efficiency, SiPM voltage-gain relation and the non-uniformity of
positional response. In this paper, the detailed calibration campaigns and data
analysis results for GECAM-C GRDs are presented, demonstrating the excellent
performance of GECAM-C GRD detectors.Comment: third versio
Synchrotron Radiation Dominates the Extremely Bright GRB 221009A
The brightest Gamma-ray burst, GRB 221009A, has spurred numerous theoretical
investigations, with particular attention paid to the origins of ultra-high
energy TeV photons during the prompt phase. However, analyzing the mechanism of
radiation of photons in the MeV range has been difficult because the high
flux causes pile-up and saturation effects in most GRB detectors. In this
letter, we present systematic modeling of the time-resolved spectra of the GRB
using unsaturated data obtained from Fermi/GBM (precursor) and
SATech-01/GECAM-C (main emission and flare). Our approach incorporates the
synchrotron radiation model, which assumes an expanding emission region with
relativistic speed and a global magnetic field that decays with radius, and
successfully fits such a model to the observational data. Our results indicate
that the spectra of the burst are fully in accordance with a synchrotron origin
from relativistic electrons accelerated at a large emission radius. The lack of
thermal emission in the prompt emission spectra supports a
Poynting-flux-dominated jet composition.Comment: 12 pages, 6 figures, 2 tables. Accepted for publication in ApJ
Phylogenetic Comparison of F-Box (FBX) Gene Superfamily within the Plant Kingdom Reveals Divergent Evolutionary Histories Indicative of Genomic Drift
The emergence of multigene families has been hypothesized as a major contributor to the evolution of complex traits and speciation. To help understand how such multigene families arose and diverged during plant evolution, we examined the phylogenetic relationships of F-Box (FBX) genes, one of the largest and most polymorphic superfamilies known in the plant kingdom. FBX proteins comprise the target recognition subunit of SCF-type ubiquitin-protein ligases, where they individually recruit specific substrates for ubiquitylation. Through the extensive analysis of 10,811 FBX loci from 18 plant species, ranging from the alga Chlamydomonas reinhardtii to numerous monocots and eudicots, we discovered strikingly diverse evolutionary histories. The number of FBX loci varies widely and appears independent of the growth habit and life cycle of land plants, with a little as 198 predicted for Carica papaya to as many as 1350 predicted for Arabidopsis lyrata. This number differs substantially even among closely related species, with evidence for extensive gains/losses. Despite this extraordinary inter-species variation, one subset of FBX genes was conserved among most species examined. Together with evidence of strong purifying selection and expression, the ligases synthesized from these conserved loci likely direct essential ubiquitylation events. Another subset was much more lineage specific, showed more relaxed purifying selection, and was enriched in loci with little or no evidence of expression, suggesting that they either control more limited, species-specific processes or arose from genomic drift and thus may provide reservoirs for evolutionary innovation. Numerous FBX loci were also predicted to be pseudogenes with their numbers tightly correlated with the total number of FBX genes in each species. Taken together, it appears that the FBX superfamily has independently undergone substantial birth/death in many plant lineages, with its size and rapid evolution potentially reflecting a central role for ubiquitylation in driving plant fitness
Human Cataract Mutations in EPHA2 SAM Domain Alter Receptor Stability and Function
The cellular and molecular mechanisms underlying the pathogenesis of cataracts leading to visual impairment remain poorly understood. In recent studies, several mutations in the cytoplasmic sterile-Ξ±-motif (SAM) domain of human EPHA2 on chromosome 1p36 have been associated with hereditary cataracts in several families. Here, we have investigated how these SAM domain mutations affect EPHA2 activity. We showed that the SAM domain mutations dramatically destabilized the EPHA2 protein in a proteasome-dependent pathway, as evidenced by the increase of EPHA2 receptor levels in the presence of the proteasome inhibitor MG132. In addition, the expression of wild-type EPHA2 promoted the migration of the mouse lens epithelial Ξ±TN4-1 cells in the absence of ligand stimulation, whereas the mutants exhibited significantly reduced activity. In contrast, stimulation of EPHA2 with its ligand ephrin-A5 eradicates the enhancement of cell migration accompanied by Akt activation. Taken together, our studies suggest that the SAM domain of the EPHA2 protein plays critical roles in enhancing the stability of EPHA2 by modulating the proteasome-dependent process. Furthermore, activation of Akt switches EPHA2 from promoting to inhibiting cell migration upon ephrin-A5 binding. Our results provide the first report of multiple EPHA2 cataract mutations contributing to the destabilization of the receptor and causing the loss of cell migration activity
Synthesis and photovoltaic performance of DPP-based small molecules with tunable energy levels by altering the molecular terminals
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