GREEN SYNTHESIS OF NANOSTRUCTURED ZINC PARTICLES USING AQUEOUS LEAF EXTRACT OF SCHREBERA SWIETENIOIDES ROXB. AND THEIR CATALYTIC APPLICATION IN DEGRADATION OF METHYL ORANGE, CRYSTAL VIOLET DYES AND CHROMIUM METAL

Objective: The present work was aimed to synthesized the zinc nanoparticles (ZnO NPs) using aqueous leaf extract of Schrebera swietenioides Roxb., and further, the green-synthesized ZnO NPs were studied for its efficacy in the degradation of hazardous dyes like methyl orange, crystal violet and hazardous metal such as chromium. Methods: The ZnO NPs were synthesized using aqueous leaf extract of S. swietenioides Roxb., as a green reducing agent and 0.1 M Zinc acetate as metal source and the NPs synthesis was completed within a short period of 6 h. The ZnO NPs synthesized were characterized using SEM, TEM, EDS, XRD, FT-IR and UV-visible spectrophotometer. Further, the synthesized NPs were applied for reduction of pollutant days such as methyl orange, crystal violet and pollutant metal chromium. Results: The synthesis of NPs was monitored by observing the color change in the reaction mixture and UV visible spectral analysis. The UV spectral analysis shows a characteristic absorption wavelength at 379 nm. The synthesized NPs were hexagonal wurtzite form crystals having a spherical shape with rough surfaces with an average size of 68 nm and having 73.7 % of zinc content. At a NPs dose of 1.0 g/l the photocatalytic reduction was observed as 85.33±0.02 %, 86.82±0.095 % and 86.73±0.104 % for crystal violet dye, methyl orange dye and chromium metal, respectively. The NPs shows a high % photocatalytic reduction of chromium metal, crystal violet dye and methyl orange dye with less contact time confirms that the synthesized ZnO NPs were effectively catalyzed the degradation of methyl orange, crystal violet dyes and chromium metal. The NPs were observed to be recyclable and can shows high reduction activity after the completion of three cycles of degradation. Conclusion: Hence it can be concluded that synthesized greener nanocatalyst was efficient for pollutant treatment and demonstrated the power of green biosynthesis for metallic nanoparticles

Simulation of DTC-CBSVPWM fed SPMSM Drive with Five-level Diode Clamped Inverter

In this paper a simulation analysis of DTC-CBSVPWM of SPMSM drive using five-level diode clamped inverter is analyzed. It has simple structure and provides dynamic behavior comparable with classical DTC. Direct Torque Control (DTC) is an accurate controller for permanent magnet synchronous motor (PMSM) due to its robust and fast torque response in steady-state and transient operating condition. However, the main disadvantage of DTC is high ripples in stator current, flux linkage and torque due to the application of same active voltage vector during the whole sample period and possibly several consecutive sample intervals. This can be overcome by using proper modulation technique. Space Vector Modulation (SVM) which synthesizes any voltage vector lying inside the sextant gives good performance, but however the complexity involved is more in calculating angle and sector. To reduce the complexity involved in SVPWM, a novel modulation technique named Unified voltage modulation or carrier based space vector pulse width modulation (CBSVPWM) is described using the concept of effective time. By using this method the inverter output voltage is directly synthesized by the effective times and the voltage modulation task can be greatly simplified. The actual gating signals for each inverter arm can be easily deduced as a simple form using the effective time relocation algorithm

GREEN SYNTHESIS OF ZINC OXIDE NANOPARTICLES USING SCHREBERA SWIETENIOIDES ROXB., AQUEOUS LEAF EXTRACT AND INVESTIGATION OF ITS EFFECT ON SEED GERMINATION AND PLANT GROWTH ON PIGEON PEA (CAJANUS CAJAN LINN.)

Objective: The present work intended to green and eco-friendly synthesis of Zinc oxide (ZnO) nano particles (NPs) using aqueous leaf extract of Schrebera swietenioides and the synthesised NPs were applied for enhancement of seed germination and plant growth in pigeon pea (Cajanus cajan Linn.). Methods: The Zinc acetate was utilised as metal source and metal was reduced using aqueous leaf extract of S. swietenioides as green reducing agent. The synthesised NPs were characterized using various techniques such as SEM-EDS, TEM, XRD, FT-IR and UV-visible spectrophotometer. The seed germination study as well as plant growth promotion activity, was performed on pigeon pea seeds. Results: The result achieved in characterization of NPs confirms that he NPs were hexagonal wurtzite form having a spherical shape with irregular surfaces. The average size was found to be 68 nm with the metal composition of 73.7 %. The NPs were studied for seed germination and growth promotion activity on pigeon pea seeds and the mean germination time was observed to be 38.60±0.56, 28.53±0.59 and 37.53±0.40 h whereas the final germination percentage was found as 91.33±0.58, 98.00±1.00, and 92.67±1.15 h for control, NPs treated and zinc acetate treated seeds respectively. The NPs treated plants grow more rapidly than the untreated as well as Zn acetate-treated pigeon pea plants. The pigeon pea seeds treated with ZnO NPs shows the high activity of enzyme activities such as amylases, protease, catalase than the untreated as well as Zn acetate treated seeds. Conclusion: The aqueous leaf extract of S. swietenioides mediated ZnO NPs can augment the growth of pigeon pea seedlings, and the NPs treatment shows a stimulatory effect on the enzymes associated with the growth of seedlings

Treatment of electroplating effluent through emulsion-free liquid embrane

Separation of dissolved heavy metals such-as Cr(VI) and Cu(II) from electroplating effluents using a new technique of emulsion-free liquid membrane (EFLM) has been studied. Experimental results show that nearly 95% extraction is obtained resulting in stripping phase enrichment up to 50 times relative to feed. It is also found that emulsion-free liquid membranes are highly efficient and superior to other types of liquid membranes

Treatment of electroplating effluent through emulsion-free liquid membrane

21-24<span style="font-size:11.0pt;line-height: 115%;font-family:Calibri;mso-fareast-font-family:" times="" new="" roman";mso-bidi-font-family:="" "times="" roman";mso-ansi-language:en-us;mso-fareast-language:en-us;="" mso-bidi-language:ar-sa"="" lang="EN-US">Separation of dissolved heavy metals such-as Cr(VI) and Cu(II) from electroplating effluents using a new technique of emulsion-free liquid membrane (EFLM) has been studied. Experimental results show that nearly 95% extraction is obtained resulting in stripping phase enrichment up to 50 times relative to feed. It is also found that emulsion-free liquid membranes are highly efficient and superior to other types of liquid membranes.</span

VHF and L-band scintillation characteristics over an Indian low latitude station, Waltair (17.7° N, 83.3° E)

Characteristics of simultaneous VHF (244 MHz) and L-band (1.5 GHz) scintillations recorded at a low-latitude station, Waltair (17.7° N, 83.3° E), during the low sunspot activity year of March 2004 to March 2005, suggest that the occurrence of scintillations is mainly due to two types, namely the Plasma Bubble Induced (PBI), which maximizes during the post sunset hours of winter and equinoctial months, and the Bottom Side Sinusoidal (BSS) type, which maximizes during the post-midnight hours of the summer solstice months. A detailed study on the spectral characteristics of the scintillations at both the frequencies show that the post-sunset scintillations are strong with fast fading (≈40 fad/min) and are multiple in nature in scattering, giving rise to steep spectral slopes, whereas the post-midnight scintillations, which occur mostly on the VHF signal with low fading rate (≈4 fad/min), are of the BSS type, often showing typical Fresnel oscillations with reduced roll off spectral slopes, indicating that the type of irregularity resembles a thin screen structure giving rise to weak scattering. Using the onset times of several similar scintillation patches across the two satellite (FLEETSAT 73° E, INMARSAT 65° E) ray paths (sub-ionospheric points are separated by 82 km), the East ward movement of the irregularity patches is found to vary from 150 to 250 m/s during the post sunset hours and decrease slowly during the post midnight hours. Further, the east-west extent of the PBI type of irregularities is found to vary from 100 to 500 km, while that of the BSS type extend up to a few thousand kilometers. Keywords. Ionosphere (Ionospheric irregularities; Auroral ionosphere; Electric fields and currents