2,632 research outputs found
Justice and security in the United Kingdom
This paper outlines the ways in which the United Kingdom manages civil litigation concerning sensitive national security material. These are: the common law of public interest immunity; the use of closed material procedure and special advocates; and the secret hearings of the Investigatory Powers Tribunal. With these existing alternatives in mind the paper analyses the background to, the reasons for, and the controversies associated with the Justice and Security Act 2013, enacted in the wake of the UK Supreme Courtâs 2011 ruling in Al Rawi v Security Service
Whatâs left of the political constitution?
This paper argues that we should move on from what has become a rather outdated contrast between the political constitution and the legal constitution. Taking as its focus the constitution of the United Kingdom, the paper analyzes the contemporary constitutional order as a mixed system of politics and law combined. It argues that such a mix may be a more compelling and attractive system than either the model of the political constitution or that of the legal constitution
Separate zones of sulfate and sulfide release from subducted mafic oceanic crust
Liberation of fluids during subduction of oceanic crust is thought to transfer sulfur into the overlying sub-arc mantle. However, despite the importance of sulfur cycling through magmatic arcs to climate change, magma oxidation and ore formation, there has been little investigation of the metamorphic reactions responsible for sulfur release from subducting slabs. Here, we investigate the relative stability of anhydrite (CaSO4) and pyrite (FeS2) in subducted basaltic oceanic crust, the largest contributor to the subducted sulfur budget, to place constraints on the processes controlling sulfur release. Our analysis of anhydrite stability at high pressures suggests that this mineral should dominantly dissolve into metamorphic fluids released across the transition from blueschist to eclogite facies (~450â650â°C), disappearing at lower temperatures on colder geothermal trajectories. In contrast, we suggest that sulfur release via conversion of pyrite to pyrrhotite occurs at temperatures above 750â°C. This higher temperature stability is indicated by the preservation of pyriteâbornite inclusions in coesite-bearing eclogites from the Sulu Belt in China, which reached temperatures of at least 750â°C.Thus, sulfur may be released from subducting slabs in two separate pulses; (1) varying proportions of SO2, HSO4â and H2S are released via anhydrite breakdown at the blueschistâeclogite transition, promoting oxidation of remaining silicates in some domains, and (2) H2S is released via pyrite breakdown well into the eclogite facies, which may in some circumstances coincide with slab melting or supercritical liquid generation driven by influx of serpentinite-derived fluids. These results imply that the metallogenic potential in the sub-arc mantle above the subducting slab varies as a function of subduction depth, having the greatest potential above the blueschistâeclogite transition given the association between oxidised magmas and porphyry Cu(âAuâMo) deposits. We speculate that this zoned sulfur liberation might be one of the factors that lead to the apparently redox-influenced zoned distribution of ore deposit types in the Andean arc. Furthermore, given the lack of sulfate-associated sea floor oxidation prior to the second great oxidation event, the pattern of sulfur transfer from the slab to the sub-arc mantle likely changed over time, becoming shallower and more oxidised from the Neoproterozoic onwards
Comparison of the Effects of Supplemental Red Palm Oil and Sunflower oil on Maternal Vitamin A Status.
Conflicting results have been reported on the ability of dietary carotenoids to improve vitamin A status in lactating women. Red palm oil is one of the richest dietary sources of beta-carotene. We aimed to determine the efficacy of red palm oil in increasing retinol and provitamin A status in pregnant and lactating women. Ninety rural, pregnant Tanzanian women from 3 randomly selected villages were recruited during their third trimester to participate in 3 dietary intervention groups: a control group, who were encouraged to maintain the traditional practice of eating staples with dark-green leafy vegetables, and 2 study groups, who were given either sunflower or red palm oil for use in household food preparations. The intervention lasted 6 mo. Plasma samples were collected at the third trimester and 1 and 3 mo postpartum, and breast-milk samples were collected 1 and 3 mo postpartum. Supplementation with red palm oil, which is rich in provitamin A, increased alpha- and beta-carotene concentrations significantly (P < 0.001) in both plasma and breast milk. Plasma retinol concentrations were similar in all dietary groups. Breast-milk retinol concentrations tended to decrease from 1 to 3 mo postpartum in the control group, but were maintained in both oil groups. The difference in change in breast-milk retinol concentration between the red palm oil group and the control group was significant (P = 0.041). Consumption of red palm oil increases concentrations of alpha- and beta-carotene in both breast milk and serum and maintains breast-milk retinol concentrations. Sunflower oil consumption seems to conserve breast-milk retinol similarly to consumption of red palm oil. Breast-milk retinol might be maintained through increased dietary intake of these vegetable oils and use of mild cooking preparation methods (such as the addition of oil at the end of cooking and avoidance of frying)
Vogt-Koyanagi-Harada syndrome - current perspectives
Vogt-Koyanagi-Harada syndrome is a cause of noninfectious panuveitis, leading to significant vision loss in many patients. It is an autoimmune disease occurring in genetically susceptible individuals and clinically presents as bilateral panuveitis with serous retinal detachments and hyperemic, swollen optic discs, which are associated with neurological and auditory manifestations. Early diagnosis and prompt and adequate treatment with immunosuppressive agents (corticosteroids and other immunosuppressive drugs) may halt disease progression and prevent recurrences and vision loss. This review summarizes the current knowledge on the variable clinical aspects of this disease, highlighting diagnostic and treatment strategies
Maternal micronutrient status and decreased growth of Zambian infants born during and after the maize price increases resulting from the southern African drought of 2001-2002.
OBJECTIVE: To investigate the effects on maternal micronutrient status and infant growth of the increased maize prices that resulted from the southern African drought of 2001-2002. DESIGN: Longitudinal cohort study. SETTING: A maternal and child health clinic in Lusaka, Zambia. SUBJECTS: Maternal and infant health and nutrition data and maternal plasma were being collected for a study of breast-feeding and postpartum health. Samples and data were analysed according to whether they were collected before (June to December 2001), during (January 2002 to April 2003) or after (May 2003 to January 2004) the period of increased maize price. Season and maternal HIV status were controlled for in analyses. RESULTS: Maize price increases were associated with decreased maternal plasma vitamin A during pregnancy (P = 0.028) and vitamin E postpartum (P = 0.042), with the lowest values among samples collected after May 2003 (vitamin A: 0.96 micromol l(-1), 95% confidence interval (CI) 0.84-1.09, n = 38; vitamin E: 30.8 micromol mmol(-1) triglycerides, 95% CI 27.2-34.8, n = 64) compared with before January 2002 (vitamin A: 1.03 micromol l(-1), 95% CI 0.93-1.12, n = 104; vitamin E: 38.9 micromol mmol(-1) triglycerides, 95% CI 34.5-43.8, n = 47). There were no significant effects of sampling date on maternal weight, haemoglobin or acute-phase proteins and only marginal effects on infant weight. Infant length at 6 and 16 weeks of age decreased progressively throughout the study (P-values for time of data collection were 0.51 at birth, 0.051 at 6 weeks and 0.026 at 16 weeks). CONCLUSIONS: The results show modest effects of the maize price increases on maternal micronutrient status. The most serious consequence of the price increases is likely to be the increased stunting among infants whose mothers experienced high maize prices while pregnant. During periods of food shortages it might be advisable to provide micronutrient supplements even to those who are less food-insecure
Experimental Resonance Enhanced Multiphoton Ionization (REMPI) studies of small molecules
Resonance enhanced multiphoton ionization (REMPI) utilizes tunable dye lasers to ionize an atom or molecule by first preparing an excited state by multiphoton absorption and then ionizing that state before it can decay. This process is highly selective with respect to both the initial and resonant intermediate states of the target, and it can be extremely sensitive. In addition, the products of the REMPI process can be detected as needed by analyzing the resulting electrons, ions, fluorescence, or by additional REMPI. This points to a number of exciting opportunities for both basic and applied science. On the applied side, REMPI has great potential as an ultrasensitive, highly selective detector for trace, reactive, or transient species. On the basic side, REMPI affords an unprecedented means of exploring excited state physics and chemistry at the quantum-state-specific level. An overview of current studies of excited molecular states is given to illustrate the principles and prospects of REMPI
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