Risk assessment of nitrate transport through subsurface layers and groundwater using experimental and modeling approach

Landfills are one of the main point sources of groundwater pollution. This research mainly aims to assess the risk of nitrate (NO-3) transport from the unlined landfill to subsurface layers and groundwater using experimental results and the SESOIL model. Samples from 12 groundwater wells downstream of the landfill were collected and analyzed in 2008, 21 years after the landfill construction. The average NO-3 concentration in the wells was 54 mg/L, slightly higher than the World Health Organization (NO-350 mg/L) standards. SESOIL model was used to predict the NO-3 concentration at the bottom of the unsaturated zone. Results indicated that the current mean NO-3 concentration at the bottom of the unsaturated zone is 75 mg/L. the model predicted that the level of NO3 will increased up to 325 mg/L within 30 years. Accordingly, the NO-3 concentration in groundwater wells near the landfill area is expected to gradually increase with time. Although the current risk associated with the NO-3 level might not be harm to adults, however, it might pose severe risks to both adults and infants in the near future due to NO-3 leaching. Urgent mitigation measures such as final cell cover (cap), lining system and vertical expansion should be considered at the landfill to protect the public health in the area. © 2017, © 2017 Informa UK Limited, trading as Taylor & Francis Group

Evaluating impacts of recharging partially treated wastewater on groundwater aquifer in semi-arid region by integration of monitoring program and GIS technique

The current study investigates the impact of recharging of partially treated wastewater through an infiltration basin on the groundwater aquifer quality parameters. A monitoring program supported by a geographic information analysis (GIS) tool was used to conduct this study. Groundwater samples from the entire surrounding boreholes located downstream the infiltration basin, in addition to samples from the recharged wastewater coming from the Beit Lahia wastewater treatment (BLWWTP), were monitored and analysed between 2011 and 2014. The analysis was then compared with the available historical data since 2008. Results revealed a groundwater replenishment with the groundwater level increased by 1.0–2.0 m during the study period. It also showed a slight improvement in the groundwater quality parameters, mainly a decrease in TDS, Cl⁻ and NO3⁻ levels by 5.5, 17.1 and 20%, respectively, resulting from the relatively better quality of the recharged wastewater. Nevertheless, the level of boron and ammonium in the groundwater wells showed a significant increase over time by 96 and 100%, respectively. Moreover, the infiltration rate was slowed down in time due to the relatively high level of total suspended solid (TSS) in the infiltrated wastewater

Simultaneous multifunctional sorption of PFOS and Cr(VI) on activated carbon prepared by one-step microwave activation

Multifunctional sorbents, activated carbons (AC), were prepared by one-step microwave activation utilizing peanut shells and sunflower seed husks. The influence of the original particle size of raw materials on the yield and specific surface area of AC was studied, which reached 33.5 % and 1133.27 m(2)/g, respectively. The repetitive and competitive uptakes of perfluorooctane sulfonate (PFOS) and chromium were applied to investigate the sorption properties of AC. The sorption mechanisms were demonstrated using sulfur Kedge X-ray absorption near edge structure analysis (XANES). In the repetitive experiment, AC made from peanut shells (AC(P05)) still retained 70 % removal efficiency of PFOS after the fourth sorption because sorbed PFOS might form a new organic phase that supplied effective sites for the hydrophobic partition of PFOS. However, the removal efficiency of Cr(VI) decreased dramatically from 60 to 11 % after the fourth uptake because electrostatic attraction was its only removal pathway. In the binary solutes system, AC(P05) possessed perfect sorption performance for both PFOS and Cr(VI), which were 885 and 192 mg/g, respectively. In the multivariate solutes system, the XANES spectra indicated that the thiol functional group existed in the resulting AC and a metal chelate was formed between thiol and Zn2+/Cu2+. Hence, the presence of Zn2+/Cu2+ further promoted the removal of PFOS and Cr(VI) through the electrostatic attraction between the anions and positive metal chelate