Infrared spectra of the cluster ions H7O⁺₃·H2 and H9O⁺₄·H2

Infrared spectra of hydrated hydronium ions weakly bound to an H2 molecule, specifically H7O + 3 ·H2 and H9O + 4 ·H2, have been observed. Mass-selected parent ions, trapped in a radio frequency ion trap, are excited by a tunable infrared laser; following absorption, the complex predissociates with loss of the H2, and the resulting fragment ions are detected. Spectra have been taken from 3000 to 4000 cm^−1, with a resolution of 1.2 cm^−1. They are compared to recent theoretical and experimental spectra of the hydronium ion hydrates alone. Binding an H2 molecule to these clusters should only weakly perturb their vibrations; if so, our spectra should be similar to spectra of the hydrated hydronium ions H7O + 3 and H9O + 4

Two-stage composite megathrust rupture of the 2015 M(w)8.4 Illapel, Chile, earthquake identified by spectral-element inversion of teleseismic waves

The Mw8.4 Illapel earthquake occurred on 16 September was the largest global event in 2015. This earthquake was not unexpected because the hypocenter was located in a seismic gap of the Peru-Chile subduction zone. However, the source model derived from 3-D spectral-element inversion of teleseismic waves reveals a distinct two-stage rupture process with completely different slip characteristics as a composite megathrust event. The two stages were temporally separated. Rupture in the first stage, with a moment magnitude of Mw8.32, built up energetically from the deeper locked zone and propagated in the updip direction toward the trench. Subsequently, the rupture of the second stage, with a magnitude of Mw8.08, mainly occurred in the shallow subduction zone with atypical repeating slip behavior. The unique spatial-temporal rupture evolution presented in this source model is key to further in-depth studies of earthquake physics and source dynamics in subduction systems

Antrodia cinnamomea reduces obesity and modulates the gut microbiota in high-fat diet-fed mice.

BackgroundObesity is associated with gut microbiota dysbiosis, disrupted intestinal barrier and chronic inflammation. Given the high and increasing prevalence of obesity worldwide, anti-obesity treatments that are safe, effective and widely available would be beneficial. We examined whether the medicinal mushroom Antrodia cinnamomea may reduce obesity in mice fed with a high-fat diet (HFD).MethodsMale C57BL/6J mice were fed a HFD for 8 weeks to induce obesity and chronic inflammation. The mice were treated with a water extract of A. cinnamomea (WEAC), and body weight, fat accumulation, inflammation markers, insulin sensitivity and the gut microbiota were monitored.ResultsAfter 8 weeks, the mean body weight of HFD-fed mice was 39.8±1.2 g compared with 35.8±1.3 g for the HFD+1% WEAC group, corresponding to a reduction of 4 g or 10% of body weight (P<0.0001). WEAC supplementation reduced fat accumulation and serum triglycerides in a statistically significant manner in HFD-fed mice. WEAC also reversed the effects of HFD on inflammation markers (interleukin-1β, interleukin-6, tumor necrosis factor-α), insulin resistance and adipokine production (leptin and adiponectin). Notably, WEAC increased the expression of intestinal tight junctions (zonula occludens-1 and occludin) and antimicrobial proteins (Reg3g and lysozyme C) in the small intestine, leading to reduced blood endotoxemia. Finally, WEAC modulated the composition of the gut microbiota, reducing the Firmicutes/Bacteroidetes ratio and increasing the level of Akkermansia muciniphila and other bacterial species associated with anti-inflammatory properties.ConclusionsSupplementation with A. cinnamomea produces anti-obesogenic, anti-inflammatory and antidiabetic effects in HFD-fed mice by maintaining intestinal integrity and modulating the gut microbiota

Superconducting Gap and Pseudogap in Iron-Based Layered Superconductor La(O1−x_{1-x}Fx_x)FeAs

We report high-resolution photoemission spectroscopy of newly-discovered iron-based layered superconductor La(O$_{0.93}$F$_{0.07}$)FeAs (Tc = 24 K). We found that the superconducting gap shows a marked deviation from the isotropic s-wave symmetry. The estimated gap size at 5 K is 3.6 meV in the s- or axial p-wave case, while it is 4.1 meV in the polar p- or d-wave case. We also found a pseudogap of 15-20 meV above Tc, which is gradually filled-in with increasing temperature and closes at temperature far above Tc similarly to copper-oxide high-temperature superconductors.Comment: 4 pages, 3 figures, J. Phys. Soc. Jpn. Vol. 77, No. 6 (2008), in pres

Evolution of superconductivity by oxygen annealing in FeTe0.8S0.2

Oxygen annealing dramatically improved the superconducting properties of solid-state-reacted FeTe0.8S0.2, which showed only a broad onset of superconducting transition just after the synthesis. The zero resistivity appeared and reached 8.5 K by the oxygen annealing at 200\degree C. The superconducting volume fraction was also enhanced from 0 to almost 100%. The lattice constants were compressed by the oxygen annealing, indicating that the evolution of bulk superconductivity in FeTe0.8S0.2 was correlated to the shrinkage of lattice.Comment: 13 pages, 6 figure

High Relief from Brush Painting

Relief is an art form part way between 3D sculpture and 2D painting. We present a novel approach for generating a texture-mapped high-relief model from a single brush painting. Our aim is to extract the brushstrokes from a painting and generate the individual corresponding relief proxies rather than recovering the exact depth map from the painting, which is a tricky computer vision problem, requiring assumptions that are rarely satisfied. The relief proxies of brushstrokes are then combined together to form a 2.5D high-relief model. To extract brushstrokes from 2D paintings, we apply layer decomposition and stroke segmentation by imposing boundary constraints. The segmented brushstrokes preserve the style of the input painting. By inflation and a displacement map of each brushstroke, the features of brushstrokes are preserved by the resultant high-relief model of the painting. We demonstrate that our approach is able to produce convincing high-reliefs from a variety of paintings(with humans, animals, flowers, etc.). As a secondary application, we show how our brushstroke extraction algorithm could be used for image editing. As a result, our brushstroke extraction algorithm is specifically geared towards paintings with each brushstroke drawn very purposefully, such as Chinese paintings, Rosemailing paintings, etc

Ground vibrations and airborne sounds generated by motion of rock in a river bed

This study investigates how ground vibrations (underground sounds) and airborne sounds that are produced by rocks in a river bed differ from each other. Airborne and underground sounds were simultaneously received at three microphones and three geophones, respectively. These sound signals were then analyzed using both the Fast Fourier Transform and the Gabor Transform to represent them in both the frequency and time-frequency domains. Experimental data indicate that the frequency of both airborne and underground sounds produced by the impact of rocks against the river bed is in the range 10–150 Hz. Furthermore, the high-frequency band of underground sounds decays much more rapidly than that of airborne sounds. The spatial decay rate of airborne sounds was also determined and compared with theoretical values. The lower spatial decay rate of airborne sounds than that of underground sounds suggests that monitoring of airborne sounds may be more efficient in the detection of debris flows or other natural hazards that generate both airborne and underground sounds

Vibrational spectroscopy of the hydrated hydronium cluster ions H3O+·(H2O)n (n=1, 2, 3)

The gas phase infrared spectra of the hydrated hydronium cluster ions H3O+·(H2O)n(n=1, 2, 3) have been observed from 3550 to 3800 cm^−1. The new spectroscopic method developed for this study is a two color laser scheme consisting of a tunable cw infrared laser with 0.5 cm^−1 resolution used to excite the O–H stretching vibrations and a cw CO2 laser that dissociates the vibrationally excited cluster ion through a multiphoton process. The apparatus is a tandem mass spectrometer with a radio frequency ion trap that utilizes the following scheme: the cluster ion to be studied is first mass selected; spectroscopic interrogation then occurs in the radio frequency ion trap; finally, a fragment ion is selected and detected using ion counting techniques. The vibrational spectra obtained in this manner are compared with that taken previously using a weakly bound H2 "messenger." A spectrum of H7 O + 3 taken using a neon messenger is also presented. Ab initio structure and frequency predictions by Remington and Schaefer are compared with the experimental results

Role of the Built Environment in the Recovery From COVID-19: Evidence From a GIS-Based Natural Experiment on the City Blocks in Wuhan, China

The built environment closely relates to the development of COVID-19 and post-disaster recovery. Nevertheless, few studies examine its impacts on the recovery stage and corresponding urban development strategies. This study examines the built environment’s role in Wuhan’s recovery at the city block level through a natural experiment. We first aggregated eight built environmental characteristics (BECs) of 192 city blocks from the perspectives of density, infrastructure supply, and socioeconomic environment; then, the BECs were associated with the recovery rates at the same city blocks, based on the public “COVID-19-free” reports of about 7,100 communities over the recovery stages. The results showed that three BECs, i.e., “number of nearby designated hospitals,” “green ratio,” and “housing price” had significant associations with Wuhan’s recovery when the strict control measures were implemented. At the first time of reporting, more significant associations were also found with “average building age,” “neighborhood facility development level,” and “facility management level.” In contrast, no associations were found for “controlled residential land-use intensity” and “plot ratio” throughout the stages. The findings from Wuhan’s recovery pinpointing evidence with implications in future smart and resilient urban development are as follows: the accessibility of hospitals should be comprehensive in general; and the average housing price of a city block can reflect its post-disaster recoverability compared to that of the other blocks