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Unfolding the impacts of transaction-specific investments: Moderation by out-of-thechannel-loop perceptions and achievement orientations
When distribution channel partners make specific investments, tailored to a particular supplier, it could prompt either opportunism or beneficial (e.g., extra-role) behaviors. The impact of the investment in turn may depend on whether the channel partner perceives that it is being left out of the channel loop by the supplier, as well as that partner’s achievement orientation. This study considers a sample of 155 IT professional service firms and finds that their knowledge-intensive, transaction-specific investments (TSIs) encourage distinct behavioral intentions. If they perceive that the supplier is leaving them out of the channel loop, the effects of the TSIs get amplified in relation to opportunistic and extra-role behavioral intentions. Furthermore, the firms’ achievement orientation moderates these influences. Suppliers thus should attend closely to achievement-oriented partners to ensure they do not perceive that they have been left out of the channel loop
Albedo and flux extinction coefficient of impure snow for diffuse shortwave radiation
Impurities enter a snowpack as a result of fallout of scavenging by falling snow crystals. Albedo and flux extinction coefficient of soot contaminated snowcovers were studied using a two stream approximation of the radiative transfer equation. The effect of soot was calculated by two methods: independent scattering by ice grains and impurities and average refractive index for ice grains. Both methods predict a qualitatively similar effect of soot; the albedo is decreased and the extinction coefficient is increased compared to that for pure snow in the visible region; the infrared properties are largely unaffected. Quantitatively, however, the effect of soot is more pronounced in the average refractive index method. Soot contamination provides a qualitative explanation for several snow observations
Decays of and into vector and pseudoscalar meson and the pseudoscalar glueball- mixing
We introduce a parametrization scheme for where
the effects of SU(3) flavor symmetry breaking and doubly OZI-rule violation
(DOZI) can be parametrized by certain parameters with explicit physical
interpretations. This scheme can be used to clarify the glueball-
mixing within the pseudoscalar mesons. We also include the contributions from
the electromagnetic (EM) decays of and via
. Via study of the isospin violated
channels, such as , ,
and , reasonable constraints on the EM decay
contributions are obtained. With the up-to-date experimental data for
, and , etc, we arrive at a consistent description of the mentioned
processes with a minimal set of parameters. As a consequence, we find that
there exists an overall suppression of the form factors,
which sheds some light on the long-standing " puzzle". By determining
the glueball components inside the pseudoscalar and in
three different glueball- mixing schemes, we deduce that the lowest
pseudoscalar glueball, if exists, has rather small component, and it
makes the a preferable candidate for glueball.Comment: Revised version to appear on J. Phys. G; An error in the code was
corrected. There's slight change to the numerical results, while the
conclusion is intac
Liquefaction of H2 molecules upon exterior surfaces of carbon nanotube bundles
We have used molecular dynamics simulations to investigate interaction of H2 molecules on the exterior surfaces of carbon nanotubes (CNTs): single and bundle types. At 80 K and 10 MPa, it is found that charge transfer occurs from a low curvature region to a high curvature region of the deformed CNT bundle, which develops charge polarization only on the deformed structure. The long-range electrostatic interactions of polarized charges on the deformed CNT bundle with hydrogen molecules are observed to induce a high local-ordering of H2 gas that results in hydrogen liquefaction. Our predicted heat of hydrogen liquefaction on the CNT bundle is 97.6 kcal kg^-1. On the other hand, hydrogen liquefaction is not observed in the CNT of a single type. This is because charge polarization is not developed on the single CNT as it is symmetrically deformed under the same pressure. Consequently, the hydrogen storage capacity on the CNT bundle is much higher due to liquefaction than that on the single CNT. Additionally, our results indicate that it would also be possible to liquefy H2 gas on a more strongly polarized CNT bundle at temperatures higher than 80 K
The theoretical study on interaction of hydrogen with single-walled boron nitride nanotubes. I. The reactive force field ReaxFFHBN development
We present a new reactive force field ReaxFFHBN derived to accurately model large molecular and condensed phase systems of H, B, and N atoms. ReaxFFHBN has been tested against quantum calculation data for B–H, B–B, and B–N bond dissociations and for H–B–H, B–N–B, and N–B–N bond angle strain energies of various molecular clusters. The accuracy of the developed ReaxFFHBN for B–N–H systems is also tested for (i) H–B and H–B bond energies as a function of out of plane in H–B(NH2)3 and H–N(BH2)3, respectively, (ii) the reaction energy for the B3N3H6+H2-->B3N3H8, and (iii) crystal properties such as lattice parameters and equations of states for the hexagonal type (h-BN) with a graphite structure and for the cubic type (c-BN) with a zinc-blende structure. For all these systems, ReaxFFHBN gives reliable results consistent with those from quantum calculations as it describes well bond breaking and formation in chemical processes and physical properties. Consequently, the molecular-dynamics simulation based on ReaxFFHBN is expected to give a good description of large systems (>2000 atoms even on the one-CPU machine) with hydrogen, boron, and nitrogen atoms
Theoretical study on interaction of hydrogen with single-walled boron nitride nanotubes. II. Collision, storage, and adsorption
Collision and adsorption of hydrogen with high incident kinetic energies on a single-walled boron nitride (BN) nanotube have been investigated. Molecular-dynamics (MD) simulations indicate that at incident energies below 14 eV hydrogen bounces off the BN nanotube wall. On the other hand, at incident energies between 14 and 22 eV each hydrogen molecule is dissociated at the exterior wall to form two hydrogen atoms, but only one of them goes through the wall. However, at the incident energies between 23 and 26 eV all of the hydrogen atoms dissociated at the exterior wall are found to be capable of going inside the nanotube and then to recombine to form hydrogen molecules inside the nanotube. Consequently, it is determined that hydrogen should have the incident energy >22 eV to go inside the nanotube. On the other hand, we find that the collisions using the incident energies >26 eV could result in damaging the nanotube structures. In addition our MD simulations find that hydrogen atoms dissociated at the wall cannot bind to either boron or nitrogen atoms in the interior wall of the nanotube
Stochastic Biasing and Weakly Non-linear Evolution of Power Spectrum
Distribution of galaxies may be a biased tracer of the dark matter
distribution and the relation between the galaxies and the total mass may be
stochastic, non-linear and time-dependent. Since many observations of galaxy
clustering will be done at high redshift, the time evolution of non-linear
stochastic biasing would play a crucial role for the data analysis of the
future sky surveys. In this paper, we develop the weakly non-linear analysis
and attempt to clarify the non-linear feature of the stochastic biasing. We
compute the one-loop correction of the power spectrum for the total mass, the
galaxies and their cross correlation. Assuming the local functional form for
the initial galaxy distribution, we investigate the time evolution of the
biasing parameter and the correlation coefficient. On large scales, we first
find that the time evolution of the biasing parameter could deviate from the
linear prediction in presence of the initial skewness. However, the deviation
can be reduced when the initial stochasticity exists. Next, we focus on the
quasi-linear scales, where the non-linear growth of the total mass becomes
important. It is recognized that the scale-dependence of the biasing
dynamically appears and the initial stochasticity could affect the time
evolution of the scale-dependence. The result is compared with the recent
N-body simulation that the scale-dependence of the halo biasing can appear on
relatively large scales and the biasing parameter takes the lower value on
smaller scales. Qualitatively, our weakly non-linear results can explain this
trend if the halo-mass biasing relation has the large scatter at high redshift.Comment: 29pages, 7 postscript figures, submitted to Ap
Gravity and Large-Scale Non-local Bias
The relationship between galaxy and matter overdensities, bias, is most often
assumed to be local. This is however unstable under time evolution, we provide
proofs under several sets of assumptions. In the simplest model galaxies are
created locally and linearly biased at a single time, and subsequently move
with the matter (no velocity bias) conserving their comoving number density (no
merging). We show that, after this formation time, the bias becomes unavoidably
non-local and non-linear at large scales. We identify the non-local
gravitationally induced fields in which the galaxy overdensity can be expanded,
showing that they can be constructed out of the invariants of the deformation
tensor (Galileons). In addition, we show that this result persists if we
include an arbitrary evolution of the comoving number density of tracers. We
then include velocity bias, and show that new contributions appear, a dipole
field being the signature at second order. We test these predictions by
studying the dependence of halo overdensities in cells of fixed matter density:
measurements in simulations show that departures from the mean bias relation
are strongly correlated with the non-local gravitationally induced fields
identified by our formalism. The effects on non-local bias seen in the
simulations are most important for the most biased halos, as expected from our
predictions. The non-locality seen in the simulations is not fully captured by
assuming local bias in Lagrangian space. Accounting for these effects when
modeling galaxy bias is essential for correctly describing the dependence on
triangle shape of the galaxy bispectrum, and hence constraining cosmological
parameters and primordial non-Gaussianity. We show that using our formalism we
remove an important systematic in the determination of bias parameters from the
galaxy bispectrum, particularly for luminous galaxies. (abridged)Comment: 26 pages, 9 figures. v2: improved appendix
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