968 research outputs found

    Perovskite thin films under the microscope: The impact of grain passivation on morphology and stability

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    Sex pheromone components of an undescribed Choristoneura species (Lepidoptera: Tortricidae) on lodgepole pine in British Columbia

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    E11-tetradecenyl acetate (E11-14 OAc) and Z11-tetradecenyl acetate (Z11-14 OAc) are sex pheromone components of an undescribed, pine-feeding Choristoneura (C. n. sp. CPG=Prince George) in British Columbia. Compounds were identified by coupled gas chromatographic- electroantennographic (GC-EAD) and coupled gas chromatographic-mass spectroscopic (GC-MS) analyses, and were field tested near Prince George, B.C. A 65:35 blend of E11-14 OAc and Z11-14 OAc attracted as many male C. n. sp. CPG as did the most attractive virgin fema1es, suggesting that the natural sex pheromone has only two significant components. This two-component blend is suggested for detecting and monitoring C. n. sp. CPG populations

    Skill Variety, Innovation and New Business Formation

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    __Abstract__ We extend Lazear’s theory of skills variety and entrepreneurship in three directions. First, we provide a theoretical framework linking new business creation with an entrepreneur’s skill variety. Second, in this model we allow for both generalists and specialists to possess skill variety. Third, we test our model empirically using data from Germany and the Netherlands. Individuals with more varied work experience seems indeed more likely to successfully start up a new business and being a generalist does not seem to be important in this regard. Finally, we find that innovation positively moderates the relationship between having varied experiences, and being successful in starting up a new business. Our conclusion is that entrepreneurs with more varied work experience are more likely to introduce innovations that have not only technical, but also commercial value. Our findings support the notion that entrepreneurship can be learned

    Invasive Techniken in der Notfallmedizin: IV. Koniotomie im Notarztdienst

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    Zusammenfassung: Die Koniotomie im Notarztdienst ist eine sehr invasive Methode zur Atemwegssicherung. Sie ist aber unabdingbar, wenn andere weniger invasive Verfahren der Atemwegssicherung misslingen oder sich situationsabhÀngig als nicht zweckmÀßig erweisen. Für die Durchführung wurden verschiedene Verfahren beschrieben, die in anatomisch-chirurgische PrÀpariertechniken und Punktionsverfahren unterteilt werden kânnen. Das im jeweiligen Notarztsystem bevorzugte Verfahren orientiert sich meist an abteilungsüblichen Standards, die vom klinischen Vorgehen abgeleitet werden. Ausbildungs- und Trainingsmâglichkeiten für die einzelnen Verfahren bestehen in der Intensivmedizin, am LeichenprÀparat und am Phantom. In dieser Arbeit werden verschiedene Methoden der Koniotomie besprochen sowie eine anatomische PrÀpariertechnik und 2Punktionsverfahren im Detail dargestell

    Plasma afterglow-assisted oxidation of iron–copper bilayers

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    International audienceIron layers with variable thicknesses, deposited onto copper thin films, are oxidized by a plasma afterglow at atmospheric pressure. Such a bilayer arrangement enables the growth of caterpillar-like patterns covered by CuO and Fe2O3 nanostructures. Two main mechanisms are at stake: either copper comes up to the surface through cracks or boundaries between the columns of the coating, or it diffuses through parts of the Fe2O3 layer made permeable by tensile stress. Structures grown by the former mechanisms are characterized by a central channel, whereas those grown by the latter exhibit a plane interface above which stands an equiaxed grain heap. This result was used to localize the growth of nanowires in cracks formed priory to the afterglow-assisted treatment. By resorting to XPS microscopy experiments carried out with the scanning photoelectron microscope at the ESCAMicroscopy beamline of the Elettra synchrotron facility in Trieste, we could gain access to the surface composition of a single isolated pattern

    ΠšΠ»ΠΈΠΌΠ°Ρ‚ΠΈΡ‡Π΅ΡΠΊΠΈΠ΅ особСнности ΠΈ статистичСскиС ΠΎΡ†Π΅Π½ΠΊΠΈ измСнСния элСмСнтов ΠΊΠ»ΠΈΠΌΠ°Ρ‚Π° Π² Ρ€Π°ΠΉΠΎΠ½Π°Ρ… Π²Π΅Ρ‡Π½ΠΎΠΉ ΠΌΠ΅Ρ€Π·Π»ΠΎΡ‚Ρ‹ Π½Π° Ρ‚Π΅Ρ€Ρ€ΠΈΡ‚ΠΎΡ€ΠΈΠΈ сСвСра Π—Π°ΠΏΠ°Π΄Π½ΠΎΠΉ Π‘ΠΈΠ±ΠΈΡ€ΠΈ

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    ΠΠΊΡ‚ΡƒΠ°Π»ΡŒΠ½ΠΎΡΡ‚ΡŒ Ρ€Π°Π±ΠΎΡ‚Ρ‹ связана с Π½Π΅ΠΎΠ±Ρ…ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒΡŽ ΠΎΡ†Π΅Π½ΠΊΠΈ ΠΈΠ·ΠΌΠ΅Π½Π΅Π½ΠΈΠΉ ΠΊΠ»ΠΈΠΌΠ°Ρ‚Π°, Π²Π»ΠΈΡΡŽΡ‰ΠΈΡ… Π½Π° ΠΌΠ½ΠΎΠ³ΠΎΠ»Π΅Ρ‚Π½ΡŽΡŽ ΠΌΠ΅Ρ€Π·Π»ΠΎΡ‚Ρƒ, Π² связи с Π²ΠΎΠ·ΠΌΠΎΠΆΠ½Ρ‹ΠΌ ΡƒΠ²Π΅Π»ΠΈΡ‡Π΅Π½ΠΈΠ΅ΠΌ выбросов ΠΏΠ°Ρ€Π½ΠΈΠΊΠΎΠ²Ρ‹Ρ… Π³Π°Π·ΠΎΠ² ΠΈ увСличСния аварийности Π½Π° ΠΎΠ±ΡŠΠ΅ΠΊΡ‚Π°Ρ… ΠΏΡ€ΠΎΠΌΡ‹ΡˆΠ»Π΅Π½Π½ΠΎΠΉ, Π² Ρ‚ΠΎΠΌ числС ΠΈ Π½Π΅Ρ„Ρ‚Π΅Π³Π°Π·ΠΎΠ²ΠΎΠΉ, инфраструктуры ΠΏΡ€ΠΈ таянии ΠΌΠ½ΠΎΠ³ΠΎΠ»Π΅Ρ‚Π½Π΅ΠΌΠ΅Ρ€Π·Π»Ρ‹Ρ… ΠΏΠΎΡ€ΠΎΠ΄. ЦСль Ρ€Π°Π±ΠΎΡ‚Ρ‹: исслСдованиС соврСмСнных ΠΈΠ·ΠΌΠ΅Π½Π΅Π½ΠΈΠΉ характСристик ΠΊΠ»ΠΈΠΌΠ°Ρ‚Π°, нСпосрСдствСнно Π²Π»ΠΈΡΡŽΡ‰ΠΈΡ… Π½Π° тСрмичСскоС состояниС ΠΏΠΎΡ‡Π²ΠΎΠ³Ρ€ΡƒΠ½Ρ‚ΠΎΠ² Π² Ρ€Π°ΠΉΠΎΠ½Π°Ρ… распространСния ΠΌΠ½ΠΎΠ³ΠΎΠ»Π΅Ρ‚Π½Π΅ΠΉ ΠΌΠ΅Ρ€Π·Π»ΠΎΡ‚Ρ‹ сСвСра Π—Π°ΠΏΠ°Π΄Π½ΠΎΠΉ Π‘ΠΈΠ±ΠΈΡ€ΠΈ. ΠœΠ΅Ρ‚ΠΎΠ΄Ρ‹ исслСдования. Анализ ΠΌΠ½ΠΎΠ³ΠΎΠ»Π΅Ρ‚Π½ΠΈΡ… ΠΈΠ·ΠΌΠ΅Π½Π΅Π½ΠΈΠΉ мСтСорологичСских Π΄Π°Π½Π½Ρ‹Ρ… Π²ΠΊΠ»ΡŽΡ‡Π°Π» Π² сСбя ΠΏΡ€ΠΎΠ²Π΅Ρ€ΠΊΡƒ Π½ΡƒΠ»Π΅Π²Ρ‹Ρ… Π³ΠΈΠΏΠΎΡ‚Π΅Π· ΠΎ случайности ΠΈ однородности рядов наблюдСний ΠΈ наличия Ρ‚Ρ€Π΅Π½Π΄Π°. ΠŸΡ€ΠΎΠ²Π΅Ρ€ΠΊΠ° Π½Π° ΠΎΠ΄Π½ΠΎΡ€ΠΎΠ΄Π½ΠΎΡΡ‚ΡŒ ΠΎΡΡƒΡ‰Π΅ΡΡ‚Π²Π»ΡΠ»Π°ΡΡŒ с ΠΏΠΎΠΌΠΎΡ‰ΡŒΡŽ тСста АббС, Π½Π° ΡΠ»ΡƒΡ‡Π°ΠΉΠ½ΠΎΡΡ‚ΡŒ - ΠΊΡ€ΠΈΡ‚Π΅Ρ€ΠΈΠ΅ΠΌ ΠŸΠΈΡ‚ΠΌΠ΅Π½Π°, Π½Π° Π½Π°Π»ΠΈΡ‡ΠΈΠ΅ Ρ‚Ρ€Π΅Π½Π΄Π° ΠΏΡ€ΠΎΠΈΠ·Π²ΠΎΠ΄ΠΈΠ»Π°ΡΡŒ с ΠΏΠΎΠΌΠΎΡ‰ΡŒΡŽ критСрия инвСрсий. Π’Ρ‹Π²ΠΎΠ΄ ΠΎ нСслучайном ΠΈΠ·ΠΌΠ΅Π½Π΅Π½ΠΈΠΈ ΠΈΠ»ΠΈ Π½Π°Ρ€ΡƒΡˆΠ΅Π½ΠΈΠΈ однородности рядов соотвСтствовал ΡƒΡΠ»ΠΎΠ²ΠΈΡŽ, ΠΊΠΎΠ³Π΄Π° расчСтная статистика ΠΏΡ€Π΅Π²Ρ‹ΡˆΠ°Π»Π° ΡΠΎΠΎΡ‚Π²Π΅Ρ‚ΡΡ‚Π²ΡƒΡŽΡ‰Π΅Π΅ критичСскоС Π·Π½Π°Ρ‡Π΅Π½ΠΈΠ΅ ΠΏΡ€ΠΈ ΡƒΡ€ΠΎΠ²Π½Π΅ значимости 0,05. Π Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Ρ‹. РассмотрСны особСнности ΠΊΠ»ΠΈΠΌΠ°Ρ‚Π° сСвСра Π—Π°ΠΏΠ°Π΄Π½ΠΎΠΉ Π‘ΠΈΠ±ΠΈΡ€ΠΈ ΠΈ Π΅Π³ΠΎ ΠΈΠ·ΠΌΠ΅Π½Ρ‡ΠΈΠ²ΠΎΡΡ‚ΡŒ Π² послСдниС Π³ΠΎΠ΄Ρ‹. Π˜ΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½Ρ‹ измСнСния Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Ρ‹ Π²ΠΎΠ·Π΄ΡƒΡ…Π° ΠΈ ΠΏΠΎΡ‡Π²ΠΎΠ³Ρ€ΡƒΠ½Ρ‚ΠΎΠ² Π½Π° Π³Π»ΡƒΠ±ΠΈΠ½Π°Ρ… 160 ΠΈ 320 см, ΠΏΡ€ΠΎΠ΄ΠΎΠ»ΠΆΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎΡΡ‚ΡŒ прямой солнСчной Ρ€Π°Π΄ΠΈΠ°Ρ†ΠΈΠΈ, суммы атмосфСрных осадков ΠΈ высоты снСТного ΠΏΠΎΠΊΡ€ΠΎΠ²Π° Π½Π° основС ΠΈΠ½ΡΡ‚Ρ€ΡƒΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½Ρ‹Ρ… Π΄Π°Π½Π½Ρ‹Ρ… Π·Π° послСдниС 35 Π»Π΅Ρ‚. Π’ Ρ€Π΅Π·ΡƒΠ»ΡŒΡ‚Π°Ρ‚Π΅ статистичСского Π°Π½Π°Π»ΠΈΠ·Π° установлСно сохранСниС Ρ‚Π΅ΠΌΠΏΠΎΠ² роста Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Ρ‹ Π²ΠΎΠ·Π΄ΡƒΡ…Π° Π² Ρ‚Π΅ΠΏΠ»ΠΎΠ΅ врСмя Π³ΠΎΠ΄Π°, ΡƒΠ²Π΅Π»ΠΈΡ‡Π΅Π½ΠΈΠ΅ Ρ‚Π΅ΠΌΠΏΠ΅Ρ€Π°Ρ‚ΡƒΡ€Ρ‹ ΠΏΠΎΡ‡Π²ΠΎΠ³Ρ€ΡƒΠ½Ρ‚ΠΎΠ² Π² Ρ‚Π΅Ρ‡Π΅Π½ΠΈΠ΅ всСго Π³ΠΎΠ΄Π°, выявлСн Π·ΠΎΠ½Π°Π»ΡŒΠ½Ρ‹ΠΉ Ρ…Π°Ρ€Π°ΠΊΡ‚Π΅Ρ€ измСнСния суммы атмосфСрных осадков ΠΈ снСТного ΠΏΠΎΠΊΡ€ΠΎΠ²Π°. ΠœΠΈΠΊΡ€ΠΎΠΊΠ»ΠΈΠΌΠ°Ρ‚ΠΈΡ‡Π΅ΡΠΊΠΈΠ΅ измСнСния характСристик мСтСорологичСских Π²Π΅Π»ΠΈΡ‡ΠΈΠ½ ΠΌΠΎΠ³ΡƒΡ‚ ΠΈΡΠΊΠ°ΠΆΠ°Ρ‚ΡŒ Ρ€Π΅Π°Π»ΡŒΠ½ΡƒΡŽ ΠΊΠ°Ρ€Ρ‚ΠΈΠ½Ρƒ измСнСния ΠΊΠ»ΠΈΠΌΠ°Ρ‚Π°.The relevance of the research is related to the necessity to assess climate changes affecting the permafrost due to the possible growth of greenhouse gas emissions and increase of accident rate in industrial, oil and gas infrastructure at permafrost thawing. The aim of the research is to estimate the current changes in climate characteristics, which affect directly the thermal state of soils in permafrost areas in the north of Western Siberia. Methods. Analysis of long-term changes of meteorological data consisted of tests of null hypothesis of randomness and homogeneity of observation series and trend presence. The homogeneity test was carried out using the Abbe test, the test of randomness was carried out by Pitman criterion, the trend presence was checked using the criterion of inversions. The conclusion on nonrandom change or violation of the homogeneity of rows corresponded to the condition, when the modulus of the estimated statistics exceeded the corresponding critical value at significance level of 0,05. Results. The paper considers the climatic features in the north of Western Siberia and its variability in recent years. The analysis of temperature changes of air and soil at depths of 160 and 320 cm, the amount of precipitation and snow cover based on the instrumental data for the last 35 years has shown that air temperature continues rising in the warmer months, soil temperature increases throughout the year. The authors have revealed zonal character of changes in the amount of precipitation and snow cover. Microclimatic changes in characteristic of meteorological values can distort the real picture of climate change

    Suspension-adapted Chinese hamster ovary-derived cells expressing green fluorescent protein as a screening tool for biomaterials

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    Synthetic biomaterials play an important role in regenerative medicine. To be effective they must support cell attachment and proliferation in addition to being non-toxic and non-immunogenic. We used a suspension-adapted Chinese hamster ovary-derived cell line expressing green fluorescent protein (GFP) to assess cell attachment and growth on synthetic biomaterials by direct measurement of GFP-specific fluorescence. To simplify operations, all cell cultivation steps were performed in orbitally-shaken, disposable containers. Comparative studies between this GFP assay and previously established cell quantification assays demonstrated that this novel approach is suitable for rapid screening of a large number of samples. Furthermore the utility of our assay system was confirmed by evaluation of cell growth on three polyvinylidene fluoride polymer scaffolds that differed in pore diameter and drawing conditions. The data presented here prove the general utility of GFP-expressing cell lines and orbital shaking technology for the screening of biomaterials for tissue engineering application

    Synthesis of RuO 2 nanowires from Ru thin films by atmospheric pressure micro-post-discharge

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    International audienceOxidation by a micro-post-discharge at atmospheric pressure of thin films of ruthenium deposited on fused silica by pressure-modulated magnetron sputtering is studied. Single-crystalline RuO 2 nanowires are obtained for the first time with a diffusion process over large areas. Nanowires grow typically at temperatures below 550-600 K, provided the level of stress is high enough to fragment grains in sub-grains with sizes between 30 and 50 nm. Because of the alternation of dense and porous layers forming the coating, inward diffusion of vacancies leads to no patent Kirkendall's effect, pores being distributed over the whole coating thickness and not mainly at the interface with the substrate. The centre of the treatment being heated at temperatures higher than 900 K, gaseous RuO 4 is formed, leading to an evaporated area. At its edge, a ring of microcrystals is formed, likely by a CVD mechanism

    Nanostructures design by plasma afterglow-assisted oxidation of iron–copper thin films

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    International audienceOxidizing thin films made of Fe-Cu alloy with an Ar-O 2 micro-afterglow operated at atmospheric pressure shows remarkable growth processes. The presence of iron in copper up to about 50% leads to the synthesis of CuO nanostructures (nanowalls, nanotowers and nanowires). Nanotowers show the presence of an amorphous phase trapped between crystalline domains. Beyond 50%, Fe 2 O 3 iron nano-blades are also found. CuO nanowires as small as 5 nm in diameter can be synthesized. Thanks to the presence of patterned domains induced by buckling, it was possible to show that the stress level decreases when the iron content in the alloy increases. Iron blades grow from the inner Fe 2 O 3 layer through the overlying CuO if it is thin enough
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