An infrared measurement of chemical desorption from interstellar ice analogues

In molecular clouds at temperatures as low as 10 K, all species except hydrogen and helium should be locked in the heterogeneous ice on dust grain surfaces. Nevertheless, astronomical observations have detected over 150 different species in the gas phase in these clouds. The mechanism by which molecules are released from the dust surface below thermal desorption temperatures to be detectable in the gas phase is crucial for understanding the chemical evolution in such cold clouds. Chemical desorption, caused by the excess energy of an exothermic reaction, was first proposed as a key molecular release mechanism almost 50 years ago. Chemical desorption can, in principle, take place at any temperature, even below the thermal desorption temperature. Therefore, astrochemical net- work models commonly include this process. Although there have been a few previous experimental efforts, no infrared measurement of the surface (which has a strong advantage to quantify chemical desorption) has been performed. Here, we report the first infrared in situ measurement of chemical desorption during the reactions H + H2S -> HS + H2 (reaction 1) and HS + H -> H2S (reaction 2), which are key to interstellar sulphur chemistry. The present study clearly demonstrates that chemical desorption is a more efficient process for releasing H2S into the gas phase than was previously believed. The obtained effective cross-section for chemical desorption indicates that the chemical desorption rate exceeds the photodesorption rate in typical interstellar environments

A New Method for Measuring Tail Exponents of Firm Size Distributions

We propose a new method for estimating the power-law exponents of firm size variables. Our focus is on how to empirically identify a range in which a firm size variable follows a power-law distribution. As is well known, a firm size variable follows a power-law distribution only beyond some threshold. On the other hand, in almost all empirical exercises, the right end part of a distribution deviates from a power-law due to finite size effect. We modify the method proposed by Malevergne et al. (2011) so that we can identify both of the lower and the upper thresholds and then estimate the power-law exponent using observations only in the range defined by the two thresholds. We apply this new method to various firm size variables, including annual sales, the number of workers, and tangible fixed assets for firms in more than thirty countries.Econophysics, power-law distributions, power-law exponents, firm size variables, finite size effect

Magnetic anisotropy switching in (Ga,Mn)As with increasing hole concentration

We study a possible mechanism of the switching of the magnetic easy axis as a function of hole concentration in (Ga,Mn)As epilayers. In-plane uniaxial magnetic anisotropy along [110] is found to exceed intrinsic cubic magnetocrystalline anisotropy above a hole concentration of p = 1.5 * 10^21 cm^-3 at 4 K. This anisotropy switching can also be realized by post-growth annealing, and the temperature-dependent ac susceptibility is significantly changed with increasing annealing time. On the basis of our recent scenario [Phys. Rev. Lett. 94, 147203 (2005); Phys. Rev. B 73, 155204 (2006).], we deduce that the growth of highly hole-concentrated cluster regions with [110] uniaxial anisotropy is likely the predominant cause of the enhancement in [110] uniaxial anisotropy at the high hole concentration regime. We can clearly rule out anisotropic lattice strain as a possible origin of the switching of the magnetic anisotropy.Comment: 5 pages, 4 figures, to appear in Phys. Rev.

Quantum Valence Criticality as Origin of Unconventional Critical Phenomena

It is shown that unconventional critical phenomena commonly observed in paramagnetic metals YbRh2Si2, YbRh2(Si0.95Ge0.05)2, and beta-YbAlB4 is naturally explained by the quantum criticality of Yb-valence fluctuations. We construct the mode coupling theory taking account of local correlation effects of f electrons and find that unconventional criticality is caused by the locality of the valence fluctuation mode. We show that measured low-temperature anomalies such as divergence of uniform spin susceptibility \chi T^{-\zeta) with $\zeta~0.6$ giving rise to a huge enhancement of the Wilson ratio and the emergence of T-linear resistivity are explained in a unified way.Comment: 5 pages, 3 figures, to be published in Physical Review Letter

Projection neurons in lamina III of the rat spinal cord are selectively innervated by local dynorphin-containing excitatory neurons

Large projection neurons in lamina III of the rat spinal cord that express the neurokinin 1 receptor are densely innervated by peptidergic primary afferent nociceptors and more sparsely by low-threshold myelinated afferents. However, we know little about their input from other glutamatergic neurons. Here we show that these cells receive numerous contacts from nonprimary boutons that express the vesicular glutamate transporter 2 (VGLUT2), and form asymmetrical synapses on their dendrites and cell bodies. These synapses are significantly smaller than those formed by peptidergic afferents, but provide a substantial proportion of the glutamatergic synapses that the cells receive (over a third of those in laminae I–II and half of those in deeper laminae). Surprisingly, although the dynorphin precursor preprodynorphin (PPD) was only present in 4–7% of VGLUT2 boutons in laminae I–IV, it was found in 58% of the VGLUT2 boutons that contacted these cells. This indicates a highly selective targeting of the lamina III projection cells by glutamatergic neurons that express PPD, and these are likely to correspond to local neurons (interneurons and possibly projection cells). Since many PPD-expressing dorsal horn neurons respond to noxious stimulation, this suggests that the lamina III projection cells receive powerful monosynaptic and polysynaptic nociceptive input. Excitatory interneurons in the dorsal horn have been shown to possess IA currents, which limit their excitability and can underlie a form of activity-dependent intrinsic plasticity. It is therefore likely that polysynaptic inputs to the lamina III projection neurons are recruited during the development of chronic pain states

Eighth-Order Vacuum-Polarization Function Formed by Two Light-by-Light-Scattering Diagrams and its Contribution to the Tenth-Order Electron g-2

We have evaluated the contribution to the anomalous magnetic moment of the electron from six tenth-order Feynman diagrams which contain eighth-order vacuum-polarization function formed by two light-by-light scattering diagrams connected by three photons. The integrals are constructed by two different methods. In the first method the subtractive counter terms are used to deal with ultraviolet (UV) singularities together with the requirement of gauge-invariance. In the second method, the Ward-Takahashi identity is applied to the light-by-light scattering amplitudes to eliminate UV singularities. Numerical evaluation confirms that the two methods are consistent with each other within their numerical uncertainties. Combining the two results statistically and adding small contribution from the muons and/or tau leptons, we obtain $0.000 399 9 (18) (\alpha/\pi)^5$. We also evaluated the contribution to the muon $g-2$ from the same set of diagrams and found $-1.263 44 (14) (\alpha/\pi)^5$.Comment: 27 page

Tau longitudinal polarization in B -> D tau nu and its role in the search for charged Higgs boson

We study the longitudinal polarization of the tau lepton in B -> D tau nu decay. After discussing possible sensitivities of tau decay modes to the tau polarization, we examine the effect of charged Higgs boson on the tau polarization in B -> D tau nu. We find a relation between the decay rate and the tau polarization, and clarify the role of the tau polarization measurement in the search for the charged Higgs boson.Comment: 17 pages, 3 figures. Tau -> l nu nu is included in Sec. II. Accordingly the title is changed. References are adde

In-plane anisotropy on the transport properties in the modulated Bi_2O_2-based conductors Bi-2212 and Bi-Sr-Co-O

We investigated the in-plane anisotropy on the resistivity and thermopower of the Bi_2Sr_2CaCu_2O_{8+\delta} (Bi-2212) and Bi-Sr-Co-O (BiCo) single crystals. In Bi-2212, the b-axis resistivity is higher than the a-axis resistivity, and is expressed as a sum of the a-axis resistivity and an additional residual resistivity. A downward deviation due to pseudogap is observed below a characteristic temperature T^*, which is isotropic in the form of conductivity. These results suggest that the modulation structure along the b-axis works as an anisotropic scattering center, but does not affect the pseudogap formation. On the other hand, the anisotropy of the resistivity and the thermopower in Pb-doped BiCo is substantial, probably owing to the misfit structure between the hexagonal CoO_2 layer and the rock salt Bi_2O_2 layer. However, the anisotropy in the resistivity in Pb-free BiCo is very small, suggesting that the in-plane anisotropy is averaged by the modulation structure, whose direction is tilted by 45 deg from the a- and b-axes.Comment: 4pages 5 figures, Proceedings of ISS2001, Physica C (in press

Microfluidic-SANS: flow processing of complex fluids

Understanding and engineering the flow-response of complex and non-Newtonian fluids at a molecular level is a key challenge for their practical utilisation. Here we demonstrate the coupling of microfluidics with small angle neutron scattering (SANS). Microdevices with high neutron transmission (up to 98%), low scattering background ([Image: see text]), broad solvent compatibility and high pressure tolerance (≈3–15 bar) are rapidly prototyped via frontal photo polymerisation. Scattering from single microchannels of widths down to 60 μm, with beam footprint of 500 μm diameter, was successfully obtained in the scattering vector range 0.01–0.3 Å(−1), corresponding to real space dimensions of [Image: see text]. We demonstrate our approach by investigating the molecular re-orientation and alignment underpinning the flow response of two model complex fluids, namely cetyl trimethylammonium chloride/pentanol/D(2)O and sodium lauryl sulfate/octanol/brine lamellar systems. Finally, we assess the applicability and outlook of microfluidic-SANS for high-throughput and flow processing studies, with emphasis of soft matter

Muon spin relaxation and rotation study on the solid solution of the two spin-gap systems (CH3)2CHNH3-CuCl3 and (CH3)2CHNH3-CuBr3

Muon-spin-rotation and relaxation studies have been performed on (CH$_3$)$_2$CHNH$_3$Cu(Cl$_x$Br$_{1-x}$)$_3$ with $x$=0.85 and 0.95, which are solid solutions of the two isomorphic spin-gap systems (CH$_3$)$_2$CHNH$_3$CuCl$_3$ and (CH$_3$)$_2$CHNH$_3$CuBr$_3$ with different spin gaps. The sample with $x$=0.85 showed a clear muon spin rotation under zero-field below $T_{\rm N}$=11.65K, indicating the existence of a long-range antiferromagnetic order. A critical exponent of the hyperfine field was obtained to be $\beta$=0.33, which agrees with 3D-Ising model. In the other sample with $x$=0.95, an anomalous enhancement of the muon spin relaxation was observed at very low temperatures indicating a critical slowing down due to a magnetic instability of the ground state