Dynamics of Chainlike Molecules on Surfaces

We consider the diffusion and spreading of chainlike molecules on solid surfaces. We first show that the steep spherical cap shape density profiles, observed in some submonolayer experiments on spreading polymer films, imply that the collective diffusion coefficient $D_C(\theta)$ must be an increasing function of the surface coverage $\theta$ for small and intermediate coverages. Through simulations of a discrete model of interacting chainlike molecules, we demonstrate that this is caused by an entropy-induced repulsive interaction. Excellent agreement is found between experimental and numerically obtained density profiles in this case, demonstrating that steep submonolayer film edges naturally arise due to the diffusive properties of chainlike molecules. When the entropic repulsion dominates over interchain attractions, $D_C(\theta)$ first increases as a function of $\theta$ but then eventually approaches zero for $\theta \to 1$. The maximum value of $D_C(\theta)$ decreases for increasing attractive interactions, leading to density profiles that are in between spherical cap and Gaussian shapes. We also develop an analytic mean field approach to explain the diffusive behavior of chainlike molecules. The thermodynamic factor in $D_C(\theta)$ is evaluated using effective free energy arguments, and the chain mobility is calculated numerically using the recently developed dynamic mean field theory. Good agreement is obtained between theory and simulations.Comment: 16 pages, 13 Postscript figure

Testing the Effectiveness of Regulation and Competition on Cable Television Rates

Regulation of the cable television industry was marked by remarkable periods of deregulation, re-regulation, and re-deregulation during the 1980s and 1990s. Using FCC firm-level survey data spanning 1993 to 2001, we model and econometrically estimate the effect of regulation and competition on cable rates. Our calculations indicate that while regulation lowered rates for small system operators, it raised them for medium and large systems. Meanwhile, competition consistently decreased rates from 5.6 to 8.8 percent, with even larger declines during periods of regulation. Our results suggest that competition is more effective than regulation in containing cable prices.cable rates, regulation, competition

Testing the Effectiveness of Regulation and Competition on Cable Television Rates

Regulation of the cable television industry was marked by remarkable periods of deregulation, re-regulation, and re-deregulation during the 1980s and 1990s. Using FCC firm-level survey data spanning 1993 to 2001, we model and econometrically estimate the effect of regulation and competition on cable rates. Our calculations indicate that while regulation lowered rates for small system operators, it raised them for medium and large systems. Meanwhile, competition consistently decreased rates from 5.6 to 8.8 percent, with even larger declines during periods of regulation. Our results suggest that competition is more effective than regulation in containing cable prices.cable rates, regulation, competition

Observation of Zeeman effect in topological surface state with distinct material dependence

The helical Dirac fermions on the surface of topological insulators host novel relativistic quantum phenomena in solids. Manipulating spins of topological surface state (TSS) represents an essential step towards exploring the theoretically predicted exotic states related to time reversal symmetry (TRS) breaking via magnetism or magnetic field. Understanding Zeeman effect of TSS and determining its g-factor are pivotal for such manipulations in the latter form of TRS breaking. Here, we report those direct experimental observations in Bi2Se3 and Sb2Te2Se by spectroscopic imaging scanning tunneling microscopy. The Zeeman shifting of zero mode Landau level is identified unambiguously by judiciously excluding the extrinsic influences associated with the non-linearity in the TSS band dispersion and the spatially varying potential. The g-factors of TSS in Bi2Se3 and Sb2Te2Se are determined to be 18 and -6, respectively. This remarkable material dependence opens a new route to control the spins in the TSS.Comment: main text: 17 pages, 4 figures; supplementary: 15 pages, 7 figure

Equilibrium Shape and Size of Supported Heteroepitaxial Nanoislands

We study the equilibrium shape, shape transitions and optimal size of strained heteroepitaxial nanoislands with a two-dimensional atomistic model using simply adjustable interatomic pair potentials. We map out the global phase diagram as a function of substrate-adsorbate misfit and interaction. This phase diagram reveals all the phases corresponding to different well-known growth modes. In particular, for large enough misfits and attractive substrate there is a Stranski-Krastanow regime, where nano-sized islands grow on top of wetting films. We analyze the various terms contributing to the total island energy in detail, and show how the competition between them leads to the optimal shape and size of the islands. Finally, we also develop an analytic interpolation formula for the various contributions to the total energy of strained nanoislands.Comment: 9 pages, 7 figure

Theory of non-Fermi liquid near a diagonal electronic nematic state on a square lattice

We study effects of Fermi surface fluctuations on a single-particle life time near the diagonal electronic nematic phase on a two-dimensional square lattice. It has been shown that there exists a quantum critical point (QCP) between the diagonal nematic and isotropic phases. We study the longitudinal fluctuations of the order parameter near the critical point, where the singular forward scattering leads to a non-Fermi liquid behavior over the whole Fermi surface except along the k_x- and k_y-directions. We will also discuss the temperature and chemical potential dependence of the single-particle decay rate.Comment: 4 pages, 3 figures, revtex

Absolute continuity of symmetric Markov processes

We study Girsanov's theorem in the context of symmetric Markov processes, extending earlier work of Fukushima-Takeda and Fitzsimmons on Girsanov transformations of ``gradient type.'' We investigate the most general Girsanov transformation leading to another symmetric Markov process. This investigation requires an extension of the forward-backward martingale method of Lyons-Zheng, to cover the case of processes with jumps.Comment: Published by the Institute of Mathematical Statistics (http://www.imstat.org) in the Annals of Probability (http://www.imstat.org/aop/) at http://dx.doi.org/10.1214/00911790400000043

Optimization of synchronization in gradient clustered networks

We consider complex clustered networks with a gradient structure, where sizes of the clusters are distributed unevenly. Such networks describe more closely actual networks in biophysical systems and in technological applications than previous models. Theoretical analysis predicts that the network synchronizability can be optimized by the strength of the gradient field but only when the gradient field points from large to small clusters. A remarkable finding is that, if the gradient field is sufficiently strong, synchronizability of the network is mainly determined by the properties of the subnetworks in the two largest clusters. These results are verified by numerical eigenvalue analysis and by direct simulation of synchronization dynamics on coupled-oscillator networks.Comment: PRE, 76, 056113 (2007